Enthalpic and entropic contributions to dissociation of halogen-acetic acids and linear free energy relationship in EtOH-H2O mixtures at 298.15 K

Thermochimica Acta

Volumn 421, Issue 1-2, 2004, Pages 185-192

  Lei, Qun Fang ^a   Fang, Wen Jun ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Acid; Dissociation; Enthalpic contribution; Entropic contribution; Linear free energy relationship (LFER); Mixed solvent

Indexed keywords

DISSOCIATION; ENTHALPY; ENTROPY; FREE ENERGY; HALOGEN COMPOUNDS; PERMITTIVITY; RATE CONSTANTS; SUBSTITUTION REACTIONS;

ENTROPIC CONTRIBUTIONS; HALOGEN-ACETIC ACIDS; HAMMET TYPE EQUATION; LINEAR FREE ENERGY RELATIONSHIP (LFER);

ACETIC ACID;

ACETIC ACID; CARBON; HALOGEN; HYDROGEN; OXYGEN; SOLVENT;

ARTICLE; CALCULATION; DIELECTRIC CONSTANT; DISSOCIATION; ENERGY; ENTHALPY; ENTROPY; QUANTITATIVE ANALYSIS; REACTION ANALYSIS;

EID: 12344293336     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2004.03.009     Document Type: Article

References (30)

1. Lior J. J. Solution Chem. 28:1999;1
2. Christensen J.J., Izatt R.M., Hansen C.D. J. Am. Chem. Soc. 89:1967;213
3. Christensen J.J., Wrathall D.P., Izatt R.M., Tolman D.O. J. Phys. Chem. 71:1967;3001
4. Christensen J.J., Oscarson J.J., Izatt R.M. J. Am. Chem. Soc. 90:1968;5949
5. Christensen J.J., Izatt R.M., Hansen L.D. Rev. Sci. Instr. 36:1965;779
6. Avedikian L. Bull. Soc. Chim. France. 8:1966;2570
7. Mozel J.P., Faure J., Avedikian L., Juiliard J. J. Solution Chem. 3:1974;403
8. Avedikian L., Dollet N. Bull. Soc. Chim. France. 12:1967;4551
9. Rodante F., Rallo F., Fiordiponti P. Thermochim. Acta. 9:1974;269
10. Rodante F. Thermochim. Acta. 57:1982;29
11. Rodante F., Pistoia G. Thermochim. Acta. 83:1985;213
12. Rodante F., Fantauzzi F. Thermochim. Acta. 109:1987;353
13. Rodante F., Fantauzzi F. Thermochim. Acta. 144:1989;75
14. Hu R.D., Yen W.X., Lin R.S., Yu Q.S. Thermochim. Acta. 183:1991;65
15. Lei Q.F., Zong H.X., Lin R.S., Yu Q.S. Thermochim. Acta. 247:1994;315
16. Lei Q.F., Yu Q.S., Zong H.X., Lin R.S. Acta Chim. Sinica. 53:1995;120
17. Li G., Lin R.S., Zong H.X. Acta Physico-Chim. Sinica. 16:2000;188
18. Hu X.G., Lin R.S. Thermochim. Acta. 346:2000;9
19. Lagoa A.L.C., Diogo H.P., Dias M.P., Minas da Piedade M.E., Amaral L.M.P.F., Ribeiro da Silva M.A.V., Martinho Simoes J.A., Guedes R.C., Costa Cabral B.J., Schwarz K., Epple M. Chem. Eur. J. 7:2001;483
20. J.A. Riddick, W.B. Bunger, T.K. Sakano, Organic solvents, Physical Properties and Methods of Purification Techniques of Chemistry, vol. II, fourth ed., Wiley, New York, 1986.
21. Evertt D.H., Wynre-Jones W.F.K. Trans. Faraday Soc. 35:1939;1380
22. Wadso I. Acta Chem. Scand. 16:1962;479
23. Harned H.S., Ehlers R.W. J. Am. Chem. Soc. 55:1933;652
24. Cannady W.J., Papee H.M., Laidler K.J. Trans. Faraday Soc. 54:1958;502
25. D.J.G. Ives, J.H. Pryor, J. Chem. Soc. (1955) 2104.
26. Wright D.D. J. Am. Chem. Soc. 56:1934;314
27. King E.J. J. Am. Chem. Soc. 82:1960;3575
28. Pytela O., Ludwig M., Vecera M. Collect. Czech. Chem. Commun. 51:1985;2143
29. Charton M. Progr. Phys. Org. Chem. 12:1981;119
30. Niazi M.S.K., Shah S.S., Ali J., Khan M.Z.I. J. Solution Chem. 19:1990;623