Ultrasensitive quantitative determination of paraquat: Application to river, ground, and drinking water analysis in an agricultural area

Journal of Agricultural and Food Chemistry

Volumn 53, Issue 2, 2005, Pages 216-219

  Bacigalupo, Maria A ^a   Meroni, Giacomo ^a   Mirasoli, Mara ^b   Parisi, Daniela ^b   Longhi, Renato ^a  

^a CNR   (Italy)

^b UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

Bipyridylium herbicides; Europium chelate; Immunoassay; Paraquat; Time resolved fluorescence

Indexed keywords

4,7 BIS(CHLOROSULFOPHENYL) 1,10 PHENANTHROLINE 2,9 DICARBOXYLIC ACID; 5 (1' METHYL 4,4 BIPYRIDINYL 1 YL)PENTANOIC ACID; ANTIBODY CONJUGATE; BOVINE SERUM ALBUMIN; DICARBOXYLIC ACID DERIVATIVE; DRINKING WATER; EUROPIUM; GROUND WATER; IMMUNOGLOBULIN G ANTIBODY; PARAQUAT; POLYCLONAL ANTIBODY; RIVER WATER; UNCLASSIFIED DRUG; VALERIC ACID DERIVATIVE; WELL WATER;

AGRICULTURE; ARTICLE; CHEMICAL ANALYSIS; FLUORESCENCE; HERBICIDAL ACTIVITY; IMMUNOASSAY; IRRIGATION (AGRICULTURE); ITALY; NONHUMAN; QUANTITATIVE ANALYSIS; RABBIT; SENSITIVITY ANALYSIS; SHEEP; SOLID; WATER ANALYSIS; WATER SAMPLING;

AGRICULTURE; ANTIBODY SPECIFICITY; CHELATING AGENTS; EUROPIUM; FLUOROIMMUNOASSAY; HERBICIDES; PARAQUAT; SENSITIVITY AND SPECIFICITY; WATER;

BOVINAE; ORYCTOLAGUS CUNICULUS; OVIS ARIES; TOUCHARDIA LATIFOLIA;

EID: 12344281550     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf048746u     Document Type: Article

References (21)

1. Suntres, Z. E. Role of antioxidants in paraquat toxicity. Toxicology 2002, 180, 65-77.
2. Halliwell, B.; Gutteridge, M. C. Free Radicals in Biology and Medicine, 3rd ed.; Oxford University Press: New York, 1999.
3. Rao, P. S. C.; Davidson, J. M. Estimation of pesticide retention and transformation parameters required in nonpoint source pollution models. In Environmental Impact of Nonpoint Source Pollution; Overcash, M. R., Davidson, J. M., Eds.; Ann Arbor Science: Newton, MA, 1980.
4. U.S. National Library of Medicine. Hazardous Substances Databank; U.S. National Library of Medicine: Bethesda, MD, 1995.
5. Drinking Water Guidelines; EEC No. L229/11-29; EU: Brussels, 1980.
6. Kuo, T.-L.; Lin, D.-L.; Liu, R. H.; Moriya, F.; Hashimoto, Y. Spectra interference between diquat and paraquat by second derivative spectrophotometry. Forensic Sci. Int. 2001, 121, 134-139.
7. Fuke, C.; Arao, T.; Morinaga, Y.; Takaesu, H.; Ameno, K.; Miyazaki, T. Analysis of paraquat, diquat and two diquat metabolites in biological materials by high-performance liquid chromatography. Leg. Med. (Tokyo) 2002, 4, 156-163.
8. Grey, L.; Nguyen, B.; Yang, P. Liquid chromatography-electrospray ionization isotope dilution mass spectrometry analysis of paraquat and diquat using conventional and multilayer solid-phase extraction cartridges. J. Chromatogr. A 2002, 958, 25-33.
9. Arys, K.; Van Bocxlaer, J.; Clauwaert, K.; Lambert, W.; Piette, M.; Van Peteghem, C.; De Leenheer, A. Quantitative determination of paraquat in fatal intoxication by HPLC-DAD following chemical reduction with sodium borohydride. J. Anal. Toxicol. 2000, 24, 116-121.
10. Nunez, O.; Moyano, E.; Puignon, L.; Galceran, M. T. Sample stacking with matrix removal for the determination of paraquat, diquat and difenzoquat in water by capillary electrophoresis. J. Chromatogr. A 2001, 912, 353-361.
11. Vinner, E.; Stievenart, M.; Humbert, L.; Mathieu, D.; Lhermitte, M. Separation and quantification of paraquat and diquat in serum and urine by capillary electrophoresis. Biomed. Chromatogr. 2001, 15, 342-347.
12. Nunez, O.; Moyano, E.; Galceran, M. T. Capillary electrophoresis-mass spectrometry for the analysis of quaternary ammonium herbicides. J. Chromatogr. A 2002, 974, 243-255.
13. Santillo, A.; Casentini, B.; Spagnoli, M.; Dommarco, R. Analysis of bipiridynium herbicides by capillary zone electrophoresis. J. Capillary Electrophor. 2003, 8, 1-5.
14. Spinks, C. A.; Wang, B.; Mills, E. N.; Morgan, M. R. Development of an ELISA for paraquat; improvement of antibody characteristics by reversed affinity chromatography. Analyst 1999, 124, 847-850.
15. Mastichiadis, C.; Kakabakos, S. E.; Christofidis, I.; Koupparis, M. A.; Willets, C.; Misiako, K. Simultaneous determination of pesticides using a four-band disposable optical capillary immunosensor. Anal. Chem. 2002, 74, 6064-6072.
16. Mallat, E.; Barzen, C.; Abuknesha, R:, Gaugitz, G.; Barceló, D. Fast determination of paraquat residues in water by an optical immunosensor and validation using capillary electrophoresis-ultraviolet detection. Anal. Chim. Acta. 2001, 427, 165-171.
17. Bacigalupo, M. A.; Ius, A.; Meroni, G.; Grassi, G.; Moschella, A. Time-resolved fluoroimmunoassay of abscisic acid in potato leaves. Analyst 1998, 123, 731-733.
18. Evangelista, P. A.; Pollak A.; Allore, B.; Templeton, E. F.; Morton, R. C.; Diamandis, E. P. A new europium chelate for protein labeling and time-resolved fluorometric applications. Clin. Biochem. 1988, 21, 173-178.
19. Van Emon, J.; Hammock, B.; Seiber, J. N. Enzyme-linked immunosorbent assay for paraquat and its application to exposure analysis. Anal. Chem. 1986, 58, 1866-1873.
20. Paixão, P.; Costa, P.; Bugalho, T.; Fidalgo, C.; Pereira, L. M. Simple method for determination of paraquat in plasma and serum of human patients by high-performance liquid chromatography. J. Chromatogr. B 2002, 775, 109-113.
21. Ross, J. H.; Krieger, R. I. Synthesis and properties of paraquat (methyl viologen) and other herbicidal alkyl homologues. J. Agric. Food Chem. 1980, 28, 1026-1031.