Ceramic materials for SOFCs: Current status

Boletin de la Sociedad Espanola de Ceramica y Vidrio

Volumn 41, Issue 5, 2002, Pages 471-480

  Kozhukharov, V ^a   Brashkova, N ^a   Ivanova, M ^a   Carda, J ^b   Machkova, M ^a  

^a UNIVERSITY OF CHEMICAL TECHNOLOGY AND METALLURGY   (Bulgaria)

^b UNIVERSITAT JAUME I   (Spain)

Author keywords

Anodes; Cathodes; Ceramic materials; Current analysis; Electrolytes; Lanthanum base perovskites; Patent status; Phase diagrams; SOFCs

Indexed keywords

ANODES; CATHODES; CERAMIC MATERIALS; ELECTRODES; ELECTROLYTES; FUEL CELLS; LANTHANUM; PATENTS AND INVENTIONS; PEROVSKITE; PHASE DIAGRAMS; SOLID OXIDE FUEL CELLS (SOFC);

COMPOSITION CONTROL; CURRENT ANALYSIS; DEVELOPMENT AND APPLICATIONS; ECONOMICAL PARAMETERS; OXYGEN INCORPORATION; PATENT STATUS; SOLID OXIDE FUEL CELLS (SOFCS); STATE OF THE ART;

SOLID ELECTROLYTES;

EID: 12344279671     PISSN: 03663175     EISSN: None     Source Type: Journal    
DOI: 10.3989/cyv.2002.v41.i5.666     Document Type: Conference Paper

References (63)

1. K. Kordesch, G. Simader. "Fuel Cells and Their Applications", VCH Verlagsgesellshaft GmbH, Weinheim, N.Y., Basel, Cambridge, Tokyo p. 9 (1996).
2. V. Kozhukharov, M. Machkova, M. Ivanova, N. Brashkova. "Patent State-of-the-art in SOFCs Application", pp. 244-254 in Solid Oxide Fuel Cells VII. vol. 16, 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc., Pennington, NJ (USA) 2001.
3. NexTechMaterials, USA, http://www.nextechmaterials.com
4. A. Ramanarayanan, S. Singhal, E. Wachsman. "High Temperature Ion Conducting Ceramics". Interface 2 [10] 22-26 (2001).
5. K.Kordesh, G.Simader. "Fuel Cells and Their Applications", VCH Verlag , Weinheim, N.Y., Basel, Cambridge, Tokyo, p.10 (1996).
6. T.Kawada, H. Yokokawa. "Materials and Characterization of Solid Oxide Fuel Cell". Key Eng. Materials 125-126 187-203 (1997).
7. J. Ralph, A. Schoeler, M. Krumpelt. "Materials for Lower Temperature Solid Oxide Fuel Cells", J. Mater. Sci. 36 1161-1164 (2001).
8. N. Hart, N. Brandon, M. Day, J. Shemilt. "Functionally Graded Cathodes for SOFCs". J. Mater. Sci. 36 1077-1080 (2001).
9. J. Kilner. "Ceramic Electrodes for SOFCs". Bol. Soc. Esp. Ceram. Vidrio 37 247-250 (1997).
10. S. Singhal. "Advances in SOFC Technology". Solid State Ionics 135 305-315 (2000).
11. N. Q. Minh, Ceramic Fuel Cells , J. Americ. Ceram. Soc. 76 , 563-588 (1993)
12. Proceedings 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII) June 3- 8,2001 / v. 2001-16, EPOCHAL Tsukuba Intern. Congress Centre, Japan, Ed. H. Yokokava & S. Singhal, Proceed. The Electrochem. Soc., Inc. (2001).
13. M. J. Jorgensen. "Effect of Sintering Temperature on Microstructure and Performance of LSM-YSZ Composite Cathodes".Solid State Ionics 139 1-11 (2001).
14. A. Petric, P. Huang, Frank Tietz. "Evaluation of La-Sr-Co-Fe-O Perovskites for Solid Oxide Fuel Cells and Gas Separation Membranes". Solid State Ionics 135 719-725 (2000).
15. V.M. Goldschmidt, Skrifter Norvske Videnskaps- Acad. Mat. Naturvid., kl. 2 (1926)
16. JCPDS Crystal Data Determinative Tables, Inorganic Compounds, Ed. J. Donnay, H. Ondik, third Edition, Published by NSRDS- Library of Congress, vol. 2, p. T-115 (1973).
17. "Ouyou Bussei Kagaku" (in Japanese), pp.112-116. Ed. T. Uchida, S. Mizuta, Asakura Shoten, Tokyo, (Japan) 2000.
18. N.Zhang, W.Yang, G.Li. "Sintering Temperature-Dependent Magnetism and Structure in Granular Perovskites". Chemical Physics Letters 313 [1-2] 69-75 (1999).
19. M. Suzuki, M. Echiko, O. Yamazaki. Osaka Gas Co. Ltd. " Cylindrical Solid Oxide Electrolyte Fuel Cell". JP num.10223239 A (21-08-1998).
20. F. Rohr. ABB Patent GmbH."Elektrodenschicht für eine Brennstoffzelle und Verfahren zur Herstellung der Electrodenschicht®. DE num. 4116734 CI (15-10-1992).
21. M. Sato, C. Ichikawa, T. Arai, T.Yoshimura, T. Kurobe. YKK Corp. "Testoxid-Brennstoffzelle und Verfahren zu ihrer Herstellung". DE num. 4241884 C2 (06-03-1997).
22. Y Sato, H. Tsuneizumi, H. Nakagawa, E.Morishige , H. Mihara. NKK. Corp. "Fuel Cell". EPnum. 0361383 Al (04-04-1990).
23. T. Satake, K. Watanabe, F. Nanjo, K. Takenobu, H. Miyamoto. Mitsubishi Jukogyo Kabushiki Kaisha. "Solid Oxide Electrolyte Fuel Cell".EPnum. 0692836 Al (17-01-1996).
24. 3-a". Solid State Ionics. 12 119-124 (1984).
25. 3+δ I. Phase relations". Acta Chem. Scand. 50 580- 586 (1996).
26. 3+δ Part II.Crystal Structure". Acta Chem. Scand. 51 904- 909 (1997).
27. 3+δ III. Magnetic Order Studied by Powder Neutron Diffraction". J. Sol. State Chem. 124 43- 51 (1996).
28. M. Machkova, N. Brashkova, P. Ivanov, J.B.Carda, V Kozhukharov. "Surface Behavior of Sr- Doped Lanthanide Perovskites". Applied Surface Science 119 127-136 (1997).
29. Phase Equilibrium Diagram, CD ROM Data Base, NIST, The Amer. Ceram. Soc. ISBN: 0-944904-93-9 Selection: Fig 61, Fig. 340, (1993).
30. I. Gavrilova, N. Proskurnina, V Cherepanov. "Phase Equilibria in the La-Co-Ni-O System", pp.458-465 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
31. 3 Perovskites. New Cathode Materials for Solid- Oxide Fuel Cells". J. Electrochem. Soc. 9 3220-3227 (1998).
32. J. Fleig, J. Maier. "On the Width of the Electrochemically Active Region in Mixed Conducting SOFCs Cathodes", pp.583-589 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc.,Pennington, NJ ,2001.
33. 3-ä / Ittria Stabilized Zirconia Interface by Secondary-Ion Mass Spectrometry". J. Electrochem. Soc. 145 3196- 3202 (1998).
34. N. Sakai, K. Yamaji, H. Negishi, T. Horita, Y.-P. Xiong, H. Yokokawa. "Effect of Water Vapor on Cathode Reaction in SOFC", pp.511-520 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
35. 3 based electrolyte", pp.439-448 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc., Pennington, NJ (USA) 2001.
36. J. Ralph, J.Vaughey, M. Krumpelt. "Evaluation of potential cathode materials for SOFC operation between 500- 800°C", p.466- 475 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
37. J. R. Jurado, E. Chinarro, M. T. Colomer. "Ceramic Conductors for Electrochemical Cell Applications: New Perspectives in Materials and Synthesis". Solid State Ionics 135 365-372 (2000).
38. T. Takahashi, Physics of Electrolytes, Vol. 2, p.65, Academic Press, London, (1972).
39. 3-δ (z=1, 0.9; M=Cr, Mn, Co, Ni) with Yttria Stabilized Zirconia". Solid State Ionics 89 215-220 (1996).
40. A.Wels. "Structural Inorganic Chemistry", p. 300 Fifth Edition., Pub. Clarendon Press, Oxford, vol. 2, Moscow, Mir, ( Russian Edition ) (1987).
41. 3 and Implications for SOFC", pp.319-328 in Solid Oxide Fuel Cells VII. vol. 16:7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
42. 3 System". Yogyo-Kyokai-Shi 93 295 (1985).
43. Y. Du, N.Sammes, G. Tompsett, M.Bowden. "Comparison of Mechanical and Thermal Properties of the Tubular LSGM CGO and YSZ Electrolytes", pp.311-318 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
44. Booklet of the Institute of Multidisciplinary Research for Advanced Materials (IMRAM) at Tohoku University, Sendai, Japan (2001) p.51
45. Y. Mizutani, M. Kawai. Toho Gas Co. Ltd. "Gas Seal Structure of Honeycomb Structure Solid Electrolyte Fuel Cell". JP num.10189017 A (21-07-1998).
46. S. Adler, R. Cutler, B. Henderson, J. Ludlow, R. Richards, D. Taylor, M. Wilson. Air Products and Chemicals, Inc. "Planar Solid Electrolyte Cell Stack Working as Oxygen Pump, with Offset Seals and Biasing Electrodes". EP num. 0834950 A2 (08-04-1998).
47. G. Blaβ, H. Peter, Detlev. Forschungszentrum Jülich GmbH. "SOFC Brennstiffzelle mit Einer Anodenzwischenschicht". DE num. 19819453 Al(ll-ll-1999).
48. U. Bossel, F. Rohr. Asea Brown Boveri AG. "Anordnung von Brennstoffzellen auf der Basis Eines Hochtemperatur-Feststoffelektrolyten". DE num. 4033284 Al (14-02-1991).
49. S. Elangovan, A. Khandkar. Gas Research Inst. "SOFC Anode for Enhanced Performance Stability and Method for Manufacturing same". US num.6099985 (2000).
50. W. Schäfer , D. Stolten, M. Fandel. Dornier GmbH. "Keramische Gasanschlussbauteile für Brennstoffzellen mit Zirkonoxid- Festelektrolyt". EP num. 0606579 A2 (20-07-1994).
51. M. Joerger, L. Gauckler. "Catalytically Active Anodes for SOFC", pp.662-670 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
52. H.Uchida, M.Sugimoto, M. Watanabe. "High Performance Electrode for Medium- Temperature SOFCs Activation on Yttria-Doped Ceria Anode with Highly Dispersed Ru Electrocatalyst", pp.653-661 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H.Yokokava and S.Singhal, The Electrochem. Soc.,Pennington, NJ, 2001.
53. J. Irvine, S. Tao, A. Feighery, T. Mc Colm. "New Mixed Conducting Oxides for SOFC Anodes", pp.738-745 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
54. J. Kilner, S. Skinner, T. Ishihara, K.Otsuka, J. Irvine, T. Mc Colm, Y. Jiang. " Zero Emission Power Generation Using an all Perovskite Fuel Cell", pp.224-233 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc Inc.,Pennington, NJ (USA) 2001.
55. T Kobayashi. "Anode Oxide Materials for SOFCs", RISM publications, Mizusaki Labs 12 (2000).
56. W. Wersing, C. Nölscher, M. Schnöller, R. Männer, H. Schmidt. Siemens AG. "Hochtemperaturbrennstoffzelle mit Verbesserter Festelektrolyt/Elektroden-Grenzflache und Verfahren zur Herstellung der Grenzfläche". DE num. 4314323 Al (17-11-1994).
57. E. Ivers-Tiffee, W. Wersing. Siemens AG. "Hochtemperatur- Festelektrolyt-Brennstoffzelle (SOFC) fur Einen Weiten Betriebstemperaturbereich". DE num. 19836132 Al (24-02-2000).
58. S. Wallin, M. Midland, D. Sunil. The Dow Chemical Co. "Feststoff-Oxidbrennstoffzellenstapel mit Zusammengesetzten Elektroden und Verfahren zur Herstellung Desselben". DE num.19817 510 Al (05-11-1998).
59. T. Cable, J. Frye, W. Kliewer, T. Mazanec The Standart Oil Company. "Electrochemical Reactors and Multicomponent Membranes Useful for Oxidation Reaction". EP num. 0438902 A2 (31-07-1991).
60. M. Mori. "Air- Sintering Characteristics of Ti-Doped Lanthanum Strontium Chromites with B-Site Doping", pp.855-864 in Solid Oxide Fuel Cells VII. vol. 16: 7-th Intern. Symposium on Solid Oxide Fuel Cells (SOFC-VII), EPOCHAL Tsukuba Intern. Congress Centre, Tsukuba (Japan), June 2001. Ed. H. Yokokava, S. Singhal, The Electrochem. Soc. Inc.,Pennington, NJ (USA) 2001.
61. U. Diekmann, H. Rindel. Forshungszentrum Jülich GmbH. "Interkonnektor für SOFC-Brennstoffzellenstapel". DE num.19705874 A1 (27-08.-1998).
62. B. Altken, T. Ketcham, M. Faber, D. St. Julien. Corning Inc. "Solid Electrolyte Fuel Cells". EP num. 0603620 A1 (29-06-1994).
63. Proceedings of 2000 FUEL CELL SEMINAR, Fuel Cells-Powering the 21-st Century. Abstracts- Section A and 6A (SOFCs), pp 546, 767. Portland, Oregon (USA), October 30- November 2, 2000.