Insertion of Ga(DDP) into the Au-Cl bond of (PPh3)AuCl: A first structurally characterized Au-Ga bond

Inorganic Chemistry

Volumn 44, Issue 2, 2005, Pages 163-165

  Kempter, Andreas ^a   Gemel, Christian ^a   Fischer, Roland A ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

2 [(2,6 DIISOPROPYLPHENYL)AMINO 4 [(2,6 DIISOPROPYLPHENYL)IMINO] 2 PENTENE]; GALLIUM; GOLD; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; STRUCTURE ANALYSIS;

EID: 12344272499     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048524d     Document Type: Article

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17. 2).
18. -3, T = 105 K, γ(Mo Kα) = 0.71073 Å, R1 = 0.0362 (I > 2σ(I)), wR2 = 0.0781 (all data). The contribution of a disordered hexane molecule within the asymmetric unit to the structure factors was taken into account by back-Fourier transformation using PLATON/ SQUEEZE. measurements: Oxford Excalibur 2 diffractometer; programs used, SHELXS-97 and SHELXL-97. CCDC-253792 contains the supplementary crystallographic data for this structure. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/ retrieving.html.
19. 6, RT): δ 54.74 (s).
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26. 6, RT): δ 56.40 (s).