The hidden equilibrium in aqueous sodium carbonate solutions - Evidence for the formation of the dicarbonate anion

European Journal of Inorganic Chemistry

Volumn , Issue 1, 2005, Pages 168-172

  Zeller, Klaus Peter ^a   Schuler, Paul ^a   Haiss, Peter ^a  

^a UNIVERSITY OF TÜBINGEN   (Germany)

Author keywords

Dicarbonate anion; Isotopic labeling; NMR spectroscopy; Oxygen transfer

Indexed keywords

CARBON DIOXIDE; CARBONATION; ISOMERS; ISOTOPES; NEGATIVE IONS; OXYGEN; SODIUM BICARBONATE; SODIUM CARBONATE;

CARBONATE ANION; COMBINED ACTIONS; DICARBONATE; DICARBONATE ANION; HYDROGENCARBONATES; ISOTOPIC LABELING; NMR EXPERIMENTS; NMR-SPECTROSCOPY; OXYGEN EXCHANGE; OXYGEN TRANSFER;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

BICARBONATE; CARBON DIOXIDE; CARBONIC ACID; HYDROXIDE; ISOTOPE; OXYGEN 18; SODIUM CARBONATE;

AQUEOUS SOLUTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; EQUILIBRIUM CONSTANT; HYDROLYSIS;

EID: 12344265912     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400445     Document Type: Article

References (26)

1. Gmelin, Handbuch der Anorganischen Chemie, 8th ed., " Kohlenstoff", part C3, 1973, pp. 117-137.
2. T. Loerting, C. Tautermann, R. T. Kroemer, I. Kohl, H. Hallbrucker, E. Mayer, K. R. Liedl, Angew. Chem. 2000, 112, 920-922; Angew. Chem. Int. Ed. 2000, 39, 891-894.
3. T. Loerting, C. Tautermann, R. T. Kroemer, I. Kohl, H. Hallbrucker, E. Mayer, K. R. Liedl, Angew. Chem. 2000, 112, 920-922; Angew. Chem. Int. Ed. 2000, 39, 891-894.
4. R. Ludwig, A. Kornath, Angew. Chem. 2000, 112, 1479-1481; Angew. Chem. Int. Ed. 2000, 39, 1421-1423.
5. R. Ludwig, A. Kornath, Angew. Chem. 2000, 112, 1479-1481; Angew. Chem. Int. Ed. 2000, 39, 1421-1423.
6. G. A. Mills, H. C. Urey, J. Am. Chem. Soc. 1940, 62, 1019-1026.
7. D. J. Poulton, H. W. Baldwin, Can. J. Chem. 1967, 45, 1045-1050.
8. D. M. Himmelblau, A. L. Babb, AIChE J. 1958, 4, 143-152.
9. J. Koefoed, K. Engel, Acta Chem. Scand. 1961, 15, 1319-1326.
10. P. V. Danckwerts, K.-A. Melkersson, Trans. Faraday Soc. 1962, 58, 1832-1838.
11. C. K. Tu, D. N. Silverman, J. Phys. Chem. 1975, 79, 1647-1651.
12. [10a] J. M. Risley, R. L. Van Etten, J. Am. Chem. Soc. 1979, 101, 252-253.
13. [10b] J. M. Risley, R. L. Van Etten, J. Am. Chem. Soc. 1980, 102, 4609-4614.
14. [10c] J. M. Risley, R. L. Van Etten, J. Am. Chem. Soc. 1980, 102, 6699-6702.
15. [10d] J. M. Risley, S. A. DeFrees, R. L. Van Etten, Org. Magn. Reson. 1983, 21, 2835.
16. [10e] T. L. Mega, R. L. Van Etten, J. Am. Chem. Soc. 1993, 115, 12056-12059.
17. R. W. Alder, R. Baker, J. M. Brown, Mechanisms in Organic Chemistry, Wiley-Interscience, London, New York, Sidney, Toronto, 1975, p. 312.
18. P. Claes, D. Moyaux, D. Peeters, Eur. J. Inorg. Chem. 1999, 583-598.
19. D. Peeters, D. Moyaux, P. Claes, Eur. J. Inorg. Chem. 1999, 589-592.
20. Y. Marcus, J. Chem. Soc., Faraday Trans. 1991, 87, 2995-2999.
21. N. Brückl, J. I. Kim, Z. Phys. Chem. (Muenchen, Ger.) 1981, 126, 133-150.
22. C. S. Choi, A. D. Mighell, Acta Crystallogr., Sect. B 1982, 38, 2874-2876.
23. V. Cirpus, A. Arnold, Z. Anorg. Allg. Chem. 1995, 621, 1197-1204.
24. N. G. Fernandez, R. Tellgren, I. Olovsson, Acta Crystallogr., Sect. B 1990, 46, 466-474.
25. U. Kraatz, in Houben-Weyl, Methoden der Organischen Chemie (Ed.: H. Hagemann), Thieme-Verlag Stuttgart, 1983, vol. E4, p. 1000.
26. R. Hutchinson, C. T. Mabuni, J. Labelled Compd. Radiopharm. 1977, 13, 571-574.