Synthesis and characterization of the complexes of pentane-2,4-dione with nickel(II) and cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione)

Molecules

Volumn 9, Issue 11, 2004, Pages 949-956

  Qu, Yang ^a,b   Zhu, Hai Liang ^a,b   You, Zhong Lu ^a,b   Tan, Min Yu ^b  

^a FUYANG NORMAL UNIVERSITY   (China)

^b LANZHOU UNIVERSITY   (China)

Author keywords

Cobalt(III) complex; Crystal structure; Nickel(II) complex; Pentane 2,4 dione

Indexed keywords

ACETYLACETONE; COBALT COMPLEX; HYDROGEN; NICKEL COMPLEX;

ARTICLE; COMPLEX FORMATION; CRYSTALLIZATION; SYNTHESIS; X RAY ANALYSIS;

EID: 12344257116     PISSN: 14203049     EISSN: None     Source Type: Journal    
DOI: 10.3390/91100949     Document Type: Article

References (9)

1. 5Ni(acac): A Monomeric, Paramagnetic, 18-Electron, Spin-Equilibrium Molecule. J. Am. Chem. Soc. 1996, 118, 11119-11128.
2. Silvana, C. N., Kulbinder, K. B., Paul J. T., John T. W. Synthesis and physical and structural characterization of Ag(I) complexes supported by non-fluorinated β-diketonate and related ancillary ligands. Polyhedron 2002, 21, 1289-1297.
3. Zhu, W.G.; Qing, J.; Lu, Z.Y.; Wei, X.Q.; Xie, M.G.; Novel binuclear uropium β-diketone chelate used as red emitter in organic electroluminescent device. Thin Solid Films 2000, 363, 167-169.
4. 2, acac-azain=1-N-7-azaindolyl-1,3- butanedionato. J. Organomet. Chem. 2001, 631, 175-180.
5. Mehrotra, R.C.; Bohra, R.; Gaur, D.P. Metal-Diketonates and Allied Derivatives; Academic Press: New York, 1978.
6. Sievers, R.E., Eisentraut, K.J., Springer Jr., C.S. In Lanthanide/Actinide Chemistry, Gould, R.F. (Ed.); American Chemical Society: Washington, DC, 1967; Chapter 11.
7. Alexander, D. G.., Alexander, P. S., Marina, I. S. Common and less-common coordination modes of the typical chelating and heteroaromatic ligands. Coord. Chem. Rev. 1998, 17331-77.
8. Burgess, J., Fawcett, J., Russell, D. R., Gilani, S. R. Monomeric bis(2,4-pentanedionato)cobalt(II). Acta Cryst. 2000. C56, 649-650.
9. 2O. Acta Cryst. 2001, E57, 506-508.