Bis(1,2,3-trimethylindenyl)iron(III) 2,3-dicyanonaphtho-1,4-quinonide, a non-metallocene, charge-transfer salt metamagnet with complementary donor-acceptor geometries

Inorganic Chemistry

Volumn 44, Issue 2, 2005, Pages 172-174

  Crisp, Jeffrey A ^a   Meredith, M Brett ^a   Hanusa, Timothy P ^a   Wang, Guangbin ^b   Brennessel, William W ^c   Yee, Gordon T ^b  

^a VANDERBILT UNIVERSITY   (United States)

^b VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

^c UNIVERSITY OF MINNESOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIS(1,2,3 TRIMETHYLINDENYL)IRON 2,3 DICYANONAPHTHO 1,4 QUINONIDE; IRON SALT; QUINONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CRYSTAL STRUCTURE; GEOMETRY; MAGNETISM; MOLECULAR INTERACTION; X RAY CRYSTALLOGRAPHY;

EID: 12344253640     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048398d     Document Type: Article

References (13)

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7. c was reported.
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9. (a) Yee, G. T.; Whitton, M. J.; Sommer, R. D.; Frommen, C. M.; Reiff, W. M. Inorg. Chem. 2000, 39, 1874-1877.
10. (b) Hamlin, J. J.; Beckett, B. R.; Tomita, T.; Schilling, J. S.; Tyree, W. S.; Yee, G. T. Polyhedron 2003, 22, 2249-2252.
11. 2) = 0.117 (for I > 2.0σ(I)).
12. Metamagnetism is characterized by antiferromagnetic order in zero applied field that gives way to a ferromagnet-like state upon the application of a sufficiently high magnetic field.
13. -4 emu/mol as determined by a fit to the Curie-Weiss law.