Applications of composition control to the styrene-butyl acrylate emulsion copolymerization

Chemical Engineering Communications

Volumn 163, Issue , 1998, Pages 69-95

  Galimberti, Francesca ^a   Siani, André ^a   Morbidelli, Massimo ^a   Storti, Giuseppe ^b  

^a POLITECNICO DI MILANO   (Italy)

^b UNIVERSITY OF CAGLIARI   (Italy)

Author keywords

Composition control; Emulsion polymerization; Latex reactors; Styrene butyl acrylate

Indexed keywords

EID: 11744271510     PISSN: 00986445     EISSN: None     Source Type: Journal    
DOI: 10.1080/00986449808912345     Document Type: Article

References (20)

1. Arzamendi, G. and Asua, J. M. (1989) Monomer Addition Policies for Copolymer Composition Control in Semicontinuous Emulsion Copolymerization, J. Applied Polym. Sci., 38, 2019.
2. Arzamendi, G. and Asua, J. M. (1991) Copolymer Composition Control of Emulsion Copolymers in Reactors with Limited Capacity for Heat Removal, Ind. Eng. Chem. Res., 30, 1342.
3. Brandrup, J. and Immergut, E. H. (1989) "Polymer Handbook", 3rd ed., J. Wiley and Sons, New York.
4. Canegallo, S., Storti, G., Morbidelli, M. and Carra, S. (1993) Densimetry for On-line Conversion Monitoring in Emulsion Homo- and Copolymerization, J. Applied Polym. Sci., 47, 961.
5. Canegallo, S., Canu, P., Morbidelli, M. and Storti, G. (1994) Composition Control in Emulsion Copolymerization. II. Application to Binary and Ternary Systems, J. Applied Polym. Sci., 54, 1919.
6. Canegallo, S., Apostolo, M., Storti, G. and Morbidelli, M. (1995) On-line Conversion Monitoring through Ultrasound Propagation Velocity Measurements in Emulsion Polymerization, J. Applied Polym. Sci., 57, 1333.
7. Canu, P., Canegallo, S., Storti, G. and Morbidelli, M. (1994) J. Applied Polym. Sci., 54, 1899.
8. Chujo, K., Harada, Y., Tokuhara, S. and Tanaka, K. (1969) The effects of various Monomer Addition Methods on the Emulsion Copolymerization of Vinyl Acetate and Butyl Acrylate, J. Polym. Sci., Part C, 27, 321.
9. Dimitratos, J., Georgakis, C, El-Asser, M. S. and Klein, A. (1989) Control of Product Composition in Emulsion Polymerization, in "Polymer Reaction Engineering", K.-H. Reichert and W. Geiseler, (Eds.) VCH Verlag, p.33.
10. Gardon, J. L. (1968) Emulsion Polymerization. VI. Concentration of Monomers in Latex Particles, J. Polym. Sci., 6, 2859.
11. Guillot, J. (1986) Computer Simulation of Emulsion Copolymerization Processes for Monomer of Different Water Solubility, in "Polymer Reaction Engineering", K.-H. Reichert and W. Geiseler, (Eds.) Huthig and Wepf, p.147.
12. Guillot, J, and Guerrero, L. (1982) Terpolymerisation acrylonitrile/styrene/acrylate de methyle, 3a) Elude du mechanisme de la copolymerisation en emulsion, Makromol. Chem., 183, 1979.
13. Mayo, F. R. and Lewis, F. M. (1944) Copolymerization. I. A Basis for comparing the Behavior of Monomers in Copolymerization; the Copolymerization of Styrene and Butyl Acrylate, J. Am. Chem. Soc., 66, 1594.
14. Moritz, H.-U. (1989) Polymerization Calorimetry. A Powerful Tool for Reactor Control, in "Polymer Reaction Engineering", K.-H. Reichert and W. Geiseler, (Eds,) VCH Verlag, p. 248.
15. Noël, L. F. J., Van Zon, J. A. M. and German, A. (1994). Monomer-to-Water Ratios as a Tool in Controlling Emulsion Copolymer Composition: the Methyl Acrylate-Indene System, J. Applied Polym. Sci., 51, 2073.
16. Schork, F. J. (1994) Reactor Operation and Control, in "Polymer Reaction Engineering", C. McGreavy, (Ed.) VCH, NY, p. 148.
17. Schork, F. J. and Ray, W. H. (1981) On-line Monitoring of Emulsion Polymerization Dynamics, in "Emulsion Polymer and Emulsion Polymerization", D. R. Basset and A. E. Hamielec, (Eds.) ACS, Washington, p.505.
18. Siani, A., Apostolo, M., Morbidelli, M. and Storti, G. (1995) On-line Monitoring of Emulsion Polymerization Reactors through Ultrasonic Velocity Measurements, in "5-th International Workshop on Polymer Reaction Engineering", Dechema, VCH, 131, p.149.
19. Snuparek, J. and Krska, F. (1977) Semicontinuous Emulsion Copolymerization of Acrylonitrile, Butyl Acrylate, and Styrene, J. Applied Polym. Sci., 21, 2253.
20. Van Doremaele, G. H. J., Schoonbrood, H. A. S., Kurja, J. and German, A. L. (1992) Copolymer Control by Means of Semicontinuous Emulsion Copolymerization, J. Applied Polym. Sci., 45, 957.