Inclusion compounds of hyocholic acid with specific alcohols

Supramolecular Chemistry

Volumn 10, Issue 2, 1998, Pages 107-109

  Miyake, Yasuhito ^a   Sada, Kazuki ^a   Miyata, Mikiji ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Butanol; Hyocholic acid; Inclusion compounds

Indexed keywords

EID: 11644311825     PISSN: 10610278     EISSN: None     Source Type: Journal    
DOI: 10.1080/10610279808055401     Document Type: Article

References (4)

1. Haslewood, G. A. D. (1956). Biochem. J., 62, 637.
2. Ziegler, P. (1956). Can. J. Chem., 34, 523.
3. Miyata, M. and Sada, K. (1996). In: Comprehensive Supramolecular Chemistry, MacNicol, D. D., Toda, F. and Bishop, R. (Eds.), Pergamon, Vol. 6, Chap. 6, p. 147.
4. -3. Intensity data were collected on Rigaku AFC-7R diffractometer with graphite-monochromated Mo-Kα radiation for a and Rigaku RAXIS-IV diffractometer with graphite-monochromated Mo-Kα radiation for b and c. 2934, 4195 and 7646 reflections for the crystals a, b and c were unique. 1586, 3306 and 4562 observed reflection with |Fo|>3σ(|Fo|) were used for further calculations after Lorenz and polarization corrections. The structure was solved by direct methods (SHLEX86 for a, SIR92 for b and SnB for c) and refined against the Fo data by full-matrix least-squares methods. All non-hydrogen atoms were refined anisotropically. Hydrogen atoms attached to carbon were placed in calculated position while O-H positions were obtained from difference Fourier synthesis. The final R values are 0.047, 0.043 and 0.045 respectively. All calculations were performed using the TEXSAN crystallographic software package of the Molecular Structure Corporation. Atomic coordinations, bond length and angles, and thermal parameters have been deposited at the Cambridge Crystallographic Data Centre.