Metallacycle transfer reaction from titanacyclopropenes: A new and versatile approach to phosphirenes

Organometallics

Volumn 17, Issue 13, 1998, Pages 2677-2679

  Mézailles, Nicolas ^a   Avarvari, Narcis ^a   Bourissou, Didier ^a   Mathey, François ^a   Le Floch, Pascal ^a  

^a ECOLE POLYTECHNIQUE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 11644297597     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980244g     Document Type: Article

References (55)

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12. When this work was already completed, an independent study describing the synthesis of some phosphirenes and phosphiranes from dichlorophosphanes and intramolecularly P=O stabilized zirconacyclopropenes and zirconacyclopropanes was brought to our attention by J. P. Majorai. Zablocka, M.; Miguel, Y.; Igau, A.; Majorai, J.-P.; Skowroriska, A. Chem. Commun., in press.
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43. 2 is syringed in. The mixture is warmed back to room temperature and stirred for an additional 1 h. The mixture is taken to dryness and the phosphirene extracted with hexanes.
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55. -3 mol) is then added and the mixture brought back to room temperature. After 1 h, the mixture is filtered and the solution reduced to dryness in vacuo. 1-Phenylphosphirenes are purified by fast column chromatography using hexane as eluant. 1-isopropoxyphosphirene (12) was distilled under vacuum using a bulb-to bulb apparatus.