Selective oxidation of thioether mustard (HD) analogs by tert-butylhydroperoxide catalyzed by H5PV2Mo10O40 supported on porous carbon materials

Journal of Catalysis

Volumn 159, Issue 2, 1996, Pages 473-478

  Gall, Robin Damico ^a   Hill, Craig L ^a   Walker, John E ^a,b  

^a EMORY UNIVERSITY   (United States)

^b US Army Natick RD and E Center   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 11544280408     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1006/jcat.1996.0111     Document Type: Article

References (25)

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21. The turnover numbers reported in Table 1 assume the number of active sites to be equal to the moles of polyoxometalate. However, some of the immobilized polyoxometalate molecules may not be accessible for catalysis. Therefore, the turnover numbers reported represent the minimum number of turnovers per mole of polyoxometalate. For a good recent discussion of the difficulties encountered when trying to do kinetics on a heterogeneous system, including the determination of active sites and calculating the turnover number, see Boudart, M., Chem. Rev. 95, 661 (1995).
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