Origin of amphibole megacrysts in the Pliocene-Pleistocene basalts of the Carpathian-Pannonian region

Geologica Carpathica

Volumn 56, Issue 2, 2005, Pages 179-189

  Demény, Attila ^a   Vennemann, Torsten W ^b   Homonnay, Zoltán ^c   Milton, Andy ^d   Embey Isztin, Antal ^e   Nagy, Géza ^a  

^a INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^b UNIVERSITY OF LAUSANNE   (Switzerland)

^c EÖTVÖS LORÁND UNIVERSITY   (Hungary)

^d NATIONAL OCEANOGRAPHY CENTRE   (United Kingdom)

^e DEPARTMENT OF ZOOLOGY   (Hungary)

Author keywords

Amphibole megacrysts; Carpathian Pannonian region; Degassing; Mantle metasomatism; Stable isotopes; Trace elements

Indexed keywords

AMPHIBOLE; BASALT; METASOMATISM;

CARPATHIAN BASIN; EASTERN HEMISPHERE; EURASIA; EUROPE; PANNONIAN BASIN; WORLD;

EID: 11444268261     PISSN: 13350552     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (77)

1. Anders E. & Grevesse N. 1989: Abundances of the elements - meteoritic and solar. Geochim. Cosmochim. Acta 53, 197-214.
2. Beattie P. 1994: Systematics and energetics of trace-element partitioning between olivine and silicate melts: Implications for the nature of mineral/melt partitioning. Chem. Geol. 117, 57-71.
3. Boettcher A.L. & O'Neil J.R. 1980: Stable isotope, chemical, and petrographic studies of high-pressure amphiboles and micas: evidence for metasomatism in the mantle source regions of alkali basalts and kimberlites. Amer. J. Sci. 280-A, 594-621.
4. Burkhard D.J.M. & O'Neil J.R. 1988: Contrasting serpentinization processes in the eastern Central Alps. Contrib. Mineral. Petrology 99, 498-506.
5. Chazot G., Lowry D., Menzies M. & Mattey D. 1997: Oxygen isotopic composition of hydrous and anhydrous mantle peridotites. Geochim. Cosmochim. Acta 61, 161-169.
6. Clayton R.N. & Mayeda T.K. 1963: The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis. Geochim. Cosmochim. Acta 27, 43-52.
7. Demény A. 1995: H isotope fractionation due to hydrogen-zinc reactions and its implications on D/H analysis of water samples. Chem. Geol. 121, 19-25.
8. Demény A., Sharp Z.D. & Pfeifer H.-R. 1997: Mg-metasomatism and formation conditions of Mg-chlorite-muscovite-quartz-phyllites (leucophyllites) of the Eastern Alps (W. Hungary) and their relations to Alpine whiteschists. Contrib. Mineral. Petrology 128, 247-260.
9. Demény A., Vennemann T.W. & Homonnay Z. 2001: H isotope compositions and oxidation state of mantle-derived hydrous minerals. J. Conference Abstracts 6, 462-463.
10. Demény A., Vennemann T.W., Hegner E., Nagy G., Milton J.A., Embey-Isztin A., Homonnay Z. & Dobosi G. 2004: Trace element and C-O-Sr-Nd isotope evidence for subduction-related carbonate-silicate melts in mantle xenoliths (Pannonian Basin, Hungary). Lithos 75, 1-2, 89-113.
11. Dobosi G., Fodor R.V. & Goldberg S.A. 1995: Late-Cenozoic alkalic basalt magmatism in the northern Pannonian basin, eastern Europe: petrology, source compositions, and relationship to tectonics. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 199-207.
12. Dobosi G., Downes H., Mattey D. & Embey-Isztin A. 1998: Oxygen isotope ratios of phenocrysts from alkali basalts of the Pannonian basin: Evidence for an O-isotopically homogeneous upper mantle beneath a subduction-influenced area. Lithos 42, 213-223.
13. Dobosi G., Downes H., Embey-Isztin A. & Jenner G.A. 2003a: Origin of megacrysts and pyroxenite xenoliths from the Pliocene alkali basalts of the Pannonian Basin (Hungary). Neu. Jb. Mineral. Abh. 178, 217-237.
14. Dobosi G., Kempton P., Downes H., Embey-Isztin A., Thirlwall M. & Greenwood P. 2003b: Lower crustal granulite xenoliths from the Pannonian Basin, Hungary. Part II: Sr-Nd-Pb-Hf and O isotope evidence for formation of continental lower crust by tectonic emplacement of oceanic crust. Contrib. Mineral. Petrology 144, 671-683.
15. Downes H. & Vaselli O. 1995: The lithospheric mantle beneath the Carpathian-Pannonian Region: a review of trace element and isotopic evidence from ultramafic xenoliths. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 219-229.
16. Downes H., Embey-Isztin A. & Thirlwall M.F. 1992: Petrology and geochemistry of spinell peridotite xenoliths from the western Pannonian Basin (Hungary): evidence for an association between enrichment and texture in the upper mantle. Contrib. Mineral. Petrology 109, 340-354.
17. Downes H., Seghedi I., Szakács A., Dobosi G., James D.E., Vaselli O., Rigby I.J., Ingram G.A., Rex D. & Pécskay Z. 1995: Petrology and geochemistry of late Tertiary/Quaternary mafic alkaline volcanism in Romania. Lithos 35, 65-81.
18. + and D/H in kaersutites - Misleading indicators of mantle source fugacities. Geology 20, 565-568.
19. + in mantle kaersutite: Implications for mantle metasomatism. Amer. Mineralogist 78, 968-979.
20. Eiler J.M. 2001: Oxygen isotope variations of basaltic lavas and upper mantle rocks. In: Valley J.W. & Cole D. (Eds.): Stable isotope geochemistry. Rev. in Mineralogy 43, 319-364.
21. Embey-Isztin A. 1976: Amphibolite/lherzolite composite xenolith from Szigliget, north of the Lake Balaton, Hungary. Earth Planet. Sci. Lett. 31, 297-304.
22. Embey-Isztin A. & Dobosi G. 1995: Mantle source characteristics for Miocene-Pleistocene alkali basalts, Carpathian-Pannonian Region: a review of trace elements and isotopic composition. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 155-166.
23. Embey-Isztin A. & Scharbert H.G. 1981: Bericht über geochemisch-petrographische Untersuchungen an Basalten vom Kovácsihegy und Uzsa, Tátika Gruppe, Ungarn. Anz. Österr. Akad. Wiss., Math.-Naturwiss. Kl. 118, 1-6.
24. Embey-Isztin A., Scharbert H.G., Dietrich H. & Poultidis H. 1990: Mafic granulite and clinopyroxenite xenoliths from the Transdanubian Volcanic Region, Hungary: implications for the deep structure of the Pannonian Basin. Mineral. Mag. 54, 463-483.
25. Embey-Isztin A., Downes H., James D.E., Upton B.G.J., Dobosi G., Ingram G.A., Harmon R.S. & Scharbert H.G. 1993a: The petrogenesis of Pliocene alkaline volcanic rocks from the Pannonian Basin, Eastern central Europe. J. Petrology 34, 317-343.
26. Embey-Isztin A., Dobosi G., James D.E., Downes H., Poultidis H. & Scharbert H.G. 1993b: A compilation of new major, trace element and isotope geochemical analyses of the young alkali basalts from the Pannonian Basin. Fragm. Mineral. Palaeont. 16, 5-26.
27. 2O contents and D/H ratios of phlogopite and biotite from lavas of different tectonic regimes. Contrib. Mineral. Petrology 126, 51-66.
28. Früh-Green G., Weissert H. & Bernoulli D. 1990: A multiple fluid history recorded in Alpine ophiolites. J. Geol. Soc., London 147, 959-970.
29. Graham C.M., Harmon R.S. & Sheppard S.M.F. 1984: Experimental hydrogen isotope studies: hydrogen exchange between amphibole and water. Amer. Mineralogist 69, 128-138.
30. Harangi Sz., Vaselli O., Tonarini S., Szabó Cs., Harangi R. & Coradossi N. 1995: Petrogenesis of Neogene extension-related alkaline volcanic rocks of the Little Hungarian Plain Volcanic Field, Western Hungary. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 173-187.
31. Hoefs J. 1987: Stable isotope geochemistry. Springer-Verlag, Berlin, 1-241.
32. Hofmann A.W. 1988: Chemical differentiation of the Earth: the relationship between mantle continental crust, and oceanic crust. Earth Planet. Sci. Lett. 90, 297-314.
33. Horn I., Foley S.F., Jackson S.E. & Jenner G.A. 1994: Experimentally determined partitioning of high field strength- and selected transition elements between spinel and basaltic melt. Chem. Geol. 117, 193-218.
34. Horváth F. 1993: Towards a mechanical model for the formation of the Pannonian Basin. Tectonophysics 226, 333-357.
35. 2 conditions and two-liquid elemental partitioning. Contrib. Mineral. Petrology 133, 12-29.
36. Huraiová M., Konečný P., Konečný V., Simon K & Hurai V. 1996: Mafic and salic igneous xenoliths in Late Tertiary alkaline basalts: Fluid inclusion and mineralogical evidence for a deep-crustal magmatic reservoir in the Western Carpathians. Eur. J. Mineral. 8, 901-916.
37. Ionov D.A. & Hofmann A.W. 1995: Nb-Ta-rich mantle amphiboles and micas - Implications for subduction-related metasomatic trace-element fractionations. Earth Planet. Sci. Lett. 131, 341-356.
38. Javoy M. 1998: The birth of the Earth' atmosphere: the behaviour and fate of its major elements. Chem. Geol. 147, 11-25.
39. Johnson K.E., Davis A.M. & Bryndzia L.T. 1996: Contrasting styles of hydrous metasomatism in the upper mantle: An ion microprobe investigation. Geochim. Cosmochim. Acta 60, 1367-1385.
40. Kasemann S., Meixner A., Rocholl A., Vennemann T., Schmitt A. & Wiedenbeck M. 2001: Boron and oxygen isotope composition of certified reference materials NIST SRM 610/612, and reference materials JB-2G and JR-2G. Geostandards Newsletter 25, 405-416.
41. Kempton P.D., Downes H. & Embey-Isztin A. 1997: Mafic granulite xenoliths in Neogene alkali basalts from the Western Pannonian Basin: Insights into the lower crust of a collapsed orogen. J. Petrology 38, 941-970.
42. King P.L., Hervig R.L., Holloway J.R., Vennemann T.W. & Righter K. 1999: Oxy-substitution and dehydrogenation in mantle-derived amphibole megacrysts. Geochim. Cosmochim. Acta 63, 3635-3651.
43. Konečný V., Lexa L., Balogh K. & Konečný P. 1995a: Alkali basalt volcanism in Southern Slovakia: volcanic forms and time evolution. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 167-171.
44. Konečný P., Konečný V., Lexa L. & Huraiová M. 1995b: Mantle xenoliths in alkali basalts of Southern Slovakia. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 241-247.
45. Kurat G., Embey-Isztin A., Karcher A. & Scharbert H.G. 1991: The upper mantle beneath Kapfenstein and the Transdanubian Volcanic Region, E Austria and W Hungary: a comparison. Miner. Petrology 44, 21-38.
46. Kyser T.K. & O'Neil J.R. 1984: Hydrogen isotope systematics of submarine basalts. Geochim. Cosmochim. Acta 48, 2123-2133.
47. Leake B.E., Woolley A.R., Arps C.E.S., Birch W.D., Gilbert M.C., Grice J.D., Hawthorne F.C., Kato A., Kisch H.J., Krivovichev V.G., Linthout K., Laird J., Mandarino J.A., Maresch W.V., Nickel E.H., Rock N.M.S., Schumacher J.C., Smith D.C., Stephenson N.C.N., Ungaretti L., Whittaker E.J.W. & Youzhi G. 1997: Nomenclature of amphiboles: Report of the subcommittee on amphiboles of the International Mineralogical Association, Commission on new minerals and mineral names. Canad. Mineralogist 35, 219-246.
48. Mattey D., Lowry D. & MacPherson C. 1994: Oxygen isotope composition of mantle peridotite. Earth Planet. Sci. Lett. 128, 231-241.
49. Morrison J. 1991: Compositional constraints on the incorporation of Cl into amphiboles. Amer. Mineralogist 76, 1920-1930.
50. Ti values in petrogenetic studies. Amer. Mineralogist 85, 407-419.
51. Pearce N.J.G., Perkins W.T., Westgate J.A., Gorton M.P., Jackson S.E., Neal C.R. & Chenery S.P. 1997: A compilation of new and published major and trace element data for NIST SRM 610 and NIST SRM 612 glass reference materials. Geostandard Newsletter 21, 115-144.
52. Pécskay Z., Lexa J., Szakács A., Balogh Kad., Seghedi I., Konečný V., Kovács M., Márton E., Kaličiak M., Széky-Fux V., Póka T., Gyarmati P., Edelstein O., Rosu E. & Žec B. 1995: Space and time distribution of Neogene-Quaternary volcanism in the Carpatho-Pannonian Region. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 15-28.
53. Rosenbaum J.M., Wilson M. & Downes H. 1997: Multiple enrichment of the Carpathian-Pannonian mantle: Pb-Sr-Nd isotope and trace element constraints. J. Geophys. Res. 102, 14947-14961.
54. Rumble III. D. & Hoering T.C. 1994: Analysis of oxygen and sulfur isotope ratios in oxide and sulfide minerals by spot heating with a carbon dioxide laser in a fluorine atmosphrere. Accounts of Chem. Res. 27, 237-241.
55. Salters V.J.M., Hart S.R. & Pantó Gy. 1988: Origin of late Cenozoic volcanic rocks of the Carpathian Arc, Hungary. In: Royden L.H. & Horváth F. (Eds.): The Pannonian Basin. Amer. Assoc. Petrol. Geol. Memoir 45, 279-292.
56. Scambelluri M., Müntener O., Hermann J., Piccarrdo G.B. & Trommsdorff V. 1995: Subduction of water into the mantle: History of an Alpine peridotite. Geology 23, 459-462.
57. Scambelluri M., Piccardo G.B., Philippot P., Robbiano A. & Negretti L. 1997: High salinity fluid inclusions formed from recyled seawater in deeply subducted alpine serpentinite. Earth Planet. Sci. Lett. 148, 485-499.
58. Schumacher J.C. 1997: The estimation of ferric iron in electron microprobe analysis of amphiboles: Appendix to the nomenclature of amphiboles. Canad. Mineralogist 35, 238-246.
59. Seghedi I., Downes H., Szakács A., Mason P.R.D., Thirlwall M.F., Roşsu E., Pécskay Z., Márton E. & Panaiotu C. 2004: Neogene-Quaternary magmatism and geodynamics in the Carpathian-Pannonian region: a synthesis. Lithos 72, 117-146.
60. Sharp Z.D. 1990: A laser-based microanalytical method for the in situ determination of oxygen isotope ratios of silicates and oxides. Geochim. Cosmochim. Acta 54, 1353-1357.
61. Stakes D.S. & O'Neil J.R. 1982: Mineralogy and stable isotope geochemistry of hydrothermally altered oceanic rocks. Earth Planet. Sci. Lett. 57, 285-304.
62. Suzuoki T. & Epstein S. 1976: Hydrogen isotope fractionation between OH-bearing minerals and water. Geochim. Cosmochim. Acta 40, 1229-1240.
63. Szabó Cs. & Taylor L.A. 1994: Mantle petrology and geochemistry beneath the Nógrád-Gömör Volcanic Field, Carpathian-Pannonian Region. Int. Geol. Rev. 36, 328-358.
64. Szabó Cs., Harangi Sz. & Csontos L. 1992: Review of Neogene and Quaternary volcanism of the Carpathian-Pannonian region. Tectonophysics 208, 243-256.
65. Szabó Cs., Harangi Sz., Vaselli O. & Downes H. 1995a: Temperature and oxygen fugacity in peridotite xenoliths from the Carpathian-Pannonian Region. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 231-239.
66. Szabó Cs., Vaselli O., Vannucci R., Bottazzi P., Ottolini L., Coradossi N & Kubovics I. 1995b: Ultramafic xenoliths from the Little Hungarian Plain (Western Hungary): a petrologic and geochemical study. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 249-263.
67. Szabó Cs., Bodnár R.J. & Sobolev A.V. 1996: Metasomatism associated with subduction-related, volatile-rich silicate melt in the upper mantle beneath the Nógrád-Gömör Volcanic field, Northern Hungary /Southern Slovakia: evidence for silicate melt inclusions. Eur. J. Mineral. 8, 881-899.
68. Tiepolo M., Vannucci R., Oberti R., Foley S., Bottazzi P. & Zanetti A. 2000: Nb and Ta incorporation and fractionation in titanian pargasite and kaersutite: crystal-chemical constraints and implications for natural systems. Earth Planet. Sci. Lett. 176, 185-201.
69. Török K. & De Vivo B. 1995: Fluid inclusions in upper mantle xenoliths from the Balaton Highland, Western Hungary. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 277-284.
70. Valley J.W., Kitchen N., Kohn M.J., Niendorf C.R. & Spicuzza M.J. 1995: UWG-2, a garnet standard for oxygen isotope ratios: Strategies for high precision and accuracy with laser heating. Geochim. Cosmochim. Acta 59, 5223-5231.
71. Vennemann T.W. & O'Neil J.R. 1993: A simple and inexpensive method of hydrogen isotope and water analyses of minerals and rocks based on zinc reagent. Chem. Geol. (Isot. Geosci. Sect.) 103, 227-234.
72. Vennemann T.W. & O'Neil J.R. 1996: Hydrogen isotope exchange reactions between hydrous minerals and molecular hydrogen: I. A new approach for the determination of hydrogen isotope fractionation at moderate temperatures. Geochim. Cosmochim. Acta 60, 2437-2451.
73. Wenner D.B. & Taylor H.P. 1973: Oxygen and hydrogen isotopic studies of the serpentinization of the ultramafic rocks in oceanic environments and continental ophiolitic complexes. Amer. J. Sci. 273, 207-239.
74. Witt-Eikschen G. & Harte B. 1994: Distribution of trace elements between amphibole and clinopyroxene from mantle peridotites of the Eifel (western Germany): An ion-microprobe study. Chem. Geol. 117, 235-250.
75. Yui T.-F. & Jeng R.-C. 1990: A stable-isotope study of the hydrothermal alteration of the East Taiwan Ophiolite. Chem. Geol. 89, 65-85.
76. Zanetti A., Vannucci R., Oberti R. & Dobosi G. 1995: Trace-element composition and crystal-chemistry of mantle amphiboles from the Carpatho-Pannonian Region. In: Downes H. & Vaselli O. (Eds.): Neogene and related magmatism in the Carpatho-Pannonian Region. Acta Vulcanol. 7, 265-276.
77. Zheng Y.-F. 1993: Calculation of oxygen isotope fractionation in hydroxil-bearing silicates. Earth Planet. Sci. Lett. 120, 247-263.