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note
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All of the solutions were irradiated with a 140 W high-pressure mercury lamp (λ = 365 nm) for 5 min or with a 200 W tungsten lamp (λ > 460 nm) for 5 min.
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35
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1142272587
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note
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Obviously, this complex system has different isomers (not shown in Scheme 2) with respect to each of the different forms. For example, form 1a probably has two isomers: one with only one ring-open spiropyran or another with two ring-open spiropyrans. Since changes of the fluorescence intensity are the overall result of ultraviolet light, ferric ions, and protons, we can simplify them to the extreme states (see Scheme 2) in order to interpret the mechanisms clearly.
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