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18
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85033039072
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note
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At high pressures the adsorption probability is still low but the attempt frequency (based on the impingement flux) is orders of magnitude higher. Their product leads to an observable adsorption rate.
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19
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0000886971
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85033057875
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note
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16 also decreases in response to the reduced thermal diffusion rate, e.g., in the limit of zero thermal diffusion into the subsurface, the chemisorption probability must go to zero at the saturation surface oxygen coverage.
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29
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21344498020
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85033060743
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note
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-1 in Fig. 6(a).
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33
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26844478413
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Ph.D. thesis, University of Oxford
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P. Tavemer, Ph.D. thesis, University of Oxford, 1985.
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37049119276
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36
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85033070578
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The O to Ru ratio determined by AES is found to be lower than the actual oxide stoichiometry in the surface region (Ref. 12)
-
The O to Ru ratio determined by AES is found to be lower than the actual oxide stoichiometry in the surface region (Ref. 12).
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37
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85033067417
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note
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37In the limit of infinite surface temperature, the difference in energies between the subsurface and surface states becomes irrelevant, i.e., the Boltzmann factor in the diffusion probability is unity, and entropy effects, which favor the occupation of the subsurface state, become dominant.
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