Progress in the study of the mechanism and kinetics of synthesis of methanol and DME from syngas

Petrochemical Technology

Volumn 33, Issue 6, 2004, Pages 497-507

  Xiao, Wende ^a   Teng, Lihua ^a   Lu, Wenzhi ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Dehydration; Dimethyl ether; Dynamics; Methanol; Reaction mechanism; Syngas; Synthesis

Indexed keywords

EID: 11244347866     PISSN: 10008144     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (48)

1. Fujimoto K, Asami K, Shikada T, et al. Selective Synthesis of Dimethyl Ether from Synthesis Gas. Chem Lett, 1984, 12:2 051-2 054.
2. 2 Catalyst. J Catal, 1993, 144:414-424.
3. 3 Catalysts: Influence of Carbon Monoxide Pretreatment on the Formation and Concentration of Formate Species. Appl Catal, 1990, 59(1):165-184.
4. Agny R M, Takoudis C G. Synthesis of Methanol from Carbon Monoxide and Hydrogen over a Copper-Zinc Oxide-Alumina Catalyst. Ind Eng Chem Prod Res Dev, 1985, 24:50-55.
5. Kazanskii V B. Reaction Mechanism in the Synthesis of Methanol over Low-Temperature Zinc Copper Oxide Catalysts. Kinet Katal, 1986, 27(2):489-492.
6. 2 Feed Stream Composition. J Mol Catal, 1989, 50:343-353.
7. Fujita S I, Usui M, Ito H, et al. Mechanisms of Methanol Synthesis from Carbon Dioxide and from Carbon Monoxide at Atmospheric Pressure over Cu/ZnO. J Catal, 1995, 157:403-413.
8. Chinchen G C, Spencer M S, Waugh K C, et al. Promotion of Methanol Synthesis and the Water - Gas Shift Reactions by Adsorbed Oxygen on Supported Copper Catalysts. J Chem Soc, Faraday Trans 1, 1987, 83(7):2 193-2 212.
9. Kagan Y B, Rozovskii A Y, Bashkirov A N, et al. Mechanism of Methanol Synthesis from Carbon and Hydrogen Oxides. In: Shopov D, Andreev A, Palazov A, eds. Geterogennyi Katal, Tr Mezhdunar Simp, 3rd, Bulg: Sofia (Russian), 1978.282-288.
10. th International Congress on Catalysis, Berlin: Weinheim, Fed Rep Ger, 1985.2:II 47-II 58.
11. 14C - Labelled Reactants. Appl Catal, 1987, 30:333-338.
12. Chinchen G C, Mansfield K, Spenser M S. The Methanol Synthesis: How Does it Work?. CHEMTECH, 1990, 20(11):692-699.
13. Bowker M, Houghton H, Waugh K C. Mechanism and Kinetics of Methanol Synthesis on Zinc Oxide. J Chem Soc, Faraday Trans 1, 1981, 77(12):3 023-3 036.
14. 3 Catalyst. Appl Catal A, 1998, 171:301-308.
15. Amenomiya Y. Methanol Synthesis from Carbon Dioxide + Hydrogen II. Copper-Based Binary and Ternary Catalysts. Appl Catal, 1987, 30(1):57-68.
16. Denise B, Sneeden R P A. Hydrocondensation of Carbon Dioxide IV. J Mol Catal, 1982, 17(2-3):359-366.
17. th International Congress on Catalysis, Berlin: Weinheim, Fed Rep Ger, 1985.2:II 557-II 567.
18. Ramaroson E, Kieffer R, Kiennemann A. Reactions of Carbon Monoxide-Hydrogen and Carbon Dioxide-Hydrogen on Copper-Zinc Catalysts Promoted by Metal Oxides of Groups III and IV. Appl Catal, 1982, 4(3):281-286.
19. Neophytides S G, Marchi A J, Froment G F. Methanol Synthesis by Means of Diffuse Reflectance Infrared Fourier Transform and Temperature - Programmed Reaction Spectroscopy. Appl Catal A, 1992, 86:45-64.
20. 4 Catalysts. J Mol Catal A, 1998, 132:91-100.
21. Klier K, Chatikavanij V, Herman R G, et al, Catalytic Synthesis of Methanol from Carbon Monoxide/Hydrogen IV: The Effects of Carbon Dioxide. J Catal, 1982, 74(2):343-360.
22. 2 in Methanol Synthesis on Cu - Zn oxide: An Isotope Labeling Study. J Catal, 1985, 96:251-260.
23. Graaf G H, Stamhuis E J, Beenachers A A C M. Kinetics of Low - Pressure Methanol Synthesis. Chem Eng Sci, 1988, 43(12):3 185-3 195.
24. Malinovskaya O A, Rozovskii A Y, Zdotarskii I A, et al. Synthesis of Methanol on Copper - Based Catalyst: Kinetic Model. React Kinet Catal Lett, 1987, 34(1):87-92.
25. Dybkjaer I B. Design of Ammonia and Methanol Synthesis Reactors. Chem React Des Technol, 1986, 110:795-819.
26. Skrzypek J, Lachowska M, Moroz H. Kinetics of Methanol Synthesis over Commercial Copper/Zinc Oxide/Alumina Catalysts. Chem Eng Sci, 1991, 46(11):2 809-2 815.
27. 3 Catalyst. J Catal, 1996, 161:1-10.
28. Padmanabhan V R, Eastburn F J. Mechamism of Ether Formation from Alcohols over Alumina Catalyst. J Catal, 1972, 24:88-91.
29. Blaszkowski S R, Santen R A. Theoretical Study of the Mechanism of Surface Methoxy and Dimethyl Ether Formation from Methanol Catalyzed by Zeolitic Protons. J Phys Chem B, 1997, 101(13):2 292-2 305.
30. Kaeding W W, Butter S A. Production of Chemicals from Methanol I. Low-Molecular Weight Olefins. J Catal, 1980, 61(1):155-164.
31. 3OD. J Phy Chem, 1968, 72(8):2 770-2 774.
32. Rinaldo S S, Robert P M. A Mechanistic Study of the Methanol Dehydration Reaction on γ-Alumina Catalyst. J Phys Chem, 1993, 97:6 425-6 435.
33. Lin Y M, Wang Y K. A Kinetic Study of Dehydration of Methanol to Dimethyl Ether over Solid Acid - Base Catalysts. J Chin Inst Chem Eng, 1981, 12:173-182.
34. Highfield J G, Moffat J B. Elucidation of the Mechanism of Dehydration of Methanol over 12 - Tungstophosphoric Acid Using Infrared Photoacoustic Spectroscopy. J Catal, 1985, 95(1):108-119.
35. Ng K L, Chadwick D, Toseland B A. Kinetics and Modeling of Dimethyl Ether Synthesis from Synthesis Gas. Chem Eng Sci, 1999, 54:3 587-3 592.
36. Bercic G, Levec J. Intrinsic and Global Reaction Rate of Methanol Dehydration over γ-Alumina Pellets. Ind Eng Chem Res, 1992, 31(4):1 035-1 040.