Acyclic telluroiminium salts: Isolation and characterization

Journal of the American Chemical Society

Volumn 126, Issue 51, 2004, Pages 16696-16697

  Mutoh, Yuichiro ^a   Murai, Toshiaki ^a   Yamago, Shigeru ^b  

^a GIFU UNIVERSITY   (Japan)

^b Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

TELLURIUM DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; ISOLATION PROCEDURE; METHYLATION;

EID: 11244313063     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja044022n     Document Type: Article

References (16)

1. Bzhezovskii, V. M.; Kushnarev, D. F.; Trofimov, B. A.; Kalabin, G. A.; Gusarova, N. K.; Efremova, G. G. Izv. Akad. Nauk, Ser. Khim. 1981, 2507.
2. (b) Sohlberg, K.; Baker, B. L.; Leary, S. P.; Owen, N. L.; Facelli, J. C.; Trofimov, B. A. J. Mol. Struct. 1995, 354, 55.
3. (c) Yamago, S.; Kokubo, K.; Hara, O.; Masuda, S.; Yoshida, J.-i. J. Org. Chem. 2002, 67, 8584.
4. Kawahara, Y.; Kato, S.; Kanda, T.; Murai, T.; Ebihara, M. Bull. Chem. Soc. Jpn. 1995, 68, 3507.
5. Cyclic telluroiminium salts, stabilized by inserting the tellurium atom in a five-membered ring, have been reported: Sadekov, I. D.; Maksimenko, A. A.; Minkin, V. I. Sulfur Rep. 1990, 9, 359.
6. Mutoh, Y.; Murai, T. Org. Lett. 2003, 5, 1361.
7. (b) Mutoh, Y.; Murai, T. Organometallics 2004, 23, 3907.
8. For crystal data for 2a, see the Supporting Information.
9. Li, G. M.; Zingaro, R. A.; Segi, M.; Reibenspies, J. H.; Nakajima, T. Organometallics 1997, 16, 756.
10. (b) Kuhn, N.; Henkel, G.; Kartz, T. Chem. Ber. 1993, 126, 2047.
11. (c) Yamago, S.; Miyazoe, H.; Goto, R.; Hashidume, M.; Sawazaki, T.; Yoshida, J.-i. J. Am. Chem. Soc. 2001, 123, 3697.
12. Yamago, S.; Miyazoe, H.; Nakayama, T.; Miyoshi, M.; Yoshida, J. Angew. Chem., Int. Ed. 2003, 42, 117.
13. Molecular orbital calculations for the model compounds 2i, 9c, and 9d (Chart 1) were performed at the B3LYP/LANL2DZ level.
14. Murai, T.; Mutoh, Y.; Kato, S. Org. Lett. 2001, 3, 1993.
15. For the details of the reaction pathway, see the Supporting Information.
16. Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1998, 88, 899.