Bent metal carbene geometries in amido N-heterocyclic carbene complexes

Chemical Communications

Volumn , Issue 23, 2004, Pages 2738-2739

  Mungur, Shaheed A ^a   Liddle, Stephen T ^a   Wilson, Claire ^a   Sarsfield, Mark J ^b   Arnold, Polly L ^a  

^a UNIVERSITY OF NOTTINGHAM   (United Kingdom)

^b SELLAFIELD LTD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENOID; HETEROCYCLIC COMPOUND; LITHIUM; URANIUM;

ARTICLE; CHEMICAL BOND; DENSITY FUNCTIONAL THEORY; ELECTRIC ACTIVITY; ELECTROCHEMISTRY; LIGAND BINDING; MOLECULAR INTERACTION; MOLECULAR STABILITY; SUBSTITUTION REACTION;

EID: 11144309687     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b410074c     Document Type: Article

References (18)

1. W. A. Herrmann, Angew. Chem., Int. Ed, 2002, 41, 1291; J. C. Green, R. G. Scurr, P. L. Arnold and F. G. N. Cloke, Chem. Commun., 1997, 1963; M. Niehues, G. Erker, G. Kehr, P. Schwab, R. Frohlich, O. Blacque and H. Berke, Organometallics, 2002, 21, 2905.
2. W. A. Herrmann, Angew. Chem., Int. Ed, 2002, 41, 1291; J. C. Green, R. G. Scurr, P. L. Arnold and F. G. N. Cloke, Chem. Commun., 1997, 1963; M. Niehues, G. Erker, G. Kehr, P. Schwab, R. Frohlich, O. Blacque and H. Berke, Organometallics, 2002, 21, 2905.
3. W. A. Herrmann, Angew. Chem., Int. Ed, 2002, 41, 1291; J. C. Green, R. G. Scurr, P. L. Arnold and F. G. N. Cloke, Chem. Commun., 1997, 1963; M. Niehues, G. Erker, G. Kehr, P. Schwab, R. Frohlich, O. Blacque and H. Berke, Organometallics, 2002, 21, 2905.
4. (a) P. L. Arnold, M. Rodden, K. M. Davis, A. C. Scarisbrick, A. J. Blake and C. Wilson, Chem. Commun., 2004, 1612;
5. (b) H. Y. Zhou, E. J. Campbell and S. T. Nguyen, Org. Lett., 2001, 3, 2229.
6. P. L. Arnold, S. A. Mungur, A. J. Blake and C. Wilson, Angew. Chem., Int. Ed., 2003, 42, 5981.
7. C. D. Abernethy, G. M. Codd, M. D. Spicer and M. K. Taylor, J. Am. Chem. Soc., 2003, 125, 1128; P. Shukla, J. A. Johnson, D. Vidovic, A. H. Cowley and C. D. Abernethy, Chem. Commun., 2004, 360; H. Nakai, X. L. Hu, L. N. Zakharov, A. L. Rheingold and K. Meyer, Inorg. Chem., 2004, 43, 855.
8. C. D. Abernethy, G. M. Codd, M. D. Spicer and M. K. Taylor, J. Am. Chem. Soc., 2003, 125, 1128; P. Shukla, J. A. Johnson, D. Vidovic, A. H. Cowley and C. D. Abernethy, Chem. Commun., 2004, 360; H. Nakai, X. L. Hu, L. N. Zakharov, A. L. Rheingold and K. Meyer, Inorg. Chem., 2004, 43, 855.
9. C. D. Abernethy, G. M. Codd, M. D. Spicer and M. K. Taylor, J. Am. Chem. Soc., 2003, 125, 1128; P. Shukla, J. A. Johnson, D. Vidovic, A. H. Cowley and C. D. Abernethy, Chem. Commun., 2004, 360; H. Nakai, X. L. Hu, L. N. Zakharov, A. L. Rheingold and K. Meyer, Inorg. Chem., 2004, 43, 855.
10. M. J. Sarsfield, H. Steele, M. Helliwell and S. J. Teat, Dalton Trans., 2003, 3443.
11. R. W. Alder, M. E. Blake, C. Bortolotti, S. Bufalli, C. P. Butts, E. Linehan, J. M. Oliva, A. G. Orpen and M. J. Quayle, Chem. Commun., 1999, 241.
12. M. Vestergren, J. Ericsson, G. Hilmersson and M. Hakånsson, J. Organomet. Chem., 2003, 682, 172.
13. R. E. Dinnebier, U. Behrens and F. Olbrich, J. Am. Chem. Soc., 1998, 120, 1430.
14. P. J. Bailey, C. M. E. Dick, S. Fabre and S. Parsons, Dalton Trans., 2000, 1655; W. Clegg, L. Horsburgh, R. E. Mulvey, M. J. Ross, R. B. Rowlings and V. Wilson, Polyhedron, 1998, 17, 1923.
15. P. J. Bailey, C. M. E. Dick, S. Fabre and S. Parsons, Dalton Trans., 2000, 1655; W. Clegg, L. Horsburgh, R. E. Mulvey, M. J. Ross, R. B. Rowlings and V. Wilson, Polyhedron, 1998, 17, 1923.
16. A. J. Arduengo III, H. V. Rasika-Dias, R. Davidson and R. L. Harlow, J. Organomet. Chem., 1993, 462, 13.
17. The other example is also an NHC adduct: W. J. Oldham, Jr., S. M. Oldham, B. L. Scott, K. D. Abney, W. H. Smith and D. A. Costa, Chem. Commun., 2001, 1348.
18. W. A. Herrmann, F. C. Munck, G. R. J. Artus, O. Runte and R. Anwander, Organometallics, 1997, 16, 682.