Selective synthesis of N,N-dimethyl aniline derivatives using dimethyl carbonate as a methylating agent and onium salt as a catalyst

Journal of Molecular Catalysis A: Chemical

Volumn 226, Issue 1, 2005, Pages 49-56

  Shivarkar, Anand B ^a   Gupte, Sunil P ^a   Chaudhari, Raghunath V ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Aniline; Dimethyl carbonate; Methylation; N,N Dimethyl aniline; N Alkylation; Onium salts

Indexed keywords

DIMETHYL CARBONATE (DMC); N,N DIMETHYL ANILINE (NNDMA); ONIUM SALTS; REACTION-NETWORKING SCHEMES;

ALKYLATION; CATALYSIS; CATALYSTS; DERIVATIVES; REACTION KINETICS; SALTS; SYNTHESIS (CHEMICAL);

NITROGEN COMPOUNDS;

ANILINE DERIVATIVE; CARBONIC ACID; CATION;

ALKYLATION; ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL PROCEDURES; CHEMICAL REACTION; SYNTHESIS;

EID: 11144285931     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2004.09.025     Document Type: Article

References (21)

1. S. Narayanan, and K. Deshpande Appl. Catal. 199 2000 1
2. N.R. Shreve, G.N. Vriens, and D.A. Vogel Ind. Eng. Chem. 42 1950 791
3. Kirk-othmer Encyclopedia of Chemical Technology, vol. 2 4th ed. 1992 Wiley New York p. 438
4. W. Maret, and B.L. Vallee Proc. Natl. Acad. Sci. U.S.A. 95 1998 3478
5. S.P. Elangovan, C. Kannan, B. Arabindoo, and V. Murugesan Appl. Catal. A: Gen. 174 1998 213
6. B.L. Su, and D. Barthomeauf Appl. Catal. A: Gen. 124 1995 73
7. P.R.H. Prasad Rao, M. Pascale, and D. Barthomeuf Catal. Lett. 31 1995 115
8. L.K. Doraiswami, G.R.W. Krishnan, and S.P. Mukherjee Chem. Eng. 13 1981 78
9. F. Rivetti C.R. Acad. Sci., Ser. IIC: Chem. 3 2000 497
10. Y. Ono Appl. Catal. A: Gen. 155 1997 133
11. Z. Fu, and Y. Ono Catal. Lett. 22 1993 277
12. K. Sreekumar, T. Mathew, S.P. Mirajkar, S. Sugunan, and B.S. Rao Appl. Catal. A: Gen. 201 2000 L-1
13. T.M. Jyothi, T. Raja, M.B. Talawar, K. Sreekumar, S. Sugunan, and B.S. Rao Synth. Commun. 30 2000 3929
14. F. Trotta, P. Tundo, and G. Moraglio J. Org. Chem. 52 1987 1300
15. M. Selva, A. Bomben, and P. Tundo J. Chem. Soc., Perkin Trans. I 1997 1041
16. M. Selva, P. Tundo, and A. Perosa J. Org. Chem. 66 2001 677
17. E.V. Dehmlow, R. Thhieser, H.A. Zahalka, and Y. Sasson Tetrahedron Lett. 26 1985 297
18. G. Shaikh, Synthesis and characterization of poly(aryl carbonate)s and poly (arylester-carbonate)'s via carbonate interchange reactions with dialkyl carbonate, Ph.D. Thesis, University of Poona, July 1994, p. 157.
19. D. Landini, and A. Maia J. Mol. Catal. 204 2003 235
20. P.V. Gutmann Coord. Chem. Rev. 18 1976 225
21. C.L. Liotta, and H.P. Harris J. Am. Chem. Soc. 96 1974 2250