Real-time detection of doorway states in the intramolecular vibrational energy redistribution of the OH/OD stretch vibration of phenol

Journal of Chemical Physics

Volumn 121, Issue 23, 2004, Pages 11530-11534

  Yamada, Yuji ^a   Mikami, Naohiko ^a   Ebata, Takayuki ^b  

^a TOHOKU UNIVERSITY   (Japan)

^b HIROSHIMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON ENERGY LEVELS; HYDROGEN BONDS; INFRARED RADIATION; IONIZATION; SPECTROSCOPIC ANALYSIS; ULTRAVIOLET RADIATION;

DOORWAY STATES; ENERGY REDISTRIBUTION; INTRAMOLECULAR VIBRATIONS; RESONANCE ENHANCED MULTIPHOTON IONIZATION (REMPI);

PHENOLS;

EID: 11044232213     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1829634     Document Type: Article

References (24)

1. S. Woutersen, U. Emmerichs, H.-K. Nienhuys, and H. J. Bakker, Phys. Rev. Lett. 81, 1106 (1998).
2. Z. Wang, A. Pakoulev, and D. D. Dlott, Science 296, 2201 (2002).
3. C. J. Fecko, J. D. Eaves, J. J. Loparo, A. Tokmakoff, and P. L. Geissler, Science 301, 1698 (2003).
4. D. F. Heller and S. Mukamel, J. Chem. Phys. 70, 463 (1979).
5. J. S. Hutchinson, W. P. Reinhardt, and J. T. Hynes, J. Chem. Phys. 79, 4247 (1983).
6. A. McIlroy, D. J. Nesbitt, E. R. Th. Kerstel, B. H. Pate, K. K. Lehmann, and G. Scoles, J. Chem. Phys. 100, 2596 (1994).
7. S.-i. Ishiuchi, H. Shitomi, K. Takazawa, and M. Fujii, Chem. Phys. Lett. 283, 243 (1998).
8. R. Laenen and C. Rauscher, Chem. Phys. Lett. 274, 63 (1997).
9. J. Assmann, R. von Benten, A. Charvat, and B. Abel, J. Phys. Chem. A 107, 1904 (2003).
10. C. G. Elles, M. J. Cox, and F. F. Crim, J. Chem. Phys. 120, 6973 (2004).
11. R. M. Helm and H. J. Neusser, Chem. Phys. 239, 33 (1998).
12. T. Watanabe, T. Ebata, S. Tanabe, and N. Mikami, J. Chem. Phys. 105, 408 (1996).
13. S. Schumm, M. Gerhards, and K. Kleinermanns, J. Phys. Chem. A 104, 10648 (2000).
14. H. D. Bist, J. C. D. Brand, and D. R. Williams, J. Mol. Spectrosc. 24, 402 (1967).
15. H. D. Bist, J. C. D. Brand, and D. R. Williams, J. Mol. Spectrosc. 24, 413 (1967).
16. G. Keresztury, F. Billes, M. Kubinyi, and T. Sundius, J. Phys. Chem. A 102, 1371 (1998).
17. Y. Yamada, T. Ebata, M. Kayano, and N. Mikami, J. Chem. Phys. 120, 7400 (2004).
18. T. Ebata, M. Kayano, S. Sato, and N. Mikami, J. Phys. Chem. A 105, 8623 (2001).
19. M. Bixon and J. Jortner, J. Chem. Phys. 48, 715 (1968).
20. E. R. T. Kerstel, K. K. Lehmann, T. F. Mentel, B. H. Pate, and G. Scoles, J. Phys. Chem. 95, 8282 (1991).
21. The density of states was estimated by a direct counting method under a harmonic oscillator approximation, with vibrational frequencies taken from Refs. 14 and 16.
22. F. Lahmani, A. Tramer, and C. Tric, J. Chem. Phys. 60, 4431 (1974).
23. P. M. Felker and A. H. Zewail, Phys. Rev. Lett. 53, 501 (1984).
24. -1 (5 ps) from the simulation of the decay profile of the CH stretching vibration in our previous paper (Ref. 17). The results obtained in Figs. 3(b) and 3(c) show that the above assumption is satisfied in the present condition.