Application of PSRK for process design

Chemical Engineering Communications

Volumn 192, Issue 1-3, 2005, Pages 336-350

  Horstmann, Sven ^a   Fischer, Kai ^a   Gmehling, Jürgen ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

Author keywords

Critical data; Equation of state; Group contribution; Phase equilibrium; PSRK; UNIFAC

Indexed keywords

ABSORPTION; ELECTROLYTES; ENTHALPY; HYDROGEN SULFIDE; MATHEMATICAL MODELS; NATURAL GAS; PARAMETER ESTIMATION; PHASE EQUILIBRIA; PRESSURE EFFECTS; PROCESS CONTROL; SOLUBILITY; SOLVENTS; SURVEYS; THERMAL EFFECTS; THERMODYNAMICS;

AIR SOLUBILITY; ASYMMETRIC SYSTEMS; GROUP CONTRIBUTION MODEL; SOAVE-RELICH-KWONG (PSRK);

EQUATIONS OF STATE;

PROCESS CONTROL;

EID: 11044226700     PISSN: 00986445     EISSN: None     Source Type: Journal    
DOI: 10.1080/00986440590473542     Document Type: Article

References (26)

1. Fischer, K. and Gmehling, J. (1996). Further development, status and results of the PSRK method for the prediction of vapor-liquid equilibria and gas solubilities, Fluid Phase Equilib., 121, 185-206.
2. Fischer, K. and Wilken, M. (2001). Experimental determination of oxygen and nitrogen solubility in organic solvents up to 10 MPa at temperatures between 298 K and 398 K J. Chem. Thermodyn., 155, 1285-1308.
3. Gmehling, J., Li, Jiding, and Fischer, K. (1997). Further development of the PSRK model for the prediction of gas solubilities and vapor-liquid equilibria at low and high pressures: II. Fluid Phase Equilib., 141, 113-127.
4. 2S+COS: Extension of the PSRK group contribution equation of state, Fluid Phase Equilib.,170, 193-202.
5. Hansen, H. K., Rasmussen, P., Fredenslund, A., Schiller, M., and Gmehling, J. (199 1). Vaporliquid equilibria by UNIFAC group contribution. 5: Revision and extension, Ind Eng. Chem. Res.,30 2352-2355.
6. Heidemann, R. A. and Khalil, A. M. (1980). The calculation of critical points, AIChE J., 26, 769-779.
7. Holderbaum, T. and Gmehling, J. (1991). PSRK: A group contribution equation of state based on UNIFAC, Fluid Phase Equilib., 70, 251-265.
8. Horstmann, S. (2000). Theoretical and experimental investigations on the high pressure phase equilibrium behavior of fluid mixtures for the extension of the PSRK group contribution equation of state, Shaker, Aachen.
9. Horstmann, S., Fischer, K., and Gmehling, J. (1999). Experimental determination of critical points of pure components and binary mixtures using a flow apparatus, Chem. Eng. Technol., 22, 839-842.
10. Horstmann, S., Fischer, K., and Gmehling, J. (2000a). PSRK Group contribution equation of state: Revision and extension: III, Fluid Phase Equilib., 167, 173-186.
11. Horstmann, S., Fischer, K., Gmehling, J., and Koláǐ, P. (2000b). Experimental determination of the critical line for (carbon dioxide + ethane) and calculation of various thermodynamic properties for (carbon dioxide + n-alkane) using the PSRK model, J. Chem. Thermodyn., 32, 451-464.
12. Horstmann, S., Fischer, K., and Gmehling, J. (2001). Experimental determination of critical data of mixtures and their relevance for the development of thermodynamic models, Chem. Eng. Sci., 560, 6905-6913.
13. Huron, M. J. and Vidal, J. (1979). New mixing rules in simple equations of state for representing vapour-liquid equilibria of strongly non-ideal mixtures, Fluid Phase Equilib., 3, 255-271.
14. Koláǎ, P. and Kojima, K. (1996). Prediction of critical points in multicomponent systems using the PSRK group contribution equation of state, Fluid Phase Equilib., 118, 175-200.
15. E model for single and mixed solvent electrolyte systems. 1: Model and results for strong electrolytes, Fluid Phase Equilib., 94, 89-114.
16. Li, Jiding, Fischer, K., and Gmehling, J. (1998). Prediction of vapor-liquid equilibria for asymmetric systems at low and high pressures with the PSRK model, Fluid Phase Equilib., 143, 71-82.
17. Li, Jiding, Topphoff, M., Fischer, K., and Gmehling, J. (2001). Prediction of gas solubilites in aqueous electrolyte systems using the PSRK model, Fluid Phase Equilib., 40, 3703-3710.
18. Mathias, P.M. and Copeman, T. W. (1983). Extension of the Peng-Robinson equation of state to complex mixtures: Evaluation of the various forms of the local composition concept, Fluid Phase Equilib., 13, 91-108.
19. McFall, T. A., Post, M. E., Christensen, J. J., and Izatt, R. M. (1981). The excess enthalpies of eight (ethane + alcohol) mixtures at 298.15 K, J. Chem. Thermodyn., 13, 441-446.
20. Ott, J. B., Lemon, L. R., Sipowska, J. T., and Brown, P. R. (1995). Excess enthalpies and excess volumes for (ethane + propan-l-ol) at the temperatures (298.15, 323.15, and 348.15) K and the pressures (5, 10, 12.5, and 15) MPa, J. Chem. Thermodyn., 27, 1033-1045.
21. Péneloux, A., Rauzy, E., and Fréze, R. (1982). A consistent correction for Redlich-Kwong Soave volumes, Fluid Phase Equilib., 8, 7-23.
22. Soave, G. (1972). Equilibrium constants from a modified Redlich-Kwong equation of state, Chem. Eng. Sci., 4, 1197-1203.
23. van Koynenburg, P. H., and Scott, R. L. (1980). Critical lines and phase equilibria in binary van der waals mixtures, Phils. Trans. R. Soc. London Ser. A, 298, 495-540.
24. Vigh, L. (1997). Prediction of excess entropy and critical points using group contribution methods. Ph.D. Thesis, Nihon University, Tokyo.
25. Vigh, L., Kolář, P. and Kojima, K. (1996). PSRK prediction of critical points in binary mixtures containing alkanes or cycloalkanes, J. Chem. Eng. Jpn., 29, 1054-1057.
26. Yan, W., Topphoff, M., Rose, C., and Gmehling, J. (1999). Prediction of vapor-liquid equilibria in mixed-solvent electrolyte systems using the group contribution concept, Fluid Phase Equilib., 162, 97-113.