Fluorescence fingerprint of fulvic and humic acids from varied origins as viewed by single-scan and excitation/emission matrix techniques

Chemosphere

Volumn 58, Issue 6, 2005, Pages 715-733

  Sierra, M M D ^a   Giovanela, M ^b   Parlanti, E ^c   Soriano Sierra, E J ^a  

^a FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

^b UNIVERSITY OF CAXIAS DO SUL   (Brazil)

^c UNIVERSITÉ DE BORDEAUX   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; ESTUARIES; FLUORESCENCE; MARINE BIOLOGY; PROTEINS; SPECTROSCOPIC ANALYSIS;

EXCITATION/EMISSION MATRIX (EEM) TECHNIQUE; FLUVIC ACID (FA); HUMIC ACID (HA); ORGANIC MATTERS (OM);

ORGANIC ACIDS;

FULVIC ACID; HUMIC ACID; ORGANIC MATTER; PROTEIN; TRYPTOPHAN; WATER;

DETECTION METHOD; FLUORESCENCE SPECTROSCOPY; FULVIC ACID; HUMIC ACID;

ENVIRONMENT; ESTUARY; EXCITATION; EXCITATION EMISSION MATRIX FLUORESCENCE; FLUORESCENCE; FLUORESCENCE SPECTROSCOPY; INCIDENCE; LAND BIOME; MARINE ENVIRONMENT; REVIEW; SINGLE SCAN EXCITATION SPECTROSCOPY; SPECTROSCOPY; SPECTRUM; WATER SAMPLING;

EID: 11044225125     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2004.09.038     Document Type: Article

References (41)

1. G.R. Aiken, and A.H. Gillam Determination of molecular weights of humic substances by collogative property measurements M.H.B. Hayes P. MacCarthy R.L. Malcolm R.S. Swift Humic Substances II, in search of structure 1989 John Wiley & Sons Ltd Chichester
2. A. Baker Fluorescence excitation-emission matrix characterization of some sewage-impacted rivers Environ. Sci. Technol. 35 2001 948 953
3. C. Belin, C. Quellec, M. Lamotte, M. Ewald, and Ph. Simon Characterization by fluorescence of the dissolved organic matter in natural water. Application to fractions obtained by tangential ultrafiltration and XAD resin isolation Environ. Technol. 14 1993 1131 1144
4. S.E. Cabaniss Synchronous fluorescence spectra of metal-fulvic acid complexes Environ. Sci. Technol. 26 1992 1133 1139
5. S.E. Cabaniss, and M.S. Shuman Synchronous fluorescence spectra of natural waters: tracing sources of dissolved organic matter Mar. Chem. 21 1987 37 50
6. J. Chen, E.J. LeBoeuf, S. Dai, and B. Gu Fluorescence spectroscopic studies of natural organic matter fractions Chemosphere 50 2003 639 647
7. P.G. Coble Characterization of marine and terrestrial DOM in seawater using excitation-emission matrix spectroscopy Mar. Chem. 51 1996 325 346
8. C.E. Del Castillo, P.G. Coble, J.M. Morell, J.M. Lopez, and J.E. Corredor Analysis of the optical properties of the Orinico River plume by absorption and fluorescence spectroscopy Mar. Chem. 66 1999 35 51
9. S. Determann, J.M. Lobbes, R. Reuter, and J. Rullkötter Ultraviolet fluorescence excitation and emission spectroscopy of marine algae and bacteria Mar. Chem. 62 1998 137 156
10. J.C.G. Esteves da Silva, and A.A.S.C. Machado Evolving factor analysis of synchronous fluorescence spectra of humic substances in the presence of Cu(II) Chemometr. Intell. Lab. Syst. 27 1995 115 128
11. M. Ewald, C. Belin, P. Berger, and J.H. Weber Corrected fluorescence spectra of fulvic acids isolated from soil and water Environ. Sci. Technol. 17 1983 201 504
12. A.N. Fernandes, M. Giovanela, E.J. Soriano-Sierra, and M.M.D. Sierra Acidity data on humic substances from distinct environments: methodology considerations J. Coastal Res. SI 2004 39 in press
13. G.M. Ferrari, and M. Mingazzini Synchronous fluorescence spectra of dissolved organic matter (DOM) of algal origin in marine coastal systems Mar. Ecol. Progr. Series 125 1995 305 315
14. French, C.S., 1960. The chlorophylls in vivo and in vitro. In: Ruhland, W. (Ed.), Encyclopedia of Plant Physiology, Vol. 5/1. Berlin, Springer, pp. 252-297
15. M. Fukushima, S. Tanaka, K. Nakayasu, K. Sasaki, H. Nakamura, and K. Tatsumi Anal. Sci. 13 1997 1011 1015
16. M. Giovanela, E. Parlanti, M.S. Soldi, E.J. Soriano-Sierra, and M.M.D. Sierra Elemental compositions, FT-IR spectra and thermal behavior of sedimentary fulvic and humic acids from aquatic and terrestrial environments Geochem. J. 38 2004 255 264
17. IHSS home page: http://www.ihss.gatech.edu/
18. A.T. Lombardi, and W.F. Jardim Synchronous-scan fluorescence and the complexation of copper (II) ions by humic substances J. Braz. Chem. Soc. 8 1997 1 6
19. A.A.S.C. Machado, J.C.G. Esteves da Silva, and J.A.C. Maia Multi-wavelength analysis of synchronous fluorescence spectra of the complexes between a soil fulvic acid and Cu(II) Anal. Chim. Acta 292 1994 121 132
20. R.L. Malcolm, and P.M. MacCarthy Limitations in the use of commercial humic acids in water and soil research Environ. Sci. Technol. 20 1986 904 911
21. B.J.H. Mattews, A.C. Jones, N.K. Theodorou, and A.W. Tudhope Excitation-emission-matrix fluorescence spectroscopy applied to humic acid bands in coral reefs Mar. Chem. 55 1996 317 332
22. L.M. Mayer, L.L. Schick, and T.C. Loder III Dissolved protein fluorescence in two Maine estuaries Mar. Chem. 64 1999 171 179
23. T.M. Miano, and N. Senesi Synchronous excitation fluorescence spectroscopy applied to soil humic substances chemistry Sci. Total Environ. 117/118 1992 41 51
24. T.M. Miano, G. Sposito, and J.P. Martín Fluorescence spectroscopy of humic substances Soil Sci. Soc. Am. J. 52 1988 1016 1019
25. J.J. Mobed, S.L. Hemmingsen, J.L. Autry, and L.B. MacGown Fluorescence characterization of IHSS humic substances: total luminescence spectra with absorbance correction Environ. Sci. Technol. 30 1996 3061 3065
26. K. Mopper, and C.A. Schultz Fluorescence as a possible tool for studying the nature and water column distribution of DOC components Mar. Chem. 41 1993 229 238
27. S. Mounier, N. Patel, L. Quilici, J.Y. Benaim, and C. Benamou Fluorescence 3D de la matière organique dissoute du fleuve Amazone (Three-dimensional fluorescence of the disolved organic carbon in the Amazon river) Water Res. 33 1999 1523 1533
28. E. Parlanti, B. Morin, and L. Vacher Combined 3D-spectrofluorimetry, high performance liquid chromatography and capillary electrophoresis for the characterization of dissolved organic matter in natural waters Org. Geochem. 33 2002 221 236
29. E. Parlanti, K. Wörz, L. Geoffroy, and M. Lamotte Dissolved organic matter fluorescence spectroscopy as a tool to estimate biological activity in a coastal zone submitted to anthropogenic inputs Org. Geochem. 31 2000 1765 1781
30. N. Patel-Sorrentino, S. Mounier, and J.Y. Benaim Excitation-emission fluorescence matrix to study pH influence on organic matter fluorescence in the Amazon basin rivers Water Res. 36 2002 2571 2581
31. N. Senesi Molecular and quantitative aspects of the chemistry of fulvic acid and its interactions with metal ions and organic chemicals. Part II. The fluorescence spectroscopy Anal. Chim. Acta 232 1990 77 106
32. N. Senesi, T.M. Miano, M.R. Provenzano, and G. Brunetti Characterization, differentiation, and classification of humic substances by fluorescence spectroscopy Soil Sci. 152 1991 259 271
33. M.M.D. Sierra, O.F.X. Donard, and M. Lamotte Behaviour of dissloved fluorescent organic matter during estuarine mixing Mar. Chem. 58 1997 51 58
34. M.M.D. Sierra, O.F.X. Donard, M. Lamotte, C. Belin, and M. Ewald Fluorescence spectroscopy of coastal and marine waters Mar. Chem. 47 1994 127 144
35. M.M.D. Sierra, M. Giovanela, and E.J. Soriano-Sierra Fluorescence properties of well-characterized sedimentary estuarine humic compounds and surrounding pore waters Environ. Technol. 21 2000 979 988
36. 13C-solid state NMR data J. Coast. Res. SI 2004 42 in press
37. Silva, M.R., 1996. Estudos potenciométricos e fluorimé tricos dos equilíbrios ácido-básicos e da complexação de metais com o Obisdien e as substâncias húmicas. Contaminação pelos metais em sedimentos da Ilha de Santa Catarina (Brasil). PhD Thesis, Universidade Federal de Santa Catarina
38. C.S.P.C.O. Silva, J.C.G. Esteves da Silva, and A.A.S.C. Machado Evolving factor analysis of synchronous fluorescence spectra of fulvic acids in the presence of aluminium Appl. Spectrosc. 48 1994 363 371
39. R.S. Swift Organic matter characterization D.L. Sparks Methods of Soil Analysis 1996 Soil Science Society of America Madison, WI 1018 1020
40. B.L. Van Duuren The fluorescence spectra of aromatic hydrocarbons and heterocyclic aromatic compounds Anal. Chem. 32 1960 1436 1442
41. T. Vo-Dinh Multicomponent analysis by synchronous luminescence spectrometry Anal. Chem. 50 1978 396 401