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The α,α,α-trifluoromethylbenzonitrile isomers were purchased from Ald-rich Chemicals and stated to be 99% pure, except for the ortho-isomer (98%). Approximate vapor pressures we observed while preparing mixtures in He at 299 K were 31(o-TFMBN), 69(m-TFMBN), and 55 Pa (p-TFMBN). None proved sticky on surfaces, and all were easily handled, though transfer of p-TFMBN required a few degrees of warming to liquefy.
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