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0346610043
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note
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Both in the bis(iminodiphenylphosphorano)methylene complexes and in the imidazol-2-ylidene complexes of group 4 metals the carbenoid carbon atoms are stabilized by directly bound heteroatoms. Therefore, these carbenoid species are not being consumed in this work: (a) Cavell, R. A.; Kamalesh Babu, R. P.; Aparna, K. J. Organomet. Chem. 2001, 617-618, 158-169 and literature cited therein.
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19
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0037011774
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(b) Niehues, M.; Kehr, G.; Erker, G.; Wibbeling, B.; Fröhlich, R.; Blacque, O.; Berke, H. J. Organomet. Chem. 2002, 663, 192-203 and literature cited therein.
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21
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1142265890
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note
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C,H = 124.5 Hz, =CMe) (see the Supporting Information).
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22
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1142265888
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note
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-3.
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23
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0001348064
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25
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1142302244
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note
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-3.
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26
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33745231055
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Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G. J. Chem. Soc., Dalton Trans. 1989, S1-S83.
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