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Volumn 23, Issue 3, 2004, Pages 320-322

α-H elimination from homoleptic bis(1-aza-1,3-diene)titanium: Formation of a new metallacyclic titanium alkylidene complex

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; BOND STRENGTH (CHEMICAL); METHANE; MOLECULES; REDUCTION; SYNTHESIS (CHEMICAL); TEMPERATURE; TITANIUM COMPOUNDS;

EID: 10744228088     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034172r     Document Type: Article
Times cited : (17)

References (26)
  • 6
    • 0001270989 scopus 로고
    • Alkene metathesis and related reactions
    • Trost, B. M., Flemming, I., Paquette, L. A., Eds.; Pergamon: New York
    • (a) Grubbs, R. H.; Pine, R. H. Alkene Metathesis and Related Reactions. In Comprehensive Organic Synthesis; Trost, B. M., Flemming, I., Paquette, L. A., Eds.; Pergamon: New York, 1991; Vol. 5, pp 1115-1127.
    • (1991) Comprehensive Organic Synthesis , vol.5 , pp. 1115-1127
    • Grubbs, R.H.1    Pine, R.H.2
  • 7
    • 0000272607 scopus 로고    scopus 로고
    • Titanium-carbene mediated reactions
    • Beller, M., Bolm, C., Eds.; Wiley-VCH: Weinheim, Germany; Chapter 3.2
    • (b) Petasis, N. A. Titanium-Carbene Mediated Reactions. In Transition Metals for Organic Synthesis; Beller, M., Bolm, C., Eds.; Wiley-VCH: Weinheim, Germany, 1998; Vol. 1, Chapter 3.2, pp 361-380.
    • (1998) Transition Metals for Organic Synthesis , vol.1 , pp. 361-380
    • Petasis, N.A.1
  • 18
    • 0346610043 scopus 로고    scopus 로고
    • note
    • Both in the bis(iminodiphenylphosphorano)methylene complexes and in the imidazol-2-ylidene complexes of group 4 metals the carbenoid carbon atoms are stabilized by directly bound heteroatoms. Therefore, these carbenoid species are not being consumed in this work: (a) Cavell, R. A.; Kamalesh Babu, R. P.; Aparna, K. J. Organomet. Chem. 2001, 617-618, 158-169 and literature cited therein.
    • (2001) J. Organomet. Chem. , vol.617-618 , pp. 158-169
    • Cavell, R.A.1    Kamalesh Babu, R.P.2    Aparna, K.3
  • 21
    • 1142265890 scopus 로고    scopus 로고
    • note
    • C,H = 124.5 Hz, =CMe) (see the Supporting Information).
  • 22
    • 1142265888 scopus 로고    scopus 로고
    • note
    • -3.
  • 25
    • 1142302244 scopus 로고    scopus 로고
    • note
    • -3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.