Salt effects in the kinetics of reaction between iodide and bromate ions

Pakistan Journal of Scientific and Industrial Research

Volumn 45, Issue 3, 2002, Pages 168-171

  Uddin, Fahim ^a   Tahir, Hajira ^a  

^a UNIVERSITY OF KARACHI   (Pakistan)

Author keywords

Bromate ions; Iodide; Kinetic reaction; Salt effects

Indexed keywords

POTASSIUM BROMATE; POTASSIUM IODIDE; SODIUM CHLORIDE;

IODIDE; KINETICS;

ARTICLE; CHEMICAL REACTION; ENERGY; ENTHALPY; ENTROPY; IONIC STRENGTH; KINETICS; TEMPERATURE;

EID: 10644221838     PISSN: 00309885     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (17)

1. Atkins PW 1998 Physical Chemistry, 6th edition. Oxford University Press Oxford Melbourne Tokyo, pp. 776-777.
2. Debye P, Huckel E 1923 Lowering of freezing point and related phenomena. Z Phys Chem 24 185-206.
3. Holmberg B 1921 Cation catalysis. Z Physik Chem 97 134-157.
4. Indelli A, Bartocci V 1971 Kientic salt effect and structure of aqueous solution. Isr J Chem 9 301-320.
5. Kilpatrick M 1934 The effect of electrolytes in ionic reactions. J Am Chem Soc 56 2326-2327.
6. King DEC, Lister MW 1968 Reaction between iodide and sodium bromate. Can J Chem 46 279-286.
7. Taube H, Dodgen H 1949 Application of radioactive chlorine to the study of the mechanisms of reactions involving changes in the oxidation states of chlorine. J Am Chem 71 3330-3336.
8. Uddin F, Ahmed M G 1979 Influence of ionic strength on the specific rate constant, energy of activation and the evaluation of change of enthalpy of activation of iodide-bromate reaction. Pak J Sci Ind Res 22 (4) 181-184.
9. Uddin F, Ahmed M G 1980 Study of the rate and some thermodynamic parameters of the reaction between bromide and peroxydisulphate. Gazz Chim Ital 110 (11-12) 593-595.
10. Uddin F, Hussain I 1985 Shape of the activated complex for the ionic reaction. Nig J Sci Tech 3 (1) 81-85.
11. Uddin F, Khalid Z 1992 Cationic salt effects on the reaction between bromopropionate and thiosulphate ions in presence of lithium and sodium chlorides. Acta Cientif Venezol 43 (3) 143-147.
12. Uddin F, Khalid Z 1995 Effect of electrolytes on the kinetics of reaction between monobromopropionate and thiosulphate ions. Egypt J Sci 38 (1) 15-26.
13. Uddin F, Shahid N 1996 The ionic strength dependence on the rates of reaction of ethyloxalate ions. Acta Cientif Venezol 47 167-171.
14. Uddin F, Akber S, Jabeen S 1992 Cationic catalytic effects for the ionic reaction between 2, 3-dibromosuccinate and hydroxide ions. J Sci Ind Res 35 (6) 235-237.
15. Uddin F, Ahmed M G 1981 Dependence of specific rate constant of iodide-bromate reaction on dielectric constant of medium. Arab J Sc Engg 6 (2) 105-109.
16. Uddin F, Ahmed M G, Hasnain Q Z 1986 Kinetics and activation parameters of the reaction between sodium bromoacetate and sodium thiosulphate. Acta Cientif Venezol 37 (6) 67-69.
17. Uddin F, Khalid Z, Kausar T 1996 Salt effects on the kinetics of reaction between bromopropionate and thiosulphate ions. J Nat Sci Maths 6 69-75.