Simplifying DOSY spectra with selective TOCSY edited preparation

Journal of Magnetic Resonance

Volumn 172, Issue 1, 2005, Pages 110-117

  Bradley, Scott A ^a   Krishnamurthy, Krish ^a   Hu, Haitao ^a  

^a ELI LILLY AND COMPANY   (United States)

Author keywords

BASHD TOCSY; DOSY; NMR spectral editing; Selective TOCSY edited preparation; STEP DOSY; TOCSY DOSY; Zero quantum coherence

Indexed keywords

DIFFUSION; MAGNETIZATION; MATRIX ALGEBRA; MIXING; PROTONS; SPECTRUM ANALYSIS; THREE DIMENSIONAL;

BASHD-TOCSY; DOSY; NMR SPECTRAL EDITING; SELECTIVE TOCSY EDITED PREPARATION; STEP-DOSY; TOCSY-DOSY; ZERO-QUANTUM COHERENCE;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CARBOHYDRATE; RAFFINOSE; SUCROSE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SIGNAL PROCESSING;

CARBOHYDRATES; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; RAFFINOSE; SIGNAL PROCESSING, COMPUTER-ASSISTED; SUCROSE;

EID: 10444240170     PISSN: 10907807     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jmr.2004.10.004     Document Type: Article

References (38)

1. K.F. Morris, C.S. Johnson, Diffusion-ordered two dimensional nuclear magnetic resonance spectroscopy, J. Am. Chem. Soc. 114 (1992) 3139-3141.
2. C.S. Johnson, Diffusion ordered nuclear magnetic resonance spectroscopy: principles and applications, Prog. NMR Spectrosc. 34 (1999) 203-256.
3. D.H. Wu, A.D. Chen, C.S. Johnson, Three-dimensional diffusion-ordered NMR spectroscopy: the homonuclear COSY-DOSY experiment, J. Magn. Reson. A 121 (1996) 88-91.
4. E.K. Gozansky, D.G. Gorenstein, DOSY-NOESY: diffusion-ordered NOESY, J. Magn. Reson. Bill (1996) 94-96.
5. A. Jerschow, N. Müller, 3D diffusion-ordered TOCSY for slowly diffusing molecules, J. Magn. Reson. A 123 (1996) 222-225.
6. M.F. Lin, M.J. Shapiro, Mixture analysis in combinatorial chemistry. Application of diffusion-resolved NMR spectroscopy, J. Org. Chem. 61 (1996) 7617-7619.
7. H. Barjat, G.A. Morris, A.G. Swanson, A three-dimensional DOSY-HMQC experiment for the high-resolution analysis of complex mixtures, J. Magn. Reson. 131 (1998) 131-138.
8. L.H. Lucas, W.H. Otto, C.K. Larive, The 2D-J-DOSY experiment: resolving diffusion coefficients in mixtures, J. Magn. Reson. 156 (2002) 138-145.
9. A.M. Dixon, C.K. Larive, NMR spectroscopy with spectral editing for the analysis of complex mixtures, Appl. Spectrosc. 53 (1999) 426A-440A.
10. W.H. Otto, C.K. Larive, Improved spin-echo-edited NMR diffusion measurements, J. Magn. Reson. 153 (2001) 273-276.
11. M.J. Gradwell, H. Kogelberg, T.A. Frenkiel, Applying excitation sculpting to construct singly and doubly selective 1D NMR experiments, J. Magn. Reson. 124 (1997) 267-270.
12. G. Xu, J.S. Evans, The application of "excitation sculpting" in the construction of selective one-dimensional homonuclear coherence-transfer experiments, J. Magn. Reson. B 111 (1996) 183-185.
13. P. Adell, T. Parella, F. Sanchez-Ferrando, A. Virgili, Gradient selection in pseudo-3D experiments, J. Magn. Reson. A 113 (1995) 124-127.
14. D. Uhrín, P.N. Barlow, Gradient-enhanced one-dimensional proton chemical-shift correlation with full sensitivity, J. Magn. Reson. 126 (1997) 248-255.
15. L. Poppe, H. van Halbeek, NOE measurements on carbohydrates in aqueous solution by double-selective pseudo-3D TOCSY-ROESY and TOCSY-NOESY. Application to Gentiobiose, J. Magn. Reson. 96 (1992) 185-190.
16. H.T. Hu, S.A. Bradley, K. Krishnamurthy, Extending the limits of the selective 1D NOESY experiment with an improved selective TOCSY edited preparation function, J. Magn. Reson. 171 (2004) 201-206.
17. K. Stott, J. Stonehouse, J. Keeler, T.-L. Hwang, A.J. Shaka, Excitation sculpting in high-resolution nuclear magnetic resonance spectroscopy: application to selective NOE experiments, J. Am. Chem. Soc. 117 (1995) 4199-4200.
18. E. Kupče, P. Schmidt, M. Rance, G. Wagner, Adiabatic mixing in the liquid state, J. Magn. Reson. 135 (1998) 361-367.
19. M.D. Pelta, H. Barjat, G.A. Morris, A.L. Davis, S.J. Hammond, Pulse sequences for high-resolution diffusion-ordered spectroscopy (HR-DOSY), Magn. Reson. Chem. 36 (1998) 706-714.
20. K. Straubinger, F. Schick, O. Lutz, Relaxation of AB spin systems in stimulated-echo spectroscopy, J. Magn. Reson. B 109 (1995) 251-258.
21. S. Macura, Y. Huang, D. Suter, R.R. Ernst, Two-dimensional chemical exchange and cross-relaxation spectroscopy of coupled nuclear spins, J. Magn. Reson. 43 (1981) 259-281.
22. S. Macura, K. Wüthrich, R.R. Ernst, Separation and suppression of coherent transfer effects in two-dimensional NOE and chemical exchange spectroscopy, J. Magn. Reson. 46 (1982) 269-282.
23. M. Rance, G. Bodenhausen, G. Wagner, K. Wüthrich, R.R. Ernst, A systematic approach to the suppression of J cross peaks in 2D exchange and 2D NOE spectroscopy, J. Magn. Reson. 62 (1985) 497-510.
24. 0 fields, J. Magn. Reson. A 105 (1993) 167-183.
25. G. Estcourt, A.L. Davis, J. Keeler, Suppression of zero-quantum interference in two-dimensional z-COSY spectra, J. Magn. Reson. 96 (1992) 191-198.
26. M.J. Thrippleton, J. Keeler, Elimination of zero-quantum interference in two-dimensional NMR spectra, Angew. Chem. Int. Ed. Engl. 42 (2003) 3938-3941.
27. K.E. Cano, M.J. Thrippleton, J. Keeler, A.J. Shaka, Cascaded z-filters for efficient single-scan suppression of zero-quantum coherence, J. Magn. Reson. 167 (2004) 291-297.
28. D.H. Wu, A.D. Chen, C.S. Johnson Jr., An improved diffusion-ordered spectroscopy experiment incorporating bipolar-gradient pulses, J. Magn. Reson. A 115 (1995) 260-264.
29. A. Jerschow, N. Müller, Suppression of convection artifacts in stimulated-echo diffusion experiments. Double-stimulated-echo experiments, J. Magn. Reson. 125 (1997) 372-375.
30. M.D. Pelta, G.A. Morris, M.J. Stchedroff, S.J. Hammond, A one-shot sequence for high-resolution diffusion-ordered spectroscopy, Magn. Reson. Chem. 40 (2002) S147-S152.
31. V.V. Krishnamurthy, Application of semi-selective excitation sculpting for homonuclear decoupling during evolution in multi-dimensional NMR, Magn. Reson. Chem. 35 (1997) 9-12.
32. A.L. Van Geet, Calibration of the methanol and glycol nuclear magnetic resonance thermometers with a static thermistor probe, Anal. Chem. 40 (1968) 2227-2229.
33. L.G. Longsworth, The mutual diffusion of light and heavy water, J. Phys. Chem. 64 (1960) 1914-1917.
34. E. Kupče, R. Freeman, Techniques for multisite excitation, J. Magn. Reson. A 105 (1993) 234-238.
35. H. Geen, R. Freeman, Band-selective radiofrequency pulses, J. Magn. Reson. 93 (1991) 93-141.
36. A.J. Shaka, C.J. Lee, A. Pines, Iterative schemes for bilinear operators - application to spin decoupling, J. Magn. Reson. 77 (1988) 274-293.
37. E. Kupče, R. Freeman, Optimized adiabatic pulses for wideband spin inversion, J. Magn. Reson. A 118 (1996) 299-303.
38. E.O. Stejskal, J.E. Tanner, Spin diffusion measurements - spin echoes in presence of a time-dependent field gradient, J. Chem. Phys. 42 (1965) 288.