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Volumn 33, Issue 8 SUPPL.1, 1998, Pages 119-128

Disappearing and reappearing polymorphs - An anathema to crystal engineering?

Author keywords

Chemical microscopy; Crystallization conditions; Historical perspective; Metastable phases; Polymorphism; Thermomicroscopy

Indexed keywords


EID: 1042296567     PISSN: 00255408     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (9)

References (58)
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    • A. Gavezzotti and G.Fillipini, J. Am. Chem. Soc. 117, 12299 (1995); H.R. Karfunkel, Z.J. Wu, A. Burkhard, G. Rihs, D. Sinnreich, H.M. Buerger, and J. Stanek, Acta Cryst. B52, 555 (1995), and references therein.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 12299
    • Gavezzotti, A.1    Fillipini, G.2
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    • April 9
    • C. Leadbeater, Financial Times, April 9, 1991, p.1; Wall Street Journal, Sept. 20, 1993, p. A5B; U.S. District Court, Eastern District of North Carolina, No. 91-759-CIV-5-BO Glaxo v. Novopharm; J.-O. Henck, U.J. Griesser, and A. Burger, Pharm. Ind. 58, 165 (1997).
    • (1991) Financial Times , pp. 1
    • Leadbeater, C.1
  • 5
    • 0030942345 scopus 로고    scopus 로고
    • Sept. 20, U.S. District Court, Eastern District of North Carolina, No. 91-759-CIV-5-BO Glaxo v. Novopharm
    • C. Leadbeater, Financial Times, April 9, 1991, p.1; Wall Street Journal, Sept. 20, 1993, p. A5B; U.S. District Court, Eastern District of North Carolina, No. 91-759-CIV-5-BO Glaxo v. Novopharm; J.-O. Henck, U.J. Griesser, and A. Burger, Pharm. Ind. 58, 165 (1997).
    • (1993) Wall Street Journal
  • 6
    • 0030942345 scopus 로고    scopus 로고
    • C. Leadbeater, Financial Times, April 9, 1991, p.1; Wall Street Journal, Sept. 20, 1993, p. A5B; U.S. District Court, Eastern District of North Carolina, No. 91-759-CIV-5-BO Glaxo v. Novopharm; J.-O. Henck, U.J. Griesser, and A. Burger, Pharm. Ind. 58, 165 (1997).
    • (1997) Pharm. Ind. , vol.58 , pp. 165
    • Henck, J.-O.1    Griesser, U.J.2    Burger, A.3
  • 13
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    • Martini Publishing, New York
    • Dalton actually inscribed the principles of the atomic structure of matter in his notebook on 6 Sept. 1803, and lectured on them at the Royal Institution on 22 December of the same year. The formal publication did not come until five years later. See J.R. Partington, A History of Chemistry, " Vol. 3, Martini Publishing, New York, 1961.
    • (1961) A History of Chemistry , vol.3
    • Partington, J.R.1
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    • W.F. Ostwald, Z. Phys. Chem. 22, 289 (1897); W.F. Ostwald, Lehrbuch der Allgemein Chemie, Engelmann, Leipzig, 2nd ed. Part 1 (1902), pp. 448-49.
    • (1897) Z. Phys. Chem. , vol.22 , pp. 289
    • Ostwald, W.F.1
  • 15
    • 33646251950 scopus 로고
    • Engelmann, Leipzig, 2nd ed.
    • W.F. Ostwald, Z. Phys. Chem. 22, 289 (1897); W.F. Ostwald, Lehrbuch der Allgemein Chemie, Engelmann, Leipzig, 2nd ed. Part 1 (1902), pp. 448-49.
    • (1902) Lehrbuch der Allgemein Chemie , Issue.1 PART , pp. 448-449
    • Ostwald, W.F.1
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    • ed. J. Lima-de-Faria, Chapter 3, Kluwer Academic Publishers, Dordrecht
    • See M. Senechal, Historical Atlas of Crystallography, ed. J. Lima-de-Faria, Chapter 3, Kluwer Academic Publishers, Dordrecht (1990).
    • (1990) Historical Atlas of Crystallography
    • Senechal, M.1
  • 17
    • 33748216139 scopus 로고
    • For instance, see B. Kahr and M. McBride, Angew. Chem. Int. Ed. Eng. 31, 1 (1992) for an account of the historical development of the phenomenon of optical anomalies, a field which went dormant for nearly half a century for reasons similar to those involving activity in the field of polymorphism.
    • (1992) Angew. Chem. Int. Ed. Eng. , vol.31 , pp. 1
    • Kahr, B.1    McBride, M.2
  • 19
    • 0008906910 scopus 로고
    • Chapter 3, Kluwer Academic Publishers, Dordrecht
    • The polarizing microscope had developed to its modern form essentially by 1879; see Historical Atlas of Crystallography, ed. J. Lima-de-Faria, Chapter 3, (1990), pp. 68-69, Kluwer Academic Publishers, Dordrecht.
    • (1990) Historical Atlas of Crystallography , pp. 68-69
    • Lima-de-Faria, J.1
  • 30
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    • personal communication.
    • D.Y. Curtin, personal communication.
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  • 34
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    • note
    • In 1956 McCrone founded McCrone Associates, a private analytical laboratory in which the principal analytical technique employed was polarized light spectroscopy. Over the years he and his staff learned to visually identify over 30,000 particles [27]. McCrone Associates specialized in the identification of asbestos samples, airborne impurities, and the identification and classification polymorphism, among others. McCrone recently partially endowed a chair of chemical microscopy to Cornell University.
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    • personal communication
    • S.R. Byrn, personal communication.
    • Byrn, S.R.1
  • 46
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    • note
    • Although we carried out a rather thorough literature search prior to beginning our crystallization experiments, we did not locate reference 41. It did not come up in a citation search, since it did not cite the original Nielsen/Borka paper. Another reason is that other searches were based on "benzocaine" while reference 41 refers to the molecule as ethyl aminobenzoate. One of us (J.B.) came across reference 41 in his own reprint collection subsequent to our determination of the structure of the 2:1 complex. This incident simply demonstrates the reproducibility of these phenomena, and the necessity for keen observation to characterize a system.
  • 47
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    • Pennsylvania State University Press, University Park, PA
    • H.K. Henisch, Crystallization in Gels, Pennsylvania State University Press, University Park, PA, (1970).
    • (1970) Crystallization in Gels
    • Henisch, H.K.1
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    • Ph. D. thesis, University of Marburg
    • K. Schaeling, Ph. D. thesis, University of Marburg (1910).
    • (1910)
    • Schaeling, K.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.