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Volumn 10, Issue 1, 1996, Pages 235-242

Study of hydrogen shuttling reactions in anthracene/9,10-dihydroanthracene-naphthyl-X mixtures

Author keywords

[No Author keywords available]

Indexed keywords


EID: 1042270445     PISSN: 08870624     EISSN: None     Source Type: Journal    
DOI: 10.1021/ef950128f     Document Type: Article
Times cited : (19)

References (42)
  • 17
    • 85033808508 scopus 로고    scopus 로고
    • note
    • 0 = 16.5 kcal/mol; α= 0.65 and ΔH = 14.7 kcal/mol.
  • 19
    • 85033820155 scopus 로고    scopus 로고
    • note
    • The entropy contribution in the equilibrium constant is very small. The reaction path degeneracy for the forward and backward reaction and spin factors result in ΔS = 0.6 eu. ΔH = 31.6 kcal/mol.
  • 20
    • 85033819891 scopus 로고    scopus 로고
    • note
    • -1
  • 21
    • 85033830498 scopus 로고    scopus 로고
    • note
    • In this discussion the influence of the substituent on the BDE (C-H) in the adduct radical (e.g., I) is ignored; however, this is not likely to affect the RHT/RRD ratio.
  • 22
    • 84986773640 scopus 로고
    • a of 30 kcal/mol. Note that additions to naphthalene and benzene have comparable activation energies
    • a of 30 kcal/mol. Note that additions to naphthalene and benzene have comparable activation energies.
    • (1977) Int. J. Chem. Kinet. , vol.9 , pp. 185
    • Holt, P.N.1    Kerr, J.A.2
  • 23
    • 85033825905 scopus 로고    scopus 로고
    • note
    • f(naphthalene).
  • 27
    • 85033815694 scopus 로고    scopus 로고
    • note
    • 31
  • 28
    • 85033826985 scopus 로고    scopus 로고
    • note
    • 22
  • 32
    • 85033828966 scopus 로고    scopus 로고
    • note
    • 15 exp(-62 kcal/mol/RT) in 1 h, a conversion of 0.3% is reached at 370 °C.
  • 34
    • 85033806028 scopus 로고    scopus 로고
    • note
    • 12-z; n = 0-12.
  • 35
    • 3242869507 scopus 로고
    • Thesis, Leiden University, The Netherlands
    • Arends, I. W. C. E. Thesis, Leiden University, The Netherlands, 1993.
    • (1993)
    • Arends, I.W.C.E.1
  • 41
    • 85033808175 scopus 로고    scopus 로고
    • note
    • 31
  • 42
    • 85033808996 scopus 로고    scopus 로고
    • note
    • 17 of 28.9 kcal/mol.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.