Hydroxypyridinone extraction agents for Pu(IV)

Solvent Extraction and Ion Exchange

Volumn 22, Issue 6, 2004, Pages 1037-1068

  Veeck, Alan C ^a,b   White, David J ^a   Whisenhunt Jr , Donald W ^a,b   Xu, Jide ^a   Gorden, Anne E V ^a   Romanovski, Vadim ^b   Hoffman, Darleane C ^a,b   Raymond, Kenneth N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE LIVERMORE NATIONAL LABORATORY   (United States)

Author keywords

Decontamination factor; Dicyclohexylurea; Dimethylaminopyridine; Hydroxypyridinone

Indexed keywords

NITRIC ACID; ORGANIC COMPOUNDS; REACTION KINETICS; SYNTHESIS (CHEMICAL);

CHELATING MOIETIES; EXTRACTION AGENTS;

SOLVENT EXTRACTION;

SOLVENT EXTRACTION;

EID: 10244255141     PISSN: 07366299     EISSN: None     Source Type: Journal    
DOI: 10.1081/SEI-200037773     Document Type: Article

References (28)

1. Nash, K.L. Aqueous complexes in f-element separation science. In Metallon Separation and Preconcentration: Progress and Opportunities; Bond, A.H., Dietz, M.L., Rogers, R.M., Eds.; Oxford University Press: Washington, DC, 1999; 52-79.
2. National Research Council. In Nuclear Wastes: Technologies for Separations and Transmutations; National Academy Press: Washington, DC, 1996.
3. Johnson, J. DOE needs new waste separation technology. Chem. Eng. News 2002, 80, 24-33.
4. Gorden, A.E.V.; Xu, J.; Raymond, K.N.; Durbin, P.W. The rational design of sequestering agents for plutonium and other actinide elements. Chem. Rev. 2003, 103, 4207 -4282.
5. Stintzi, A.; Barnes, C.; Xu, J.; Raymond, K.N. Microbial iron transport via a siderophore shuttle: a new membrane ion transport paradigm. Proc. Natl. Acad. Sci. USA 2000, 97, 10691-10696.
6. Turcot, I.; Stintzi, A.; Xu, J.; Raymond, K.N. Fast biological iron chelators: kinetics of iron removal from human diferric transferrin by multidentate hydroxypyridonates. J. Biol. Inorg. Chem. 2000, 5, 634-641.
7. Zhao, P.H.; Romanovski, V.V.; Whisenhunt, D.W.; Hoffman, D.C.; Mohs, T.R.; Xu, J.D.; Raymond, K.N. Extraction of plutonium by chelating hydroxypyridinone and catecholamide resins. Solv. Extr. Ion Exch. 1999, 17, 1327-1353.
8. Gramer, C.J.; Raymond, K.N.; Jarvinen, G.D.; Schroeder, N.C.; Robison, T.W.; Smith, B.F. The removal of dilute concentrations of Pu(IV) from waste streams using 2,3-dihydroxyterephthalamide functionalized PEI and polymer filtration. Sep. Sci. Technol. 2003, 39, 321-339.
9. White, D.L.; Durbin, P.W.; Jeung, N.; Raymond, K.N. Specific sequestering agents for the actinides. 16. Synthesis and initial biological testing of polydentate oxohydroxpyridinecarboxylate ligands,. J. Med. Chem. 1988, 31, 11-18.
10. Xu, J.; Kullgren, B.; Durbin, P.W.; Raymond, K.N. Specific sequestering agents. 28. Synthesis and initial evaluation of multidentate 4-carbamoyl 3-hydroxy-l-methyl-2(IH)-pyridinone ligands for in vivo plutonium (IV) chelation. J. Med. Chem. 1995, 38, 2606 - 2614.
11. Harris, R.L.N. Potential wool growth inhibitors. Improved syntheses of mimosine and related 4(1H)-pyridinones. Aust. J. Chem. 1976, 29, 1329.
12. Hart, N.K.; Hoffman, A.; Lamperton, J.A.; Richards, C.M. Mimosine, mimosinamine and 3,4-dihydroxypyridine. Heterocycles 1977, 7, 265-272.
13. Hider, R.C.; Kontoghiorghes, G.J.; Silver, J. Pharmaceutical compositions of N-substituted 3-hydroxy-2- or -4-pyridinones. Brit. UK Pat. Appl., UK, 1984.
14. Hider, R.C.; Kontoghiorghes, G.J.. Pharmaceutical compositions of hydroxypyridinones. U.S. Patent No. 4,666,927, 1987.
15. 2+ complexes of linear tetradentate 1-methyl-3-hydroxy-2(IH)-pyridinone ligands. Inorg. Chem. 1999, 38, 308-315.
16. Färber, M.; Osiander, H.; Severin, T. Synthesis of N-substituted 3hydroxy-2- methyl-4-pyridinones and -pyridonimines. J. Heterocyclic. Chem. 1994, 31, 947-956.
17. Neu, M.P. Coordination chemistry of two heavy metals: 1. Ligand preferences in Lead(II) complexation, toward the development of therapeutic agents for lead poisoning. II. Plutonium solubility and speciation relevant to the environment. In Chemistry; University of California, Berkeley: Berkeley, 1993.
18. Raymond, K.N.; Freeman, G.E.; Kappel, M.J. Actinide-specific complexing agents: their structural. Inorg. Chem. Acta 1984, 94, 193-194.
19. Martell, A.E.; Smith, R.N. Critical Stability Constants; Plenum: New York, 1974.
20. Lumetta, G.J.; Wagner, M.J.; Carlson, C.D. Actinide, strontium, and cesium removal from Hanford radioactive sludge. Solv. Extr. Ion Exch. 1996, 14, 35.
21. Cleveland, J.M. The Chemistry of Plutonium; American Nuclear Society: La Grange Park, IL, 1979, and references therein.
22. Romanovski, V.V., Whiesenhunt, D.W. Jr.; Veeck, A.C.; Andersen, R.A.; Hoffman, D.C.; Xu, J.; White, D.J.; Raymond, K.N. Potential agents for removal of actinides from waste solutions. In Intemational Topical Meeting on Nuclear and Hazardous Waste Management; American Nuclear Society, LaGrange Park, IL: Seattle, Washington, 1996; Vol. 3, 2330-2334.
23. Romanovski, V.V.; White, D.J.; Xu, J.; Hoffman, D.C.; Raymond, K.N. Plutonium (IV) and plutonium (VI) extraction, by 1,2-hydroxy-6-N-octylcarboxamide-2 (1H)-pyridinone. Solv. Extr. Ion Exch. 1999, 17, 55-71.
24. Baes, C.F.; Mesmer, R.E. The Hydrolysis of Cations; Wiley: New York, 1986.
25. Xu, J.; Stack, T.D.P.; Raymond, K.N. An eight-coordinate cage: synthesis and structure of the first macrotricyclic tetraterephthalamide ligand. Inorg. Chem. 1992, 31, 903-4905.
26. Allen, G.K. Estimated inventory of chemicals added to underground waste tanks, 1944-1975, Technical Report ARH-CD-6108, Pacific Northwest National Laboratory, Research and Engineering Division, 1976.
27. Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.; Diamond, H.; Nelson, D.M. Separation and preconcentration of actinides from acidic media by extraction chromatography. Anal. Chim. Acta 1993, 281, 361-372.
28. Horwitz, E.P.; Diamond, H.; Gatrone, R.C.; Nash, K.L.; Rickert, P. In Proceedings of the International Solvent Extraction Conference; Elsevier: New York, 1990.