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The proposal for dimeric structures in LO cuprates has been confirmed by molecular weight determinations and NMR spectroscopy and amply demonstrated by X-ray crystallography:, and references cited therein
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The proposal for dimeric structures in LO cuprates has been confirmed by molecular weight determinations and NMR spectroscopy and amply demonstrated by X-ray crystallography: Snyder, J. P.; Tipsword, G. E.; Spangler, D. P. J. Am. Chem. Soc. 1992, 114, 1507 and references cited therein.
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Although literature data suggest a higher stability with aromatic groups, a structure in LO cuprates in which the alkyl bridge again involves a three-center two-electron bond, with linear coordination at copper, has also been demonstrated
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Although literature data suggest a higher stability with aromatic groups, a structure in LO cuprates in which the alkyl bridge again involves a three-center two-electron bond, with linear coordination at copper, has also been demonstrated: Jarvis, J. A. J.; Kilbourn, B. T.; Pearce, R.; Lappert, M. F. J. Chem. Soc., Chem. Commun. 1973, 475.
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The oxidation potential data for Ph (<−0.1 V) and Me (−0.5 V), Springer: Berlin) suggest a decrease in hardness in moving from the aromatic to the aliphatic series and therefore support a more favorable interaction of aromatic and heteroaromatic ligands as compared with that of the alkyl groups with the harder N heteroatom
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The oxidation potential data for Ph (<−0.1 V) and Me (−0.5 V) (Eberson, L. In Electron transfer reactions in Organic Chemistry; Springer: Berlin, 1987) suggest a decrease in hardness in moving from the aromatic to the aliphatic series and therefore support a more favorable interaction of aromatic and heteroaromatic ligands as compared with that of the alkyl groups with the harder N heteroatom.
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