An example of falsified kinetics by diffusional limitations in gas-solid catalytic reactions

International Journal of Engineering Education

Volumn 20, Issue 6, 2004, Pages 1074-1084

  Pina, Pilar ^a   Mallada, Reyes ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC REACTIONS; HETEROGENEOUS CATALYSTS; PERMEATION FLUX;

ACTIVATION ENERGY; DIFFUSION; GASES; MASS TRANSFER; PLATINUM; POROSITY; REACTION KINETICS;

CATALYSIS;

EID: 10044258694     PISSN: 0949149X     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (12)

1. G. F., Froment and K. B. Bischoff, Chemical Reactor Analysis & Design, 2nd ed., Wiley Series in Chemical Engineering, John Wiley & Sons, New York (1990).
2. O. Levenspiel, Chemical Reaction Engineering, 3rd ed., John Wiley & Sons, New York (1999).
3. J. J. Spivey, Complete catalytic oxidation of volatile organic compounds, Ind. Eng. Chem. Res., 26, 1987, p. 2165.
4. M. P. Pina, S. Irusta, M. Menéndez and J. Santamaría, Combustion of volatile organic compounds over platinum-based catalytic membranes, Ind. Eng. Chem. Res., 36, 1997, p. 4557.
5. M. P. Pina, M. Menéndez and J. Santamaría, The Knudsen diffusion catalytic membrane reactor: an efficient contactor for the combustion of volatile organic compounds, Appl. Catal. B. Environmental, 11, 1996, p. L19.
6. S. Zalamea, M. P. Pina, A. Villellas, M. Menéndez and J. Santamaría, Combustion of volatile organic compounds over mixed-regime catalytic membranes, React. Kinet. Catal. Lett., 67(1), 1999, p. 13.
7. L. M. Gandía, A. Gil, S.A Korili, Effects of various alkali-acid additives on the activity of a manganese oxide in the catalytic combustion of ketones, Appl. Catal. B. Environmental, 33(1), 2001.
8. R. P. Hesketh, D. Bosak and L. Kline, Automotive catalytic reaction engineering experiment, Chem. Eng. Ed., 34(3), 2000, p. 241.
9. S. Saddawi and R. A. Schmitz, Experiments with a fixed-bed catalytic reactor, Chem. Eng. Ed., 36(1), 2002, p. 58.
10. S. C. Paspek, A. Varma and J. J. Carberry, Utilization of the recycle reactor in determining kinetics of gas-solid catalytic reactions, Chem. Eng. Ed., 14(1), 1980, p. 78.
11. C. Finol and J. Coronas, Permeation of gases in asymmetric membranes, Chem. Eng. Ed., 33(1), 1999, p. 58.
12. Y. S. Lin and A. J. Burggraaf, Preparation and characterization of high temperature thermally stable alumina composite membrane, J. Am. Ceram. Soc., 74, 1991, p. 219.