Cubic, hydrogen-bonded (10,3)-a networks in the family [C(NH 2)3][N(CH3)4][XO4] (X = S, Cr, and Mo)

Angewandte Chemie - International Edition

Volumn 43, Issue 45, 2004, Pages 6157-6160

  Abrahams, Brendan F ^a   Haywood, Marissa G ^a   Hudson, Timothy A ^a   Robson, Richard ^a  

^a UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

Coordination modes; Crystal engineering; Hydrogen bonds; Structure elucidation; Supramolecular chemistry

Indexed keywords

CRYSTAL STRUCTURE; HYDROGEN BONDS; X RAYS;

CHIRAL COMPOUNDS; GUANIDINIUM IONS; HYDROGEN-BONDED NETWORKS;

SULFUR;

CHROMIUM DERIVATIVE; COORDINATION COMPOUND; GUANIDINE DERIVATIVE; GUANIDINIUM BORATE; GUANIDINIUM DERIVATIVE; HYDROGEN; MOLYBDENUM COMPLEX; SULFONIC ACID DERIVATIVE; SULFUR DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; GEOMETRY; HYDROGEN BOND; STRUCTURE ANALYSIS; SUPRAMOLECULAR CHEMISTRY; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

CHROMIUM; CRYSTALLOGRAPHY, X-RAY; HYDROGEN BONDING; METALS, HEAVY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; SULFUR;

EID: 10044248336     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461678     Document Type: Article

References (21)

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4. B. F. Abrahams, M. G. Haywood, R. Robson, unpublished results.
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6. K. T. Holman, A. M. Pivovar, M. D. Ward, Science 2001, 294, 1907; K. T. Holman, S. M. Martin, D. P. Parker, M. D. Ward, J. Am. Chem. Soc. 2001, 123, 4421; V. A. Russell, M. D. Ward, Chem. Mater. 1996, 8, 1654.
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8. A. F. Wells, Three-Dimensional Nets and Polyhedra, Wiley-Interscience, New York, 1977, p. 35.
9. 3 (130 mg, 0.925 mmol) and guanidinium chloride (160 mg, 1.85 mmol) were dissolved in a hot solution of tetramethylammonium hydroxide (1 mL of 25% w/w in methanol, 2.4 mmol) and water (1 mL). Hot dimethylformamide (4 mL) was added and colorless crystals, which were deliquescent, separated after one day at room temperature. A single crystal was removed, immersed in oil and cooled as quickly as possible prior to collecting X-ray diffraction data.
10. 2 using a full-matrix least-squares refinement;[12] hydrogen atoms were included at geometrically estimated positions. CCDC-247060-247062 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
11. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998, 37, 1475.
12. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998, 37, 1475.
13. G. R. Desiraju, Acc. Chem. Res. 1996, 29, 441.
14. 2 net is considered in the Supporting Information.
15. P. Dera, A. Katrusiak, M. Szafranski, Pol. J. Chem. 2000, 74, 1637.
16. I. Boldog, E. B. Rusanov, J. Sieler, S. Blaurock, K. V. Domasevitch, Chem. Commun. 2003, 740; L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 12861; S. C. Abrahams, R. L. Collin, W. N. Lipscomb, Acta Crystallogr. 1951, 4, 15; M. Tadokoro, T. Shiomi, K. Isobe, K. Nakasuji, Inorg. Chem. 2001, 40, 5476; L. Denner, P. Luger, J. Buschmann, Acta Crystallogr. Sect. C 1988, 44, 1979. (The structure of cyanamide reported in the latter reference was recognised as two interpenetrating (10,3)-a nets in ref. [6].)
17. I. Boldog, E. B. Rusanov, J. Sieler, S. Blaurock, K. V. Domasevitch, Chem. Commun. 2003, 740; L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 12861; S. C. Abrahams, R. L. Collin, W. N. Lipscomb, Acta Crystallogr. 1951, 4, 15; M. Tadokoro, T. Shiomi, K. Isobe, K. Nakasuji, Inorg. Chem. 2001, 40, 5476; L. Denner, P. Luger, J. Buschmann, Acta Crystallogr. Sect. C 1988, 44, 1979. (The structure of cyanamide reported in the latter reference was recognised as two interpenetrating (10,3)-a nets in ref. [6].)
18. I. Boldog, E. B. Rusanov, J. Sieler, S. Blaurock, K. V. Domasevitch, Chem. Commun. 2003, 740; L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 12861; S. C. Abrahams, R. L. Collin, W. N. Lipscomb, Acta Crystallogr. 1951, 4, 15; M. Tadokoro, T. Shiomi, K. Isobe, K. Nakasuji, Inorg. Chem. 2001, 40, 5476; L. Denner, P. Luger, J. Buschmann, Acta Crystallogr. Sect. C 1988, 44, 1979. (The structure of cyanamide reported in the latter reference was recognised as two interpenetrating (10,3)-a nets in ref. [6].)
19. I. Boldog, E. B. Rusanov, J. Sieler, S. Blaurock, K. V. Domasevitch, Chem. Commun. 2003, 740; L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 12861; S. C. Abrahams, R. L. Collin, W. N. Lipscomb, Acta Crystallogr. 1951, 4, 15; M. Tadokoro, T. Shiomi, K. Isobe, K. Nakasuji, Inorg. Chem. 2001, 40, 5476; L. Denner, P. Luger, J. Buschmann, Acta Crystallogr. Sect. C 1988, 44, 1979. (The structure of cyanamide reported in the latter reference was recognised as two interpenetrating (10,3)-a nets in ref. [6].)
20. I. Boldog, E. B. Rusanov, J. Sieler, S. Blaurock, K. V. Domasevitch, Chem. Commun. 2003, 740; L. Carlucci, G. Ciani, D. M. Proserpio, A. Sironi, J. Am. Chem. Soc. 1995, 117, 12861; S. C. Abrahams, R. L. Collin, W. N. Lipscomb, Acta Crystallogr. 1951, 4, 15; M. Tadokoro, T. Shiomi, K. Isobe, K. Nakasuji, Inorg. Chem. 2001, 40, 5476; L. Denner, P. Luger, J. Buschmann, Acta Crystallogr. Sect. C 1988, 44, 1979. (The structure of cyanamide reported in the latter reference was recognised as two interpenetrating (10,3)-a nets in ref. [6].)
21. G. M. Sheldrick, SHELX-97, Program for Crystal Structure Analysis, University of Gottingen, Gottingen (Germany), 1997.