(EDT-TTF-I2)2PbI3·H2O: An ambient pressure metal with a β′ donor slab topology

Journal of Materials Chemistry

Volumn 14, Issue 2, 2004, Pages 135-137

  Devic, Thomas ^a   Canadell, Enric ^b   Auban Senzier, Pascale ^c   Batail, Patrick ^a  

^a UNIVERSITÉ D'ANGERS   (France)

^b INSTITUT DE CIÈNCIA DE MATERIALS DE BARCELONA ICMAB CSIC   (Spain)

^c UNIVERSITÉ PARIS SUD   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC CONDUCTIVITY; POSITIVE IONS; PRESSURE EFFECTS;

ORGANIC RADICAL CATIONS;

LEAD COMPOUNDS;

CATION; ETHYLENE DERIVATIVE; ETHYLENEDITHIO 1,2 DIIODOTETRATHIAFULVALENE; METAL; RADICAL; UNCLASSIFIED DRUG; WATER;

ARTICLE; CONDUCTANCE; HYBRID; MOLECULE;

EID: 0942279533     PISSN: 09599428     EISSN: None     Source Type: Journal    
DOI: 10.1039/b312493b     Document Type: Article

References (12)

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4. x, for one particular composition (x = 0.66) upon doping by a mono-anion; see: H. Mori, M. Masakazu, M. Haemori, H. Suzuki, S. Tanaka, Y. Nisio, K. Kajita and H. Motiyama, J. Am. Chem. Soc., 2002, 124, 1251.
5. T. Devic, M. Evain, Y. Moëlo, E. Canadell, P. Auban-Senzier, M. Fourmigué and P. Batail, J. Am. Chem. Soc., 2003, 125, 3295.
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8. (a) M.-H. Whangbo, J. M. Williams, P. C. W. Leung, M. A. Beno, T. J. Emge and H. H. Wang, Inorg. Chem., 1985, 24, 3500;
9. (b) note that although there can be small differences in details the βHOMO-HOMO interaction energies and the associated transfer integrals (t) are obviously related and have the same physical meaning. However, because overlap is explicitly taken into account in extended Hückel calculations, the absolute values of β are somewhat larger than those of t. We use the β values here because it facilitates the comparison with other calculations for β ′ salts already reported in the literature.
10. 2 becomes a superconductor at 14.2 K under high hydrostatic pressure (8.2 GPa); see: H. Taniguchi, M. Miyashita, K. Uchiyama, K. Satoh, N. Mori, H. Okamoto, K. Miyagawa, K. Kanoda, M. Hedo and Y. Uwatoko, J. Phys. Soc. Jpn., 2003, 72, 468.
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