Ruthenium hydride complexes with a heteroscorpionate ligand derived from methane: 2-Phenoxy-bis(pyrazol-1-yl)methane. The hemilabile role of the ligand in substitution and proton transfer reactions

Polyhedron

Volumn 23, Issue 2-3, 2004, Pages 361-371

  Caballero, Agustín ^a   Carrión, M Carmen ^a   Espino, Gustavo ^b   Jalón, Félix A ^a   Manzano, Blanca R ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

^b UNIVERSITY OF BURGOS   (Spain)

Author keywords

Hemilabile ligands; Heteroscorpionates; Hydrides; Phosphine complexes; Ruthenium

Indexed keywords

ACETONE; LIGANDS; METHANE; METHANOL; PHOSPHORUS COMPOUNDS; PROTON TRANSFER; RUTHENIUM COMPOUNDS;

COMPLEX 1; HEMILABILE LIGAND; HETEROSCORPIONATE; METAL CENTRES; PHOSPHINE COMPLEX; POTASSIUM SALTS; PROTON TRANSFER REACTIONS; RUTHENIUM HYDRIDE COMPLEX; SYNTHESISED; TRIS(PYRAZOLYL)BORATES;

HYDRIDES;

2 PHENOXYBIS(PYRAZOL 1 YL)METHANE; ACETONE; LIGAND; METHANE; OXYGEN; PHOSPHINE DERIVATIVE; POTASSIUM SALT; RUTHENIUM DERIVATIVE; UNCLASSIFIED DRUG;

ACCURACY; AQUEOUS SOLUTION; ARTICLE; CIS ISOMER; COMPLEX FORMATION; CORRELATION ANALYSIS; DENSITY GRADIENT CENTRIFUGATION; DIASTEREOISOMER; DONOR; HEATING; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR MECHANICS; PROTON TRANSPORT; REACTION ANALYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; THERMODYNAMICS;

EID: 0842332885     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2003.11.023     Document Type: Article

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