The kinetics and mechanism of aquation and base hydrolysis of the cis-[Co(cyclen)Cl2]+ cation (cyclen = 1,4,7,10-tetraazacyclo-dodecane)

Transition Metal Chemistry

Volumn 22, Issue 3, 1997, Pages 248-253

  Hay, Robert W ^a   Norman, Paul R ^b  

^a UNIVERSITY OF ST ANDREWS   (United Kingdom)

^b UNIVERSITY OF STIRLING   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0842289780     PISSN: 03404285     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1018460307204     Document Type: Article

References (26)

1. ‡.
2. J. P. Collman and P. W. Schneider, Inorg. Chem., 5, 1380 (1966).
3. R. W. Hay and P. R. Norman, J. Chem. Soc., Dalton Trans., 1441 (1979).
4. Y. Hung and D. H. Busch, J. Am. Chem. Soc., 99, 4977 (1977).
5. R. W. Hay and P. R. Norman, J. Chem. Soc. Chem. Commun., 734 (1980).
6. H. S. Harned and R. A. Robinson, Trans. Faraday Soc., 36, 973 (1940).
7. C. W. Davies, J. Chem. Soc., 2093 (1938).
8. For general procedures see E. Ahmed and M. L. Tobe, Inorg. Chem., 13, 2956 (1974).
9. M. L. Tobe, Inorg. Chem., 7, 1260 (1968);
10. G. Jackson, Inorg. Chem., 17, 1348 (1978).
11. For extensive compilations of the rates of base hydrolysis of cobalt(III) complexes see M. L. Tobe, Adv. Inorg. Bioinorg. Chem., 2, 1 (1983).
12. E. Ahmed, M. L. Tucker and M. L. Tobe, Inorg. Chem., 14, 1 (1975).
13. For reviews see M. L. Tobe, Acc. Chem. Res., 3, 377 (1970);
14. T. W. Swaddle, Coord. Chem. Rev., 14, 217 (1974);
15. J. O. Edwards, F. Monacelli and G. Ortaggi, Inorg. Chim. Acta, 11, 47 (1974);
16. D. A. House, Coord. Chem. Rev., 23, 223 (1977). See also Ref. 10.
17. R. W. Hay, Inorg. Chim. Acta, 45, L83 (1980); see also Ref. 5.
18. J. W. Palmer and F. Basolo, J. Phys. Chem., 64, 778 (1960);
19. R. Bramley. I. I. Creaser, D. J. Mackey and A. M. Sargeson, Inorg. Chem., 17, 244 (1978).
20. M. E. Sosa and M. L. Tobe, J. Chem. Soc., Dalton Trans., 475 (1985).
21. S. E. Castillo-Blum and M. E. Sosa-Torres, Polyhedron, 14, 223 (1995).
22. P. Comba and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 51 (1985).
23. M. E. Sosa and M. L. Tobe, J. Chem. Soc., Dalton Trans., 475 (1985).
24. See for example, F. R. Nordmeyer, Inorg. Chem., 8, 2780 (1969).
25. R. J. Geue, T. W Hambley, J. McB. Harrowfield, A. M. Sargeson and M. R. Snow, J. Am. Chem. Soc., 106, 5478 (1984).
26. E. Ahmed, C. Chatterjee, C. J. Cooksey, M. L. Tobe, G. Williams and M. Humanes, J. Chem. Soc., Dalton Trans., 645 (1989).