A Duplex of Tetra(2-pyridyl)porphyrin and Tetrahydroxylcalix[4]arene

Chemistry Letters

Volumn 32, Issue 11, 2003, Pages 1052-1053

  Ohkawa, Haruki ^a   Arai, Satoshi ^a   Takeoka, Shinji ^a   Shibue, Toshimichi ^a   Nishide, Hiroyuki ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CALIXARENE; HYDROGEN; PORPHYRIN DERIVATIVE; TETRAHYDROXYCALIX[4]ARENE; TETRAKIS(2 PYRIDYL)PORPHYRIN; UNCLASSIFIED DRUG;

ARTICLE; CAPPING PHENOMENON; CHEMICAL STRUCTURE; HYDROGEN BOND;

EID: 0842285318     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.1052     Document Type: Article

References (24)

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20. -1 ascribed to the stretching vibration of the phenolic hydroxy groups. In the NMR spectrum, the OH signal was broadened, shifted due to the ring current effect, and overlapped with the signal b, after the duplex formation. This also supported the formation of hydrogen bonds.
21. Tetra(3-pyridyl)porphyrin did not form the duplex under the same conditions. No heterodimers were detected for the mixture solution of 5,11-or 5,17-dihydroxy-25,26,27,28-tetraoctyloxy-calix[4]arene and the porphyrin 1, whereas 5,17,23-trihydroxy-25,26,27,28-tetraoctyloxy-calix[4]arene formed the duplex with 1.
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23. 3 at -30°C ascribed to fast rotation of the pyridyl ring.
24. 3.