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Volumn 120, Issue 2, 2004, Pages 691-703

Spectroscopy of highly excited vibrational states of HCN in its ground electronic state

Author keywords

[No Author keywords available]

Indexed keywords

BAND STRUCTURE; BINDING ENERGY; CARBON; FLUORESCENCE; FREE RADICALS; HYDROGEN; LASER APPLICATIONS; NITROGEN; PHASE TRANSITIONS; PHOTODISSOCIATION;

EID: 0842268405     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1631253     Document Type: Article
Times cited : (13)

References (103)
  • 9
    • 84958724095 scopus 로고    scopus 로고
    • note
    • 3) = (CN stretch, bending mode, CH stretch). Many authors invert the labels of the two stretching modes to be consistent with modern conventions.
  • 83
    • 84958724097 scopus 로고    scopus 로고
    • note
    • Variational calculations carried out according to the procedure described in Ref. 102, using the Carter-Handy-Mills potential (Ref. 93) and the dipole moment function proposed by Botschwina (Ref. 103).
  • 90
    • 84958724098 scopus 로고    scopus 로고
    • note
    • 1Π excited state than the value used in our calculations.
  • 91
    • 84958724099 scopus 로고    scopus 로고
    • note
    • Collisional relaxation studies are a good example: since the first vibrational excitation populates a single rotational state, a very short delay between the pump and jump pulses combined with a low sample pressure would result in vibrational spectra consisting of a single rotational line in every branch of the spectrum. As the delay is increased, collisional relaxation populates the other rotational states in (0,0,4) and more lines appear in the spectra. Although we observed these effects in our experiment, in this work we decided to focus our efforts in the sdpectroscopic part.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.