Novel Structural Transformation around Ln(III) and Unusual Bending of Acetylacetonato Chelate in a Series of New 3d-4f Dinuclear Complexes [(hfac)3Ln(μ-bpypz)Cr(acac)2]

Chemistry Letters

Volumn 32, Issue 11, 2003, Pages 1084-1085

  Kawahata, Ryouji ^a   Tsukuda, Toshiaki ^a   Yagi, Takashi ^a   Subhan, Md Abdus ^a   Nakata, Hiroyasu ^a   Fuyuhiro, Akira ^a   Kaizaki, Sumio ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETOACETIC ACID DERIVATIVE; CHELATING AGENT; CHROMIUM DERIVATIVE;

ARTICLE; CHIRALITY; COMPLEX FORMATION; STEREOSPECIFICITY;

EID: 0842263683     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.1084     Document Type: Article

References (17)

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15. 18YbCr: C, 36.06 (36.05); H, 2.07 (1.99); N, 4.43 (4.49)%.
16. 1 = 0.0393.
17. Occupancies of the A and B forms were estimated to be about 70% and 30%, respectively, for the Cr-Sm complex. The 50% occupancy for both forms was found for the Cr-Nd complex.