Arylation of Heterocycles via Rhodium-Catalyzed C-H Bond Functionalization

Organic Letters

Volumn 6, Issue 1, 2004, Pages 35-38

  Lewis, Jared C ^a   Wiedemann, Sean H ^a   Bergman, Robert G ^a   Ellman, Jonathan A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE; HETEROCYCLIC COMPOUND; RHODIUM;

ARTICLE; ARYLATION; CATALYSIS; CHEMICAL BOND;

CATALYSIS; HETEROCYCLIC COMPOUNDS; IMIDAZOLES; MODELS, CHEMICAL; RHODIUM;

EID: 0742321839     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol035985e     Document Type: Article

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36. 3 protons, respectively, were observed during the reaction. This complex has not yet been characterized.
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40. 31P NMR spectrum. These peaks are consistent with exchange of phosphine on 14 to give a mixture of tricyclohexyl and cyclohexylcyclohexenyl phosphines.
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44. Itagaki et al. reported formation of 14 (vide infra) from 10 in cyclohexane solution in ref 12b.