Influence of Hydrotropes and Glycols on the Clouding Behavior of Surfactants (TritonX 100 and Brij 56) and Polymers (Polyvinylmethyl Ether and Triblock Co-Polymer, Pluronic 85)

Journal of Oleo Science

Volumn 52, Issue 10, 2003, Pages 523-534

  Prasad, M ^a   Moulik, S P ^a   Chisholm, D ^b   Palepu, R ^b  

^a JADAVPUR UNIVERSITY   (India)

^b ST FRANCIS XAVIER UNIVERSITY   (Canada)

Author keywords

Brij 56; cloud point; glycol; hydrotrope; Pluronic 85; polyethylene oxide; PVME; thermodynamics; TritonX 100

Indexed keywords

EID: 0742289716     PISSN: 13458957     EISSN: 13473352     Source Type: Journal    
DOI: 10.5650/jos.52.523     Document Type: Article

References (22)

1. D. MYERS, Surfactant Science and Technology, 2nd edn, VCH, New York, p. 22 (1992).
2. Y. MOROI, Micelles-Theoretical and Applied Aspects, Plenum Press, New York, Chap 4 (1992).
3. B. K. ROY and S. P. MOULIK, Functions of Hydrotropes (Sodi-um Salicylate, Proline, Pyrogallol, Resorcinol and Urea) in Solu0-tion with Special Reference to Amphiphile Behaviors, Colloids Surf. A., Vol. 203, 155-166 (2002).
4. S. GHOSH and S. P. MOULIK, The Clouding Behaviours of Binary Mixtures of Polyoxyethylene (10) Cetyl Ether (Brij-56) with Polyvinyl Alcohol (PVA) and Methyl Cellulose (MC), Ind. J. Chem., Vol. 38A, 201-208 (1999).
5. P. R. MAJHI, K. MUKHERJEE, S. P. MOULIK, S. SEN and N. P. SAHU, Solution Properties of a Saponin (Acaciaside) in the Presence of Triton X-100 and Igepal, Langmuir, Vol. 15, 6624-6630 (1999).
6. B. M. CORDERO, J. L. P. PAVON, C. G. PINTO and M. E. F. LAESPADA, Cloud Point Methodology: A New Approach for Preconcentration and Separation in Hydrodynamic Systems of Analysis, Talanta, Vol. 40, 1703-1710 (1993).
7. S. AKITA and H. TAKEUCHI, Cloud-Point Extraction of Organic Compounds from Aqueous Solutions with Nonionic Surfactant, Sep. Sci. Technol., Vol. 30, 833-846 (1995).
8. T. SAITOH and W. L. HINZE, Use of Surfactant-Mediated Phase Separation (Cloud Point Extraction) with Affinity Ligands for the Extraction of Hydrophilic Proteins, Talanta, Vol. 42, 119-127 (1995).
9. P. A. GALERA-GOMEZ and T. GU, Cloud Point of Mixtures of Polypropylene Glycol and Triton X-100 in Aqueous Solutions, Langmuir, Vol. 12, 2602-2604 (1996).
10. T. LIU, V. M. NACE and B. CHU, Cloud-Point Temperatures of BnEmBn and PnEmPn, J. Phys. Chem. B, Vol. 101, 8074-8078 (1997).
11. n Copolymers, Macromolecules, Vol. 29, 670-680 (1996).
12. 5 in Aqueous Solutions, Langmuir, Vol. 12, 5016-5021 (1996).
13. A. CHATTERJEE, B. K. ROY, S. P. MOULIK, N. P. SAHU and N. B. MONDAL, Saponin Induced Clouding Behavior of Triton X-100 and Methyl Cellulose, J. Disp. Sci. Technol., Vol. 23, 1-11 (2002).
14. S. GHOSH and S. P. MOULIK, Clouding of Binary Mixtures of Surfactants (Triton X-100 / Tween-20 / Brij-35) and Binary Sur-factant and Polymer Combinations (Brij-56 / Poly-vinyl Alcohol (PVA) and Brij-56 / Methyl Cellulose (MC)), J. Surf. Sci. Tech-nol., Vol. 14, 110-119 (1998).
15. N. M. VANOS, J. R. HAAK and L. A. M. RUPERT, Physico- Chemical Properties of Selected Anionic Cationic and Nonionic Surfactants, Elsevier, Amsterdam (1993).
16. P. D. T. HUIBERS, D. O. SHAH and A. R. KATRITZKY, Predict-ing Surfactant Cloud Point from Molecular Structure, J. Colloid Interface Sci., Vol. 193, 132 and references cited therein (1997).
17. n Oleyl Ether Systems, Langmuir, Vol. 17, 4717-4723 (2001).
18. T. GU and J. SIOBLOM, Surfactant Structure and its Relation to the Krafft Point, CP and Micellization; Some Empirical Rela-tionships, Colloids Surf., Vol. 64, 39-46 (1992).
19. G. SUGIHARA and M. HISATOMI, Enthalpy-Entropy Com-pensation Phenomenon Observed for Different Surfactants in Aqueous Solution, J. Colloid Interface Sci., Vol. 219, 31-36 (1999).
20. G. SUGIHARA, T. NAKANO, S. B. SULTHANA and A. K. RAKSHIT, Enthalpy-Entropy Compensation Rule and the Com-pensation Temperature Observed in Micelle Formation of Differ-ent Surfactants in Water. What is the so-called Compensation Temperature?, J. Oleo Sci., Vol. 50, 29-39 (2001).
21. H. J. ROSEN, Surfactants and Interfacial Phenomena, 2nd ed. Wiley, New York (1989).
22. J. A. MACINNIS, S. L. MACNEIL, S. E. BURKE and R. PALEPU, Physicochemical Properties of Aqueous Solutions of Sodium Dihydroxybenzoates, J. Surf. Sci. Technol., Vol. 16, 66-76 (2000).