A new, efficient, and simple method for the synthesis of thiiranes from epoxides under solvent-free conditions

Tetrahedron Letters

Volumn 45, Issue 6, 2004, Pages 1283-1285

  Kaboudin, Babak ^a   Norouzi, Hamid ^a  

^a INSTITUTE FOR ADVANCED STUDIES IN BASIC SCIENCES IASBS   (Iran)

Author keywords

Ammonium acetate; Diethylphosphite; Epoxides; Microwave; Thiiranes

Indexed keywords

ALKENE DERIVATIVE; ALUMINUM OXIDE; AMMONIUM ACETATE; EPOXIDE; THIIRANE; UNCLASSIFIED DRUG;

ARTICLE; MICROWAVE IRRADIATION; REACTION ANALYSIS; SYNTHESIS;

EID: 0742269721     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.11.099     Document Type: Article

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19. 3. All of the ammonium salts were removed by washing with an aq solution of sodium carbonate and then water. Chromatography through a plug of silica gel with EtOAc/n-hexane (1:9) and evaporation of the solvent under reduced pressure gave the pure products in 42-83% yields. The procedure was the same in the case of ammonium hydrogen carbonate. All the products gave satisfactory spectral data in accordance with the assigned structures.