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Volumn 45, Issue 3, 1997, Pages 753-759

Analysis of Steroidal Sapogenins from Amber Fenugreek (Trigonella foenum-graecum) by Capillary Gas Chromatography and Combined Gas Chromatography/Mass Spectrometry

Author keywords

Diosgenin; Fenugreek; Foliage; Quantitation; Seed; Spirostanols; Steroidal sapogenins

Indexed keywords

TRIGONELLA FOENUM; TRIGONELLA FOENUM GRAECUM;

EID: 0642367373     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf960200n     Document Type: Article
Times cited : (75)

References (45)
  • 1
    • 0014472035 scopus 로고
    • Experimental studies on the effect of Trigonella foenum-graecum
    • Abdo, M. S.; Al-Kafawi, A. A. Experimental studies on the effect of Trigonella foenum-graecum. Planta Med. 1969, 17, 14-18.
    • (1969) Planta Med. , vol.17 , pp. 14-18
    • Abdo, M.S.1    Al-Kafawi, A.A.2
  • 2
    • 0000944561 scopus 로고
    • Steroid sapogenins VII. Identification and origin of 25D-spirosta-3,5-diene among the fenugreek sapogenins
    • Bedour, M. S.; El-Munajjed, D.; Fayez, M. B. E.; Girgis, A. N. Steroid sapogenins VII. Identification and origin of 25D-spirosta-3,5-diene among the fenugreek sapogenins. J. Pharm. Sci. 1964, 53, 1276-1278.
    • (1964) J. Pharm. Sci. , vol.53 , pp. 1276-1278
    • Bedour, M.S.1    El-Munajjed, D.2    Fayez, M.B.E.3    Girgis, A.N.4
  • 3
    • 0018574235 scopus 로고
    • Epineotigogenin and epi-tigogenin, two new steroidal sapogenins from Cordyline cannifolia leaves
    • Blunden, G.; Jaffer, J. A.; Jewers, K.; Griffin, W. J. Epineotigogenin and epi-tigogenin, two new steroidal sapogenins from Cordyline cannifolia leaves. J. Nat. Prod. 1979, 42, 478-482.
    • (1979) J. Nat. Prod. , vol.42 , pp. 478-482
    • Blunden, G.1    Jaffer, J.A.2    Jewers, K.3    Griffin, W.J.4
  • 4
    • 0019164526 scopus 로고
    • Configurational assignments to spirostan-3-ols by mass spectrometry
    • Blunden, G.; Jaffer, J. A.; Jewers, K.; Robinson, J. M. Configurational assignments to spirostan-3-ols by mass spectrometry. Steroids 1980, 36, 299-303.
    • (1980) Steroids , vol.36 , pp. 299-303
    • Blunden, G.1    Jaffer, J.A.2    Jewers, K.3    Robinson, J.M.4
  • 5
    • 0000746634 scopus 로고
    • Screening seed of Trigonella and three related genera for diosgenin
    • Bohannon, M. B.; Hagemann, J. W.; Earle, F. R.; Barclay, A. S. Screening seed of Trigonella and three related genera for diosgenin. Phytochemistry 1974, 13, 1513-1514.
    • (1974) Phytochemistry , vol.13 , pp. 1513-1514
    • Bohannon, M.B.1    Hagemann, J.W.2    Earle, F.R.3    Barclay, A.S.4
  • 6
    • 0642284075 scopus 로고
    • Massenspektroskopie und ihre anwendung auf strukturelle und stereochemische probleme, 15. Mitt.: Steroidsapogenine (Mass spectrometry in structural and stereochemical problems-XV: Steroidal sapogenins)
    • Budzikiewicz, H.; Wilson, J. M.; Djerassi, C. Massenspektroskopie und ihre anwendung auf strukturelle und stereochemische probleme, 15. Mitt.: Steroidsapogenine (Mass spectrometry in structural and stereochemical problems-XV: steroidal sapogenins). Monatsh. Chem. 1962, 93, 1033-1045.
    • (1962) Monatsh. Chem. , vol.93 , pp. 1033-1045
    • Budzikiewicz, H.1    Wilson, J.M.2    Djerassi, C.3
  • 7
    • 0022880278 scopus 로고
    • Improvement of diosgenin yield from Dioscorea deltoidea plant cell cultures by use of a nontraditional hydrolysis method
    • Drapeau, D.; Sauvaire, Y.; Blanch, H. W.; Wilke, C. R. Improvement of diosgenin yield from Dioscorea deltoidea plant cell cultures by use of a nontraditional hydrolysis method. Planta Med. 1986, 474-478.
    • (1986) Planta Med. , pp. 474-478
    • Drapeau, D.1    Sauvaire, Y.2    Blanch, H.W.3    Wilke, C.R.4
  • 8
    • 84934237179 scopus 로고
    • Mass spectrometry in structural and stereochemical problems-CXCIV: The mass spectrometric fragmentations of steroidal sapogenins
    • Faul, W. H.; Djerassi, C. Mass spectrometry in structural and stereochemical problems-CXCIV: The mass spectrometric fragmentations of steroidal sapogenins. Org. Mass Spectrom. 1970, 3, 1187-1213.
    • (1970) Org. Mass Spectrom. , vol.3 , pp. 1187-1213
    • Faul, W.H.1    Djerassi, C.2
  • 9
    • 0002653728 scopus 로고
    • The spice, fenugreek (Trigonella foenum graecum L.): Its commercial varieties of seed as a source of diosgenin
    • Fazli, F. R. Y.; Hardman, R. The spice, fenugreek (Trigonella foenum graecum L.): Its commercial varieties of seed as a source of diosgenin. Trop. Sci. 1968, 10, 66-78.
    • (1968) Trop. Sci. , vol.10 , pp. 66-78
    • Fazli, F.R.Y.1    Hardman, R.2
  • 10
    • 0000017371 scopus 로고
    • Isolation and characterization of steroids and other constituents from Trigonella foenumgraecum
    • Fazli, F. R. Y.; Hardman, R. Isolation and characterization of steroids and other constituents from Trigonella foenumgraecum. Phytochemistry 1971, 10, 2497-2503.
    • (1971) Phytochemistry , vol.10 , pp. 2497-2503
    • Fazli, F.R.Y.1    Hardman, R.2
  • 11
    • 0004208435 scopus 로고
    • Reinhold Publishing: New York
    • Fieser, L. F.; Fieser, M. Steroids; Reinhold Publishing: New York, 1959; p 821.
    • (1959) Steroids , pp. 821
    • Fieser, L.F.1    Fieser, M.2
  • 12
    • 0001731889 scopus 로고
    • An attempt to reproduce crystal-associated cholangitis in lambs by the experimental dosing of sarsasapogenin or diosgenin alone and in combination with sporidesmin
    • Flaoyen, A.; Smith, B. L.; Miles, C. O. An attempt to reproduce crystal-associated cholangitis in lambs by the experimental dosing of sarsasapogenin or diosgenin alone and in combination with sporidesmin. N. Z. Vet. J. 1993, 41, 171-174.
    • (1993) N. Z. Vet. J. , vol.41 , pp. 171-174
    • Flaoyen, A.1    Smith, B.L.2    Miles, C.O.3
  • 13
    • 0003056574 scopus 로고
    • Forage fiber analyses (appartus, reagents, procedures and some applications)
    • ARS, USDA: Washington, DC
    • Goering, H. K.; Van Soest, P. J. Forage fiber analyses (appartus, reagents, procedures and some applications). Agricultural Handbook 379; ARS, USDA: Washington, DC, 1970; p 15.
    • (1970) Agricultural Handbook , vol.379 , pp. 15
    • Goering, H.K.1    Van Soest, P.J.2
  • 14
    • 0001390499 scopus 로고
    • Furostanol glycosides from Trigonella foenum-graecum seeds
    • Gupta, R. K.; Jain, D. C.; Thakur, R. S. Furostanol glycosides from Trigonella foenum-graecum seeds. Phytochemistry 1984, 23, 2605-2607.
    • (1984) Phytochemistry , vol.23 , pp. 2605-2607
    • Gupta, R.K.1    Jain, D.C.2    Thakur, R.S.3
  • 15
    • 0011332575 scopus 로고
    • Trigofoenoside E-1, a new furostanol saponin from Trigonella foenum-graecum
    • Gupta, R. K.; Jain, D. C.; Thakur, R. S. Trigofoenoside E-1, a new furostanol saponin from Trigonella foenum-graecum. Indian J. Chem. 1985, 24B, 1215-1217.
    • (1985) Indian J. Chem. , vol.24 B , pp. 1215-1217
    • Gupta, R.K.1    Jain, D.C.2    Thakur, R.S.3
  • 16
    • 0006876313 scopus 로고
    • A combined column-chromatographic and infrared spectrophotometric determination of diosgenin and yamogenin in fenugreek seed
    • Hardman, R.; Jefferies, T. M. A combined column-chromatographic and infrared spectrophotometric determination of diosgenin and yamogenin in fenugreek seed. Analyst 1972, 97, 437-441.
    • (1972) Analyst , vol.97 , pp. 437-441
    • Hardman, R.1    Jefferies, T.M.2
  • 18
    • 0001161775 scopus 로고
    • Isolation of the steroidal sapogenin epismilagenin from the bile of sheep affected by Panicum dichotomiflorum toxicosis
    • Holland, P. T.; Miles, C. O.; Mortimer, P. H.; Wilkins, A. L.; Hawkes, A. D.; Smith, B. L. Isolation of the steroidal sapogenin epismilagenin from the bile of sheep affected by Panicum dichotomiflorum toxicosis. J. Agric.Food Chem. 1991, 39, 1963-1965.
    • (1991) J. Agric.Food Chem. , vol.39 , pp. 1963-1965
    • Holland, P.T.1    Miles, C.O.2    Mortimer, P.H.3    Wilkins, A.L.4    Hawkes, A.D.5    Smith, B.L.6
  • 19
    • 0028119949 scopus 로고
    • Effects of dietary saponins on fecal bile acids and neutral sterols, and availability of vitamins A and E in the chick
    • Jenkins, K. J.; Atwal, A. S. Effects of dietary saponins on fecal bile acids and neutral sterols, and availability of vitamins A and E in the chick. J. Nutr. Biochem. 1994, 5, 134-137.
    • (1994) J. Nutr. Biochem. , vol.5 , pp. 134-137
    • Jenkins, K.J.1    Atwal, A.S.2
  • 20
    • 0017575659 scopus 로고
    • Analysis of Fenugreek sapogenins by gas-liquid chromatography
    • Knight, J. C. Analysis of Fenugreek sapogenins by gas-liquid chromatography. J. Chromatogr. 1977, 133, 222-225.
    • (1977) J. Chromatogr. , vol.133 , pp. 222-225
    • Knight, J.C.1
  • 21
    • 0028895985 scopus 로고
    • Supercritical fluid extraction of diosgenin from tubers of Dioscorea nipponica
    • Liu, B.; Lockwood, B.; Gifford, L. A. Supercritical fluid extraction of diosgenin from tubers of Dioscorea nipponica. J. Chromatogr. 1995, 690, 250-253.
    • (1995) J. Chromatogr. , vol.690 , pp. 250-253
    • Liu, B.1    Lockwood, B.2    Gifford, L.A.3
  • 23
    • 0040621386 scopus 로고
    • Relationships between ruminant bloat and the composition of alfalfa herbage. II. Saponins
    • Majak, W.; Howarth, R. E.; Fesser, A. C.; Goplen, B. P.; Pedersen, M. W. Relationships between ruminant bloat and the composition of alfalfa herbage. II. Saponins. Can. J. Anim. Sci. 1980, 60, 699-708.
    • (1980) Can. J. Anim. Sci. , vol.60 , pp. 699-708
    • Majak, W.1    Howarth, R.E.2    Fesser, A.C.3    Goplen, B.P.4    Pedersen, M.W.5
  • 25
    • 0017067796 scopus 로고
    • Steroids and an artifact from Dioscorea deltoidea tissue cultures
    • Marshall, J. G.; Staba, E. J. Steroids and an artifact from Dioscorea deltoidea tissue cultures. Lloydia 1976, 39, 84-85.
    • (1976) Lloydia , vol.39 , pp. 84-85
    • Marshall, J.G.1    Staba, E.J.2
  • 26
    • 0001361425 scopus 로고
    • Identification of the calcium salt of epismilagenin β-D-glucuronide in the bile crystals of sheep affected by Panicum dichotomiflorum and Panicum schinzii toxicoses
    • Miles, C. O.; Wilkins, A. L.; Munday, S. C.; Holland, P. T.; Smith, B. L.; Lancaster, M. J.; Embling, P. P. Identification of the calcium salt of epismilagenin β-D-glucuronide in the bile crystals of sheep affected by Panicum dichotomiflorum and Panicum schinzii toxicoses. J. Agric. Food Chem. 1992, 40, 1606-1609.
    • (1992) J. Agric. Food Chem. , vol.40 , pp. 1606-1609
    • Miles, C.O.1    Wilkins, A.L.2    Munday, S.C.3    Holland, P.T.4    Smith, B.L.5    Lancaster, M.J.6    Embling, P.P.7
  • 27
    • 0001060926 scopus 로고
    • Identification of insoluble salts of the β-D-glucuronides of episarsasapogenin and epismilagenin in the bile of lambs with alveld and examination of Narthecium ossifragum, Tribulus terrestris, and Panicum miliaceum for sapogenins
    • Miles, C. O.; Wilkins, A. L.; Munday, S. C.; Flaoyen, A.; Holland, P. T.; Smith, B. L. Identification of insoluble salts of the β-D-glucuronides of episarsasapogenin and epismilagenin in the bile of lambs with alveld and examination of Narthecium ossifragum, Tribulus terrestris, and Panicum miliaceum for sapogenins. J. Agric. Food Chem. 1993, 41, 914-917.
    • (1993) J. Agric. Food Chem. , vol.41 , pp. 914-917
    • Miles, C.O.1    Wilkins, A.L.2    Munday, S.C.3    Flaoyen, A.4    Holland, P.T.5    Smith, B.L.6
  • 28
    • 0028508642 scopus 로고
    • Photosensitivity in South Africa. VII. Chemical composition of biliary crystals from a sheep with experimentally induced geeldikkop
    • Miles, C. O.; Wilkins, A. L.; Erasmus, G. L.; Kellerman, T. S.; Coetzer, J. A. W. Photosensitivity in South Africa. VII. Chemical composition of biliary crystals from a sheep with experimentally induced geeldikkop. Onderstepoort J. Vet. Res. 1994a, 61, 215-222.
    • (1994) Onderstepoort J. Vet. Res. , vol.61 , pp. 215-222
    • Miles, C.O.1    Wilkins, A.L.2    Erasmus, G.L.3    Kellerman, T.S.4    Coetzer, J.A.W.5
  • 29
    • 0028679554 scopus 로고
    • Photosensitivity in South Africa. VIII. Ovine metabolism of Tribulus terrestris saponins during experimentally induced geeldikkop
    • Miles, C. O.; Wilkins, A. L.; Erasmus, G. L.; Kellerman, T. S. Photosensitivity in South Africa. VIII. Ovine metabolism of Tribulus terrestris saponins during experimentally induced geeldikkop. Onderstepoort J. Vet. Res. 1994b, 61, 351-359.
    • (1994) Onderstepoort J. Vet. Res. , vol.61 , pp. 351-359
    • Miles, C.O.1    Wilkins, A.L.2    Erasmus, G.L.3    Kellerman, T.S.4
  • 30
    • 21344499103 scopus 로고
    • Comparison of the nutrient content and in situ degradability of fenugreek (Trigonella foenum-graecum) and alfalfa hays
    • Mir, P. S.; Mir, Z.; Townley-Smith, L. Comparison of the nutrient content and in situ degradability of fenugreek (Trigonella foenum-graecum) and alfalfa hays. Can. J. Anim. Sci. 1993, 73, 993-996.
    • (1993) Can. J. Anim. Sci. , vol.73 , pp. 993-996
    • Mir, P.S.1    Mir, Z.2    Townley-Smith, L.3
  • 31
    • 0031491621 scopus 로고    scopus 로고
    • Nurtient composition, in vitro gas production and digestibility of fenugreek (Trigonella foenum-graecum) and alfalfa forages
    • in press
    • Mir, Z.; Acharya, S. N.; Mir, P. S.; Taylor, W. G.; Zaman, M. S.; Mears, G. J.; Goonewardene, L. A. Nurtient composition, in vitro gas production and digestibility of fenugreek (Trigonella foenum-graecum) and alfalfa forages. Can. J. Anim. Sci. 1997, in press.
    • (1997) Can. J. Anim. Sci.
    • Mir, Z.1    Acharya, S.N.2    Mir, P.S.3    Taylor, W.G.4    Zaman, M.S.5    Mears, G.J.6    Goonewardene, L.A.7
  • 32
    • 0012441103 scopus 로고
    • Simple procedure for the routine assay of Dioscorea tubers
    • Morris, M. P.; Roark, B. A.; Cancel, B. Simple procedure for the routine assay of Dioscorea tubers. J. Agric. Food Chem. 1958, 6, 856-858.
    • (1958) J. Agric. Food Chem. , vol.6 , pp. 856-858
    • Morris, M.P.1    Roark, B.A.2    Cancel, B.3
  • 33
    • 0010377015 scopus 로고
    • Isolation and structure elucidation of dichotomin, a furostanol saponin implicated in hepatogenous photosensitization of sheep grazing Panicum dichotomoflorum
    • Munday, S. C.; Wilkins, A. L.; Miles, C. O.; Holland, P. T. Isolation and structure elucidation of dichotomin, a furostanol saponin implicated in hepatogenous photosensitization of sheep grazing Panicum dichotomoflorum. J. Agric. Food Chem. 1993, 41, 267-271.
    • (1993) J. Agric. Food Chem. , vol.41 , pp. 267-271
    • Munday, S.C.1    Wilkins, A.L.2    Miles, C.O.3    Holland, P.T.4
  • 35
    • 0029166179 scopus 로고
    • Steroid saponins from fenugreek seeds: Extraction, purification, and pharmacological investigation on feeding behavior and plasma cholesterol
    • Petit, P. R.; Sauvaire, Y. D.; Hillaire-Buys, D. M.; Leconte, O. M.; Baissac, Y. G.; Ponsin, G. R.; Ribes, G. R. Steroid saponins from fenugreek seeds: Extraction, purification, and pharmacological investigation on feeding behavior and plasma cholesterol. Steroids 1995, 60, 674-680.
    • (1995) Steroids , vol.60 , pp. 674-680
    • Petit, P.R.1    Sauvaire, Y.D.2    Hillaire-Buys, D.M.3    Leconte, O.M.4    Baissac, Y.G.5    Ponsin, G.R.6    Ribes, G.R.7
  • 36
  • 38
    • 0015461531 scopus 로고
    • A simplified method of extraction of diosgenin from Dioscorea tubers and its determination by gas-liquid chromatography
    • Rozanski, A. A simplified method of extraction of diosgenin from Dioscorea tubers and its determination by gas-liquid chromatography. Analyst 1972, 97, 968-972.
    • (1972) Analyst , vol.97 , pp. 968-972
    • Rozanski, A.1
  • 40
    • 0001559622 scopus 로고
    • L'obtention de la diosgénine, (25R)-spirost-5-ène-3β-ol: Problèmes de l'hydrolyse acide des saponines [Diosgenin, (3β, 25R)spirost-5-en-3-ol: Problems of the acid hydrolysis of saponins]
    • Sauvaire, Y.; Baccou, J. C. L'obtention de la diosgénine, (25R)-spirost-5-ène-3β-ol: Problèmes de l'hydrolyse acide des saponines [Diosgenin, (3β, 25R)spirost-5-en-3-ol: problems of the acid hydrolysis of saponins]. Lloydia 1978, 41, 247-256.
    • (1978) Lloydia , vol.41 , pp. 247-256
    • Sauvaire, Y.1    Baccou, J.C.2
  • 41
    • 0026036209 scopus 로고
    • Implication of steroid saponins and sapogenins in the hypocholesterolemic effect of fenugreek
    • Sauvaire, Y.; Ribes, G.; Baccou, J. C.; Loubatieres-Mariani, M. M. Implication of steroid saponins and sapogenins in the hypocholesterolemic effect of fenugreek. Lipids 1991, 26, 191-197.
    • (1991) Lipids , vol.26 , pp. 191-197
    • Sauvaire, Y.1    Ribes, G.2    Baccou, J.C.3    Loubatieres-Mariani, M.M.4
  • 42
    • 0027418180 scopus 로고
    • The effect of an ethanol extract derived from fenugreek (Trigonella foenum graecum) on bile acid absorption and cholesterol levels in rats
    • Stark, A.; Madar, Z. The effect of an ethanol extract derived from fenugreek (Trigonella foenum graecum) on bile acid absorption and cholesterol levels in rats. Br. J. Nutr. 1993, 69, 277-287.
    • (1993) Br. J. Nutr. , vol.69 , pp. 277-287
    • Stark, A.1    Madar, Z.2
  • 44
    • 0004803744 scopus 로고
    • Steroidal sapogenins. XXIV. The hydrochloric acid catalyzed equilibration of 22ξ,-25D- and 22ξ,25L-spirostanes
    • Wall, M. E.; Serota, S.; Witnauer, L. P. Steroidal sapogenins. XXIV. The hydrochloric acid catalyzed equilibration of 22ξ,-25D-and 22ξ,25L-spirostanes. J. Am. Chem. Soc. 1955, 77, 3086-3089.
    • (1955) J. Am. Chem. Soc. , vol.77 , pp. 3086-3089
    • Wall, M.E.1    Serota, S.2    Witnauer, L.P.3
  • 45
    • 0000926399 scopus 로고
    • GC-MS method for analysis of steroidal sapogenins in plant and animal samples associated with ovine photosensitisation
    • Colegate, S. M., Dorling, P. R., Eds.; CAB International: Oxford, U.K., Chapter 48
    • Wilkins, A. L.; Miles, C. O.; Smith, B. L.; Meagher, L. P.; Ede, R. M. GC-MS method for analysis of steroidal sapogenins in plant and animal samples associated with ovine photosensitisation. In Plant Associated Toxins: Agricultural, Photochemical and Ecological Aspects; Colegate, S. M., Dorling, P. R., Eds.; CAB International: Oxford, U.K., 1994; Chapter 48.
    • (1994) Plant Associated Toxins: Agricultural, Photochemical and Ecological Aspects
    • Wilkins, A.L.1    Miles, C.O.2    Smith, B.L.3    Meagher, L.P.4    Ede, R.M.5


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