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Volumn 36, Issue 12, 1997, Pages 1103-1112

Chemoselective rhodium-carbenoid reaction with the aromatic nucleus: An efficient methodology for 2-indanones, 2- Tetralones and 2-benzosuberones and its application in the synthesis of (±)-ar-Himachalene

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EID: 0642302387     PISSN: 03764699     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (6)

References (48)
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    • (1986) Chem Rev , vol.86 , pp. 919
    • Doyle, M.P.1
  • 2
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    • For recent reviews see : (a) Doyle M P, Chem Rev, 86, 1986, 919. (b) Maas G, Top Curr Chem, 137, 1987, 77. (c) Adams J Spero D M, Tetrahedron, 47, 1991, 1765; Padwa A & Krumpe K E, Tetrahedron, 48, 1992, 5385; Ye, T & Mckervey M A, Chem Rev, 94,1994, 1091.
    • (1987) Top Curr Chem , vol.137 , pp. 77
    • Maas, G.1
  • 3
    • 0025976645 scopus 로고
    • For recent reviews see : (a) Doyle M P, Chem Rev, 86, 1986, 919. (b) Maas G, Top Curr Chem, 137, 1987, 77. (c) Adams J Spero D M, Tetrahedron, 47, 1991, 1765; Padwa A & Krumpe K E, Tetrahedron, 48, 1992, 5385; Ye, T & Mckervey M A, Chem Rev, 94,1994, 1091.
    • (1991) Tetrahedron , vol.47 , pp. 1765
    • Adams, J.1    Spero, D.M.2
  • 4
    • 0026632575 scopus 로고
    • For recent reviews see : (a) Doyle M P, Chem Rev, 86, 1986, 919. (b) Maas G, Top Curr Chem, 137, 1987, 77. (c) Adams J Spero D M, Tetrahedron, 47, 1991, 1765; Padwa A & Krumpe K E, Tetrahedron, 48, 1992, 5385; Ye, T & Mckervey M A, Chem Rev, 94,1994, 1091.
    • (1992) Tetrahedron , vol.48 , pp. 5385
    • Padwa, A.1    Krumpe, K.E.2
  • 5
    • 0000709206 scopus 로고
    • For recent reviews see : (a) Doyle M P, Chem Rev, 86, 1986, 919. (b) Maas G, Top Curr Chem, 137, 1987, 77. (c) Adams J Spero D M, Tetrahedron, 47, 1991, 1765; Padwa A & Krumpe K E, Tetrahedron, 48, 1992, 5385; Ye, T & Mckervey M A, Chem Rev, 94,1994, 1091.
    • (1994) Chem Rev , vol.94 , pp. 1091
    • Ye, T.1    Mckervey, M.A.2
  • 17
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    • It may be mentioned here that 2-indanones have been prepared by a similar strategy; see: Nakatani K, Tetrahedron Lett, 28, 1987, 165.
    • (1987) Tetrahedron Lett , vol.28 , pp. 165
    • Nakatani, K.1
  • 18
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    • Hannemann, K.1
  • 23
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    • The intramolecular Buchner reaction of α- diazoketones tolerates electron donating substituents but not halogen. See: Scott L T & Sumpter C A, Org Synth Coll, VIII, 1993, 196.
    • (1993) Org Synth Coll , vol.8 , pp. 196
    • Scott, L.T.1    Sumpter, C.A.2
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    • note
    • It may be noted that bicyclic homotrienones 7a-b and 10a-e are sensitive to acid and alkali and are not amenable to purification procedures. Their preparation, handling and analysis are carried-out immediately using oven-dried apparatus washed with aqueous ammonia solution.


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