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Volumn 33, Issue 18, 1994, Pages 1839-1841

Oxygen Evolution by Oxidation of Water with Manganese Porphyrin Dimers

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EID: 0542372293     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199418391     Document Type: Article
Times cited : (275)

References (32)
  • 1
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    • Biologische Sonnenenergienutzung durch photosynthetische Wasserspaltung
    • (1987) Angewandte Chemie , vol.99 , pp. 660-678
    • Renger, G.1
  • 5
    • 0001444968 scopus 로고
    • Ein Strukturmodell für den wasseroxidierenden Mangancluster im Photosystem II
    • See also a recent Highlight
    • (1994) Angewandte Chemie , vol.106 , pp. 765
    • Wieghardt, K.1
  • 9
    • 0000051997 scopus 로고
    • Die aktiven Zentren in manganhaltigen Metalloproteinen und anorganische Modellkomplexe
    • (1989) Angewandte Chemie , vol.101 , pp. 1179-1198
    • Wieghardt, K.1
  • 13
    • 0001590362 scopus 로고
    • O2-Erzeugung durch Oxidation von Wasser mit Mangankomplexen als Heterogenkatalysatoren
    • Oxygen evolution with a solid dinuclear manganese complex [7a] or a dispersed manganese oxide [7b] has been reported. However, neither the reaction mechanism nor the reactive complex has been elucidated, (a)
    • (1986) Angewandte Chemie , vol.98 , pp. 824-825
    • Ramaraj, R.1    Kira, A.2    Kaneko, M.3
  • 16
    • 84989552270 scopus 로고    scopus 로고
    • o‐Phenylene‐linked porphyrin dimers 1‐3 were prepared by the stepwise formation of the macrocycle under Lindsey conditions after major improvement of the synthetic route.
  • 19
    • 84989556365 scopus 로고    scopus 로고
    • The applied porphyrin monomers corresponding to the dimers 1‐3 are the manganese complexes of 5,10,15,20‐tetrakis(4‐tert‐butylphenyl)‐21H,23H‐porphin (tBuPP), 5,10,15,20‐tetrakis(2,4,6‐trimethylphenyl)‐21H,23H‐porphin (TMP), and 5,10,15,20‐tetrakis(pentafluorophenyl)‐21H,23H‐porphin (PFPP), respectively.
  • 20
    • 84989582724 scopus 로고    scopus 로고
    • +:[MntBuPP] 0.89, 1.20; [MnTMP] 0.75, 0.94; 1 0.81, 0.97, 1.30; 2 0.86, 1.00. Clear reversible waves were not obtained for [MnPFPP] and 3.
  • 21
    • 84989582346 scopus 로고    scopus 로고
    • 2O. Evolved oxygen was analyzed by a Clark‐type oxygen electrode (YSI‐5531).
  • 23
    • 84989550049 scopus 로고    scopus 로고
    • 2 was not detected by mass spectrometry.
  • 27
    • 84989541876 scopus 로고    scopus 로고
    • −1 for the observed solvent system with ferrocene as a standard compound. In consideration of the higher molecular weight of 3, n and D for 3 should be smaller than those of ferrocene and the actual n should be larger than that estimated.
  • 28
    • 84989580163 scopus 로고    scopus 로고
    • Under the same conditions the Levich plot of the corresponding monomer [MnPFPP] gave n = 1.8.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.