Carboxyl-terminated isotactic polypropylene. Preparation, characterization, kinetics, and reactivities

Macromolecules

Volumn 37, Issue 2, 2004, Pages 267-275

  Fu, Peng Fei ^a   Tomalia, Mary Kay ^a  

^a DOW CORNING CORPORATION   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEGRADATION; INTERFACES (MATERIALS); MOLECULAR WEIGHT DISTRIBUTION; NITRIC ACID; REACTION KINETICS; TEMPERATURE;

CARBOXYL TERMINATED ISOTACTIC POLYPROPYLENE; CRYSTALLINE POLYMER;

POLYPROPYLENES;

EID: 0442326645     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0303061     Document Type: Article

References (53)

1. (a) Datta, S.; Lohse, D. J. Polymeric Compatibilizers: Uses and Benefits in Polymer Blend; Hanser/Gardner: New York, 1996.
2. (b) Padwa, A. Prog. Polym. Sci. 1989, 14, 811-833.
3. (c) Goethals, E. J. Telechelic Polymers: Synthesis and Application; CRC: Boca Raton, FL, 1989.
4. (d) Chung, T. C. Functionalization of Polyolefins; Academic Press: London, 2002.
5. (a) Hadjichristidis, N.; Pispas, S.; Floudas, G. A. Block Copolymers: Synthetic Strategies, Physical Properties, and Applications; Wiley: New York, 2003.
6. (b) Balta Calleja, F. J.; Roslaniec, Z. Block Copolymers; Marcel Dekker: New York, 2000.
7. (c) Noshay, A.; McGrath, J. E. Block Copolymers: Overview and Critical Survey; Academic Press: New York, 1977.
8. (d) Aggarwel, S. L. Block Polymers; Plenum Press: New York, 1970.
9. (e) Quirk, R. P.; et al. In Comprehensive Polymer Scienc; Allen, G., Bevington, J. C., Eds.; Pergamon: Oxford; 1989; Vol. 7, Chapter 1.
10. (f) Allport, D. C.; Mojaher, A. A. In Block Copolymers; Allport, D. C., Janes, W. H., Eds.; Applied Science: London, 1973; p 208.
11. (g) Goodman, I. In Comprehensive Polymer Science; Allen, G., Bevington, J. C., Eds.; Pergamon: Oxford, 1989; Vol. 6, Chapter 11.
12. (a) Hustad, P. D.; Coates, G. W. J. Am. Chem. Soc. 2002, 124, 11578.
13. (b) Stehling, U. M.; Stein, K. M.; Fischer, D.; Waymounth, R. M. Macromolecules 1999, 32, 14.
14. (c) Wilen, C.-E.; Nasman, J. H. Macromolecules 1994, 27, 4051.
15. (d) Marathe, S.; Sivaram, S. Macromolecules 1994, 27, 1083.
16. (e) Kesti, M. R.; Coates, G. W.; Waymouth, R. M. J. Am. Chem. Soc. 1992, 114, 9669.
17. For hydrogenation of functional butadiene: (a) Fraser, C.; Hillmyer, M. A.; Gutierrez, E.; Grubbs, R. H. Macromolecules 1995, 28, 7256-7261 and references therein.
18. (b) Shiono, T.; Naga, N.; Soga, K. Makromol. Chem., Rapid Commun. 1993, 14, 323-327.
19. (a) Chung, T. C.; Janvikul, W. J. Organomet. Chem. 1999, 581, 176 and references therein.
20. (b) Chung, T. C. CHEMTECH 1991, 21, 496.
21. Ratzsch, M.; Bucka, H.; Hesse, A.; Reichelt, N.; Borsig, E. Macromol. Symp. 1998, 129, 53 and references therein.
22. (a) Lia, J.; Yang, X.; Seyam, A.; Albert, I.; Fu, P.-F.; Yang, S.; Marks, T. J. J. Am. Chem. Soc. 1996, 118, 7900-7913.
23. (b) Yang, X.; Seyam, A.; Fu, P.F.; Marks, T. J. Macromolecules 1994, 27, 4625-4626.
24. (a) Fu, P.-F.; Glover, S.; King, R.; Lee, C.-L.; Pretzer, M.; Tomalia, M. K. Polym. Prepr. 2000, 41 (2), 1903.
25. (b) Weng, W.; Markel, E. J.; Dekmeziam, A. H. Polym. Prepr. 2000, 41 (1) 498.
26. (a) Fu, P.-F.; Marks, T.J. J. Am. Chem. Soc. 1995, 117, 10747.
27. (b) Brookhart, M.; et al. Macromolecules 1995, 28, 10747.
28. (c) Koo, K.; Fu, P.-F.; Marks, T, J. Macromolecules 1999, 32, 981.
29. Xu, G.; Chung, T. C. J. Am. Chem. Soc. 1999, 121, 6763.
30. (f) Dong, J. Y.; Wang, Z. M.; Hong, H.; Chung, T. C. Macromolecules 2002, 35, 9352.
31. Doi, Y.; Keii, T. Adv. Polym. Sci. 1986, 73/74, 201 and references therein.
32. Shiono, T.; Kurosawa, H.; Soga, K. Macromolecules 1992, 25, 2751 and references therein.
33. Sawaguchi, T.; Ikemura, T.; Seno, M. Macromolecules 1995, 28, 7973.
34. Kurosawa, H.; Shiono, T.; Soga, K. Macromol. Chem. Phys. 1994, 195, 3303.
35. (a) Lindsay, A. F. Chem. Eng. Sci. 1954, 3 (Special Supplement), 78.
36. (b) Ogata, Y. In Oxidation Chemistry, Trahanovsky, W. S., Ed.; Academic Press: New York, 1972; p 295.
37. (a) Keller, A.; Martuschellie, E.; Priest, D. J.; Udagawa, Y. J. Polym. Sci., Part A2 1971, 9, 1807.
38. (b) Williams, T.; Blundell, D. J.; Keller, T.; Ward, I. M. J. Polym. Sci., Part A2 1971, 6, 1613.
39. (a) Keller, A.; Udagawa, Y. J. Polym. Sci., Part A2 1970, 8, 19.
40. (b) Melby, L. R. Macromolecules 1978, 11, 50.
41. 13C NMR Predictor, Advanced Chemistry Development Inc., Toronto, 2002.
42. (b) Bremster, W.; Ernst, L.; Franke, B. Carbon-13 NMR Spectral Data, 3rd ed.; Verlag Chemie: Weinheim, 1981.
43. (c) Fresenius, W.; Huber, J. F. K.; Pungor, E.; Rechnitz, G. A.; Simon, W.; West, Th. S. Tables of Spectral Data for Structure Determination of Organic Compounds, 2nd ed.; Biemann, K., Translator; Springer-Verlag: Berlin, 1989.
44. (a) Wagner, D. D. M.; Griller, D. Adv. Free Radical Chem. 1990, 1, 159.
45. (b) March, J. Advanced Organic Chemistry, 4th ed.; Wiley: New York, 1992; p 683.
46. Sperling, L. H. Introduction to Physical Polymer Science; John Wiley: New York, 1992; p 253.
47. Olah, G. Angew. Chem., Int. Ed. Engl. 1973, 12, 173.
48. Suter, U. W.; Nenenschwander, P. Macromolecules 1981, 14, 528.
49. The density of nitric acid solution at 20°C was obtained from International Critical Tables III, 1928, 28, and was used for converting the weight percentage concentration to molar concentration in this case. Density (g/mL at 20°C) = 1.26 (42%), 1.34 (55%), and 1.41 (70%). Concentration (M) = 8.4 (42%), 11.7 (55%), and 15.7 (70%).
50. Moor, J. W.; Pearson, R. G. Kinetics and Mechanism; Wiley: New York, 1981.
51. Fu, P.-F. Manuscript in preparation.
52. (a) Fu, P.-F. Polym. Prepr. 2003, 44 (1), 788.
53. (b) Fu, P.-F.; Glover, S.; King, R. K.; Lee, C.-L.; Pretzer, M. R.; Tomalia, M. K. Polym. Prepr. 2003, 44 (1), 1014.