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The shoulder on the IHB band is likely due to hot-band structure in the ion-water stretching vibration (refs 19, 20) and is still under analysis at this time
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The shoulder on the IHB band is likely due to hot-band structure in the ion-water stretching vibration (refs 19, 20) and is still under analysis at this time.
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-1 (B in Figure 2b) occurs where expected for the overtone of the intramolecular bend of this DA water (ref 20), which again gains intensity through the bend-stretch Fermi interaction (ref 21)
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While qualitatively useful, we caution that the proximity of the bands indicates that there is significant coupling between these (ring/ion) motions in the displacement vectors (refs 3, 4, 6, 63, 69).
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While qualitatively useful, we caution that the proximity of the bands indicates that there is significant coupling between these (ring/ion) motions in the displacement vectors (refs 3, 4, 6, 63, 69).
-
-
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