An Adamantane-Based Coordination Framework with the First Observation of Discrete Metal Sulfonate Clusters

Inorganic Chemistry

Volumn 42, Issue 26, 2003, Pages 8603-8605

  Hoffart, Dennis J ^a   Côté, Adrien P ^a   Shimizu, George K H ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADAMANTANE; COORDINATION COMPOUND; LIGAND; METAL; METAL COMPLEX; SULFONIC ACID DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CLUSTER ANALYSIS; CRYSTAL STRUCTURE; STRUCTURE ANALYSIS;

EID: 0348223918     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0349398     Document Type: Article

References (55)

1. (a) Orr, G. W.; Barbour, L. J.; Atwood, J. L. Science 1999, 285, 1049.
2. (b) Kiang, Y.-H.; Gardner, G. B.; Lee, S.; Xu, Z.; Lobkovsky, E. B. J. Am. Chem. Soc. 1999, 121, 8204.
3. (c) Oh, M.; Carpenter, G. B.; Sweigart, D. A. Organometallics 2003, 22, 2364.
4. (d) Du, M.; Bu, X. H.; Guo, Y. M.; Liu, H.; Batten, S. R.; Ribas, J.; Mak, T. C. W. Inorg. Chem. 2002, 41, 4904.
5. (e) Hirsch, K. A.; Wilson, S. R.; Moore, J. S. Inorg. Chem. 1997, 36, 2960.
6. (f) Melcer, N. J.; Enright, G. D.; Ripmeester, J. A.; Shimizu, G. K. H. Inorg. Chem. 2001, 40, 4641.
7. (g) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Rizzato, S. CrystEng-Comm 2002, 413.
8. (h) Schultheiss N.; Powell D. R.; Bosch E., Inorg. Chem. 2003, 42, 5304.
9. (a) Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wachter, J.; O'Keeffe, M.; Yaghi, O. M. Science 2002, 295, 469.
10. (b) O'Keeffe, M.; Eddaoudi, M.; Li, H.; Reineke, T.; Yaghi, O. M. J. Solid State Chem. 2000, 152, 3.
11. (c) Evans, O. R.; Lin, W. Acc. Chem. Res. 2002, 35, 511-522.
12. (a) Abrahams, B. F.; Hoskins, B. F.; Michail, D. M.; Robson, R. Nature 1994, 369, 727.
13. (b) Kim, J.; Chen, B. L.; Reineke, T. M.; Li, H. L.; Eddaoudi, M.; Moler, D. B.; O'Keeffe M.; Yaghi, O. M. J. Am. Chem. Soc. 2001, 123, 8239.
14. (a) Kiang, Y. H.; Lee, S.; Xu, Z. T.; Choe, W. Y.; Gardner, G. B. Adv. Mater. 2000, 12, 767.
15. (b) Galan-Mascaros, J. R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 2289.
16. (c) Fan, J.; Sui, Okamura, T.; Sun, W. Y.; Tang, W. X.; Ueyama, N. Dalton Trans. 2002, 3868.
17. (d) Prior, T. J.; Rosseinsky, M. J. Chem. Commun. 2001, 495.
18. (e) Wang, Q. M.; Mak, T. C. W. J. Am. Chem. Soc. 2000, 122, 7608.
19. (f) Chen, B. L.; Lee, S.; Venkataraman, D.; DiSalvo, F. J.; Lobkovsky, E.; Nakayama, M. Cryst. Growth Des. 2002, 2, 101.
20. (g) Kulynych, A. D.; Shimizu, G. K. H. CrystEngCtmm 2002, 102.
21. (a) Zaworotko, M. J. Chem. Soc. Rev. 1994, 23, 283.
22. (b) Evans, O. R.; Lin, W. Chem. Mater. 2001, 13, 2705.
23. (c) MacGillivray, L. R.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1994, 1325.
24. (d) Blake, A. J.; Champness, N. R.; Chung, S. S. M.; Li, W. S.; Schröder, M. Chem. Commun. 1997, 1005.
25. (e) Chen, Z. F.; Xiong, R. G.; Abrahams, B. F.; You, X. Z.; Che, C. M. J. Chem. Soc., Dalton Trans. 2001, 2453.
26. (f) Hong, M. C.; Su, W. P.; Cao, R.; Zhang, W. J.; Li, J. X. Inorg. Chem. 1999, 38, 600.
27. (a) Li, H.; Eddaoudi, M.; O'Keeffe, M.; Yaghi, O. M. Nature 1999, 402, 276.
28. (b) Chiu, S. Y.; Lo, S. M. F.; Charmant, J. P. H.; Orpen, A. G.; Williams, I. D. Science 1999, 283, 1148.
29. (a) Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wachter, J.; O'Keeffe, M.; Yaghi, O. M. Science 2002, 295, 469.
30. (b) Eddaoudi, M.; Moler, D.; Li, H.; Reineke, T. M.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34, 319.
31. Other metal sulfonate work: (a) Mäkinen, S. K.; Melcer, N. J.; Parvez, M.; Shimizu, G. K. H. Chem. Eur. J. 2001, 7, 5176.
32. (b) Cai, J. W.; Chen, C. H.; Feng, X. L.; Liao, C. Z.; Chen, X. M. Dalton Trans. 2001, 2370.
33. (c) Chen, C. H.; Cai, J. W.; Liao, C. Z.; Feng, X. L.; Chen, X. M.; Ng, S. W. Inorg. Chem. 2002, 41, 4967.
34. (d) Park, S. H.; Lee, C. E. Chem. Commun. 2003, 1838.
35. (e) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1995, 34, 2399.
36. (f) Gunderman, B. J.; Squattrito, P. J. Inorg. Chem. 1994, 33, 2924.
37. (g) Shimizu, G. K. H.; Enright, G. D.; Ratcliffe, C. I.; Rego, G. S.; Reid, J. L.; Ripmeester, J. A. Chem. Mater. 1998, 10, 3282.
38. (h) Shimizu, G. K. H.; Enright, G. D.; Ratcliffe, C. I.; Rego, G. S.; Preston, K. F.; Reid, J. L.; Ripmeester, J. A. Chem. Commun. 1999, 1485.
39. Other Ba sulfonate structures: (a) Côté, A. P.; Shimizu, G. K. H. Chem. Commun. 2001, 251.
40. (b) Dalrymple, S. A.; Shimizu, G. K. H. Chem. Eur. J. 2002, 8, 3010.
41. (c) Garaud, Y.; Charbonnier, F.; Faure, R. J. Appl. Crystallogr 1980, 13, 190.
42. (d) Gunderman, B. J.; Kabell, I. D.; Squattrito, P. J.; Dubey, S. N. Inorg. Chim. Acta 1997, 258, 237.
43. (e) Cai, J.; Chen, C.-H.; Liao, C.-Z.; Feng, X.-L.; Chen, X.-M. Acta Crystallogr, 2001, B57, 520.
44. Sharma, S. K.; Snyder, C. E., Jr.; Gschwender, L. J. Lubr. Eng. 1999, 55, 27.
45. Fromm, K. M.; Bernardinelli, G. Z. Inorg. Allg. Chem. 2001, 627, 1626.
46. Yu, J. O.; Côté, A. P.; Enright, G. D.; Shimizu, G. K. H. Inorg. Chem. 2001, 40, 582.
47. (a) Vittal, J. J. Polyhedron 1996, 15, 1585.
48. (b) Chen, B.; Eddaoudi, M.; Reineke, T. M.; Kampf, J. M.; O'Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc. 2000, 122, 11559.
49. 4L was prepared in three steps beginning with adamantane. Details provided as Supporting Information.
50. 2, by using SHELXL-97.19 Barium and sulfur atoms were located first and the remaining atoms found by difference Fourier maps. All non-hydrogen atoms were refined anisotropically.
51. (a) Fromm, K. M. CrystEngComm 2002, 318.
52. (b) Guo, D.; Zhang, B. G.; Duan C. Y.; Pang, K. L.; Meng, Q. J. J. Chem. Soc., Dalton Trans. 2002, 3783.
53. Thermal analyses were performed on a Netzsch STA 449C from 25 to 500 °C at a heating rate of 10 °C/min. Accurate initial masses for the sample were difficult to obtain owing to the loss of volatile guests at ambient conditions.
54. This fully desolvated network is then stable to 510 °C, but PXRD analysis showed the solid to be amorphous at this stage. Upon exposure to water vapor, the network resorbs coordinated solvent molecules (two water molecules per Ba center) but does not revert to its nascent form. It does not resorb dioxane. Water vapor was used as the network has slight, but not insignificant, solubility in water.
55. Sheldrick, G. M. SHELXL-97, Structure Determination Programs; Bruker AXS Inc.: Madison, WI, 1997.