Thiophosgene, a molecule tailor-made for testing fundamental theoretical concepts of radiationless transitions: Intramolecular dynamics of S1 Cl2CS

Journal of Physical Chemistry A

Volumn 107, Issue 48, 2003, Pages 10223-10227

  Fujiwara, Takashige ^a   Moule, David C ^b   Lim, Edward C ^a  

^a UNIVERSITY OF AKRON   (United States)

^b BROCK UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; DISSOCIATION; ELECTRON TRANSITIONS; FLUORESCENCE; GROUND STATE; MATERIALS TESTING; MOLECULAR VIBRATIONS; MOLECULES; PERTURBATION TECHNIQUES; PHASE COMPOSITION; QUANTUM THEORY; THERMAL EFFECTS;

CORIOLIS COUPLING; FRANCK-CONDON FACTOR; INTERNAL CONVERSION; RADIATIONLESS TRANSITION; SPIN-ORBIT COUPLING; THIOPHOSGENE;

MOLECULAR DYNAMICS;

EID: 0348209000     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0309264     Document Type: Letter

References (23)

1. (a) Henry, B. R.; Siebrand, W. In Organic Molecular Photophysics; Birks, J. B., Ed.; Wiley-Interscience: London, 1970; Vol. 1, p 153
2. (b) Freed, K. F. In Topics in Applied Physics; Fong, F. K., Ed.; Springer: Berlin, 1976; Vol. 15, p 23.
3. (c) Avouris, P.; Gelbart, W. M.; El-Sayed, M. A. Chem. Rev. 1977, 77, 793.
4. Lin, S. H.; Bersohn, R. J. Chem. Phys. 1968, 48, 2732.
5. Gardner, P. J.; Kasha, M. J. Chem. Phys 1969, 50, 1543.
6. Maciejewski, A.; Steer, R. P. Chem. Rev. 1993, 93, 977 nd references therein.
7. Brand, J. C. D.; Callomon, J. H.; Moule, D. C.; Tyrrell, J.; Goodwin, T. H. Trans. Faraday. Soc. 1965, 61, 2365.
8. Moule, D. C.; Lim, E. C. J. Chem. Phys. 1999, 110, 9341.
9. Steer, R. P. Rev. Chem. Int. 1981, 4, 1 and references therein.
10. Clouthier, D. J.; Moule, D. C. J. Mol. Spectrosc. 1973, 87, 471.
11. 2v) case of El-Sayed's rule (El-Sayed, M. A. J. Chem. Phys. 1963, 38, 2834.), which states that the spin-orbit coupling between singlet and triplet states of the same orbital character is generally small.
12. Lim, E. C. In Excited States; Lim, E. C., Ed.; Academic Press: New York, 1977; Vol. 3, p 305.
13. Lim, E. C. Adv. Photochem. 1997, 23, 165.
14. McDonald, J. R.; Brus, L. E. Chem. Phys. Lett. 1972, 16, 587.
15. Okabe, H. J. Chem. Phys. 1977, 66, 2058.
16. See, for a recent review: Felker, P. M.; Zewail, A. H. Adv. Chem. Phys. 1988, 70, 265.
17. Brenner, D. M. J. Phys. Chem. 1980, 84, 3341.
18. Kawasaki, M.; Kasatani, K.; Sato, H. Chem. Phys. 1985, 94, 179.
19. Burnell, L. Acad. R. Belg., Bull. Cl. Sci., Mem. 1958, 30, 1.
20. Papousek, D.; Alieve, M. R. In Molecular Vibrational-Rotational Spectra; Elsevier: Amsterdam, 1982.
21. Hachey, M.; Grein, F.; Steer, R. P. Can. J. Chem. 1992, 71, 112.
22. 1 transition.
23. Flicker, W. M.; Masher, O. A.; Kuppermann, A. Chem. Phys. Lett. 1978, 57, 183.A