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Volumn 624, Issue 1-2, 2001, Pages 383-387

Reactivity of γ-benzyloxyallyltins with cyclohexylidene glyceraldehydes

Author keywords

Tributylstannylacrolein dibenzyloxyacetal; Aldopentoses; Allylstannation; Benzyloxyallyltributyltins; Cyclohexylidene glyceraldehyde

Indexed keywords


EID: 0348050677     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00928-1     Document Type: Article
Times cited : (13)

References (42)
  • 8
    • 0001420154 scopus 로고
    • Even scarcely observed, examples of reaction of α-alkoxyallyltins with aldehydes without previous rearrangement into γ-alkoxyallyltins have been reported. Cf. for instance: J.A. Marshall, W.Y. Gung, Tetrahedron 45 (1989) 1043 or J.A. Marshall, D.V. Yashunsky, J. Org. Chem. 56 (1991) 5493.
    • (1989) Tetrahedron , vol.45 , pp. 1043
    • Marshall, J.A.1    Gung, W.Y.2
  • 9
    • 0026062997 scopus 로고
    • Even scarcely observed, examples of reaction of α-alkoxyallyltins with aldehydes without previous rearrangement into γ-alkoxyallyltins have been reported. Cf. for instance: J.A. Marshall, W.Y. Gung, Tetrahedron 45 (1989) 1043 or J.A. Marshall, D.V. Yashunsky, J. Org. Chem. 56 (1991) 5493.
    • (1991) J. Org. Chem. , vol.56 , pp. 5493
    • Marshall, J.A.1    Yashunsky, D.V.2
  • 26
    • 0347170679 scopus 로고    scopus 로고
    • note
    • The strategy used for the synthesis of (E)-3,3-diethoxy-1-tributylstannylprop-1-ene which has been previously described in our group [22,23] was applied successfully to the synthesis of dibenzyl acetal 2. β-Tributylstannylacrolein acetals are easily hydrolyzed on wet silica gel to afford β-tributylstannylacrolein which has been shown to react easily with higher order stannylcyanocuprates [24].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.