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0034804017
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For a tetrad system involving multistep electron transfer, a lifetime of 380 ms has also been achieved in PhCN at 163 K. See: Imahori, H.; Guldi, D. M.; Tamaki, K.; Yoshida, Y.; Luo, C.; Sakata, Y.; Fukuzumi, S. J. Am. Chem. Soc. 2001, 123, 6617.
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23
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0346722920
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note
-
The cyclic voltammetry measurements were performed in toluene containing 0.60 M tetrahexylammonium perchlorate.
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-
-
-
24
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0347983662
-
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note
-
+ in 2-methyltetrahydrofuran and in EPA glass (5:5:2 2-propanol:diethyl ether:ethanol) at 77 K. respectively.
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-
-
25
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0001096017
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+* may be negligible since the singlet excited energy of the zinc porphyrin is lower than that of the gold porphyrin; see: Brun, A. M.; Harriman, A.; Heitz, V.; Sauvage, J.-P. J. Am. Chem. Soc. 1991, 113, 8657.
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Brun, A.M.1
Harriman, A.2
Heitz, V.3
Sauvage, J.-P.4
-
26
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0346092303
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-
note
-
The g factors and hfc values were determined by computer simulation using Calleo ESR, version 1.2 program.
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-
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27
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0346722918
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II porphyrins, see: Kadish, K. M.; E. W.; Ou, Z.; Shao, J.; Sintic, P. J.; Ohkubo, K.; Fukuzumi, S.; Crossley, M. J. Chem. Commun. 2002, 356.
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Ou, Z.2
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Sintic, P.J.4
Ohkubo, K.5
Fukuzumi, S.6
Crossley, M.J.7
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