Comparative reactivities of metal cation-catalyzed hydrolysis of p-nitrophenyl picolinate in micellar solutions

Journal of Dispersion Science and Technology

Volumn 24, Issue 6, 2003, Pages 761-765

  Yu, Xiaoqi ^a   Jiang, Bing Ying ^a   Cheng, Si Qing ^b   Huang, Zhong ^a   Zeng, Xian Cheng ^a  

^a SICHUAN UNIVERSITY   (China)

^b WUHAN POLYTECHNIC UNIVERSITY   (China)

Author keywords

Catalysis; Hydrolysis of PNPP; Metal ion micelle

Indexed keywords

CATALYSIS; ELECTROSTATICS; HYDROLYSIS; ORGANIC COMPOUNDS; POSITIVE IONS; SPECTROPHOTOMETRY;

COMPARATIVE REACTIVITIES;

MICELLES;

CATALYSIS;

EID: 0347916874     PISSN: 01932691     EISSN: None     Source Type: Journal    
DOI: 10.1081/DIS-120025543     Document Type: Article

References (16)

1. Khalifah, R.G.; Regers, J.I.; Mukherjee, J. In: Zinc Enzymes; Birkhauser: Boston, MA, 1986.
2. Rosch, M.A.D.; Trogler, W.C. Hydrolysis of phosphodiesters with nickel(II), copper(II), zinc(II), palladium(II) and platinum(II) complexes. Inorg. Chem. 1990, 29, 2409-2416.
3. Fife, T.H.; Pujari, M.P. Divalent metal ion catalysis in the hydrolysis of phosphmonoesters. Hydrolysis of 2-(1,10-phenathroly) phosphate. J. Am. Chem. Soc. 1988, 110, 7790-7797.
4. Breslow, R.; Huang, D. Bifunctional zinc-imidazole and zinc-thiophenol catalysts. J. Am. Chem. Soc. 1990, 112, 3686-3687.
5. Hay, R.W.; Govan, N. A lanthanum macrycycle catalysed hydrolysis of a phosphate triester. J, Chem. Sec., Chem Commun. 1990, 714-715.
6. Huang, Z.; Cheng, S.Q.; Xie, J.Q.; Jiang, WD.; Zeng, X.C. Kinetics of metal ions mediated hydrolysis of p-nitrophenyl picolinate. Chem. Res. Appl. 2000, 12 (6), 605-609.
7. 2+ in the transacylation of p-nitrophenyl picolinate. Bull. Chem. Soc. Jpn. 1991, 64, 74-80.
8. Mancin, F.; Tecilla, P.; Tonellato, U. Metallomicelles made of Ni(II) and Zn(II) complexes of 2-pyridinealdoxime-based ligands as catalyst of the cleavage of carboxylic acid esters. Langmuir 2000, 16, 227-233.
9. Menger, F.M.; Gan, L.H.; Johnson, E.; Durst, D.H. Phosphate ester hydrolysis catalyzed by metallomicelles. J. Am. Chem. Soc. 1987, 109, 2800-2803.
10. Yang, Y.C.; Backer, J.A.; Ward, J.R. Decontamination of chemical warfare agents. Chem. Rev. 1992, 92, 1729-1743.
11. Bunton, C.A.; Gillitt, N.D.; Foroudian, H.J. A quantitative treatment of dephosphorylation by an amphiphilic hydroxyamate ion. The role of micellar charge. Langmuir 1998, 14, 4415-4421.
12. Sigman, D.S.; Jorgensen, C.T. Models for metalloenzymes. Zinc(II)-catalyzed transesterification of N-(beta-hydroxyethyl)ethylenediamine by p-nitrophenyl picolinate. J. Am. Chem. Soc. 1972, 94, 1724-1730.
13. Vogel, A.I. A Textbook of Quantitative Inorganic Analysis; Longman: London, 1961.
14. Fendler, J.H.; Fendler, E.J. Catalysis in Micellar and Macromolecular System; Academic Press: New York, 1975.
15. Menger, F.M.; Portony, C.E. Chemistry of reactions proceeding inside molecular aggregates. J. Am. Chem. Soc. 1967, 18 (89), 4698-4703.
16. Wang, K.; Xu, H.B.; Tang, Y.H.; Le, X. Trace Elements in Life; Metrological Press of China, 1989.